全文获取类型
收费全文 | 5415篇 |
免费 | 169篇 |
国内免费 | 38篇 |
专业分类
化学 | 3756篇 |
晶体学 | 26篇 |
力学 | 142篇 |
数学 | 876篇 |
物理学 | 822篇 |
出版年
2024年 | 6篇 |
2023年 | 33篇 |
2022年 | 145篇 |
2021年 | 175篇 |
2020年 | 122篇 |
2019年 | 118篇 |
2018年 | 123篇 |
2017年 | 112篇 |
2016年 | 220篇 |
2015年 | 158篇 |
2014年 | 205篇 |
2013年 | 308篇 |
2012年 | 363篇 |
2011年 | 435篇 |
2010年 | 283篇 |
2009年 | 241篇 |
2008年 | 349篇 |
2007年 | 318篇 |
2006年 | 291篇 |
2005年 | 260篇 |
2004年 | 245篇 |
2003年 | 154篇 |
2002年 | 148篇 |
2001年 | 86篇 |
2000年 | 46篇 |
1999年 | 64篇 |
1998年 | 49篇 |
1997年 | 50篇 |
1996年 | 57篇 |
1995年 | 54篇 |
1994年 | 38篇 |
1993年 | 39篇 |
1992年 | 24篇 |
1991年 | 37篇 |
1990年 | 26篇 |
1989年 | 27篇 |
1988年 | 16篇 |
1987年 | 16篇 |
1986年 | 24篇 |
1985年 | 30篇 |
1984年 | 29篇 |
1983年 | 15篇 |
1982年 | 29篇 |
1981年 | 11篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 8篇 |
1977年 | 5篇 |
1976年 | 7篇 |
1973年 | 3篇 |
排序方式: 共有5622条查询结果,搜索用时 15 毫秒
21.
22.
Francisco Marco-Serrano 《Annals of Operations Research》2006,145(1):167-181
Managerial efficiency within the performing arts programming can be understood as the technical efficiency of transforming the resources cultural managers have available into a determined cultural output. Through this explanation different conceptions on the finished performance product it leads us to select two different output variables (number of performances, and number of attendances). In this way, three different models are considered regarding those conceptual points of view. Data on the Circuït Teatral Valencià, a Spanish regional theatres network, is used to develop empirically the concept of Managerial Efficiency and set up a framework to allow us to monitor it. 相似文献
23.
Angel L. Esteban Maria P. Galache Francisco Mora Ernesto Diez Jesus San Fabian 《Journal of computational chemistry》1989,10(7):887-895
An equation is formulated on the basis of theoretical INDO/FPT calculations which describes the angular dependence of the propanic long-range coupling constant 4JMeH in substituted HCCCH3 fragments. This equation is a truncated Fourier series in the torsion angle ?, HCCMe, which takes into account the dependence of the Fourier coefficients on the bond angle θ, CCMe. The substituent effects are assumed to be additive. Some parameters in the equation may be obtained from the 4JMeH couplings in propane and neopentane derivatives. The calculated effect upon 4JMeH of changes in the bond angle θ is significant and it seems to be in part the cause of some effects which have been attributed to conformational dependence. 相似文献
24.
25.
26.
A. González Arias C. Torres C. de
Francisco J. M. Muñoz P. Hernández
Gómez O. Alejos O. Montero J. I. Iñiguez 《Journal of Thermal Analysis and Calorimetry》2006,86(1):195-198
The article discusses theory and experiment about the measurement of
defect concentration in Ti-substituted yttrium iron garnet by means of thermogravimetry
techniques. The two possible cases arising from oxygen interchange with atmosphere,
oxygen vacancies and interstitial cations, may be analyzed quantitatively
from the derived expressions. The possibility of another type of defects being
present in the samples, not associated to oxygen evolution, is not excluded.
Measurements were carried out in air and CO2 for different
Ti contents. The substitution tends to increase slightly the defect parameter
θ in YIG, while a CO2 reducing atmosphere is
much more effective than the Ti substitution for increasing θ. Calculations
for a given single-phased sample sintered in air show two possibilities: a
deficit of one oxygen atom for every 2.5 unit cells of 96 atoms, or one excess
cation for every 3.5 cells. Other samples show very similar results. The accuracy
involved in the measurements is about 2–3%. 相似文献
27.
Zein films plasticized with oleic acid were formed by solution casting, by the stretching of moldable resins, and by blown film extrusion. The effects of the forming process on film structure were investigated by X-ray diffraction. Wide-angle X-ray scattering (WAXS) patterns showed d-spacings at 4.5 and 10 A, which were attributed to the zein alpha-helix backbone and inter-helix packing, respectively. The 4.5 A d-spacing remained stable under processing while the 10 A d-spacing varied with processing treatment. Small-angle X-ray scattering (SAXS) detected a long-range periodicity for the formed films but not for unprocessed zein, which suggests that the forming process-promoted film structure development is possibly aided by oleic acid. The SAXS d-spacing varied among the samples (130-238 A) according to zein origin and film-forming method. X-ray scattering data suggest that the zein molecular structure resists processing but the zein supramolecular arrangements in the formed films are dependent on processing methods. Structural model for a zein molecular aggregate (based on Matsushima et al.10). Rectangular prisms of individual zein molecules are hexagonally aligned parallel to each other. 相似文献
28.
Alberto Avenoza Jesús H Busto Carlos Cativiela Francisco Corzana Jesús M Peregrina María M Zurbano 《The Journal of organic chemistry》2002,67(2):598-601
A short and efficient asymