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51.
Nanotechnology processes have recently been introduced into the textile field. One of these processes involves encapsulated nanoparticles or nanoproducts, known as microcapsules. They are available with a wide range of products which confer different properties related to the nature of the encapsulated product. The composition of the wall material determines the release of the product into the fabric and is the object of study in the present work. The behaviour of microencapsulated peppermint was analyzed on cotton fabrics.Different application methods have been tested, impregnation versus bath exhaustion. As impregnation turned out to be the most efficient, some recipes were assayed and the effect of microcapsules on maintenance conditions was evaluated in order to determine the most suitable method with the longest lasting effect on fabrics.The effect of microcapsules is usually measured by the presence of a property such as odour measurements when flavours are encapsulated. The aim of this work is to explain the behaviour of the cotton fabrics with microcapsules bound to their fibers, to determine the relationship between their macroscopic properties and microscopic characteristics. A procedure based in FTIR spectroscopy is also proposed to quantify the presence of microcapsules in the fabrics.IR spectra of the textiles were obtained to determine the presence of microcapsules, which was corroborated by SEM techniques. 相似文献
52.
T. González-Lezana G. Delgado-Barrio P. Villarreal F.X. Gadéa 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(2):227-232
The stabilization method is applied to the case of interacting resonances in the photo-dissociation of van der Waals clusters
composed by a rare gas atom bound to a dihalogen molecule. The study of an illustrative two-dimensional model consisting in
a T-shaped NeI2 molecule shows the adequacy of the method whenever the projection of the stabilization wave functions on the assumed prepared
initial state is accounted for. The agreement of the fragmentation cross-sections with some previous results using the effective
resolvent method and accurate close-coupling calculations is excellent. The method reveals its utility as a complementary
tool since allows, through the analysis of the stabilization wave function in terms of zero-order levels, a precise characterization
of the resonant states involved.
Received 5 April 2002 / Received in final form 24 May 2002 Published online 19 July 2002 相似文献
53.
Pablo Alberca Bjerregaard Alberto Elduque Cndido Martín Gonzlez Francisco Jos Navarro Mrquez 《Journal of Algebra》2002,250(2):397
The well-known Cartan–Jacobson theorem claims that the Lie algebra of derivations of a Cayley algebra is central simple if the characteristic is not 2 or 3. In this paper we have studied these two cases, with the following results: if the characteristic is 2, the theorem is also true, but, if the characteristic is 3, the derivation algebra is not simple. We have also proved that in this last case, there is a unique nonzero proper seven-dimensional ideal, which is a central simple Lie algebra of type A2, and the quotient of the derivation algebra modulo this ideal turns out to be isomorphic, as a Lie algebra, to the ideal itself. The original motivation of this work was a series of computer-aided calculations which proved the simplicity of derivation algebras of Cayley algebras in the case of characteristic not 3. These computations also proved the existence of a unique nonzero proper ideal (which turns out to be seven-dimensional) in the algebra of derivations of split Cayley algebras in characteristic 3. 相似文献
54.
Olga Ordeig Craig E Banks Trevor J Davies F Javier del Campo Francesc Xavier Mu?oz Richard G Compton 《Analytical sciences》2006,22(5):679-683
Gold ultra-microelectrode arrays are used to explore the electrochemical oxidation of hydroxide ions and are shown to be analytical useful. Two types of ultra-microelectrode arrays are used; the first consist of 256 individual electrodes of 5 microm in radius, 170 of which are electrochemically active in a cubic arrangement which are separated from their nearest neighbour by a distance of 100 microm. The second array compromises 2597 electrodes of 2.5 microm in radius and of which 1550 of which are electrochemically active in a hexagonal arrangement separated by the nearest neighbour by 55 microm. Well defined voltammetric waves are found with peak currents proportional to the concentration of hydroxide ions in the range 50 microM to 1 mM. Detection limits of 20 microM using the 170 ultra-microelectrode and 10 microM with the 1550 ultra-microelectrode array are shown to be possible but with a higher sensitivity of 4 mA M(-1) observed using the 1550 ultra-microelectrode array compared to 1.2 mA M(-1) with the 170 ultra-microelectrode array. 相似文献
55.
Francisco Marco-Serrano 《Annals of Operations Research》2006,145(1):167-181
Managerial efficiency within the performing arts programming can be understood as the technical efficiency of transforming the resources cultural managers have available into a determined cultural output. Through this explanation different conceptions on the finished performance product it leads us to select two different output variables (number of performances, and number of attendances). In this way, three different models are considered regarding those conceptual points of view. Data on the Circuït Teatral Valencià, a Spanish regional theatres network, is used to develop empirically the concept of Managerial Efficiency and set up a framework to allow us to monitor it. 相似文献
56.
Angel L. Esteban Maria P. Galache Francisco Mora Ernesto Diez Jesus San Fabian 《Journal of computational chemistry》1989,10(7):887-895
An equation is formulated on the basis of theoretical INDO/FPT calculations which describes the angular dependence of the propanic long-range coupling constant 4JMeH in substituted HCCCH3 fragments. This equation is a truncated Fourier series in the torsion angle ?, HCCMe, which takes into account the dependence of the Fourier coefficients on the bond angle θ, CCMe. The substituent effects are assumed to be additive. Some parameters in the equation may be obtained from the 4JMeH couplings in propane and neopentane derivatives. The calculated effect upon 4JMeH of changes in the bond angle θ is significant and it seems to be in part the cause of some effects which have been attributed to conformational dependence. 相似文献
57.
58.
González-Diaz PF 《Physical review D: Particles and fields》1989,40(12):4184-4185
59.
Gutiérrez de Dios FJ Gómez R Feliu JM 《Langmuir : the ACS journal of surfaces and colloids》2005,21(16):7439-7448
Rhodium adlayers on Pt(100) substrates have been prepared by electrodeposition from dilute Rh(III) acidic solutions. The initially disordered layer is electrochemically annealed by applying a polarization program consisting of high-sweep-rate multicycle sequences between 0.05 and 0.78 V(RHE) in 0.1 M H(2)SO(4). In this way, a pseudomorphic Rh monolayer can be prepared on Pt(100) substrates. The degree of order of the electrochemically annealed layer has been evidenced not only through voltammetric experiments but also by means of scanning tunneling microscopy with atomic resolution for iodine-protected adlayers, which show a c(2 x 2) structure. The electrochemically induced ordering of the Rh adlayer appears to be a consequence of the repeated cycles of adsorption/desorption of H and, especially, oxygenated species. Voltammetry in sulfuric acid solutions permits examination of the energetics of H/anions and OH/O adsorption as a function of the Rh coverage. The first monolayer adsorbs both hydrogen and oxygenated species more strongly than the second one. This can be explained through an electronic effect caused by the underlying Pt(100) substrate. 相似文献
60.
Alvarez-Muñoz D Sáez M Lara-Martin PA Gómez-Parra A González-Mazo E 《Journal of chromatography. A》2004,1052(1-2):33-38
A new method has been developed for the determination of linear alkylbenzene sulfonates (LAS) from various marine organisms, and compared with Soxhlet extraction. The technique applied includes the use of pressurized liquid extraction (PLE) for the extraction stage, preconcentration of the samples, purification by solid-phase extraction (SPE) and analysis by liquid chromatography with fluorescence detection. The spiked concentrations were added to the samples (wet mass of the organisms: Solea senegalensis and Ruditapes semidecussatus), which were homogenized and agitated continuously for 25 h. The samples were extracted by pressurized hot solvent extraction using two different extraction temperatures (100 and 150 degrees C) and by traditional Soxhlet extraction. The best recoveries were obtained employing pressurized hot solvent extraction at 100 degrees C and varied in the range from 66.1 to 101.3% with a standard deviation of between 2 and 13. Detection limit was between 5 and 15 microg kg(-1) wet mass using HPLC-fluorescence detection. The analytical method developed in this paper has been applied for LAS determination in samples from a Flow-through exposure system with the objective of measuring the bioconcentration of this surfactant. 相似文献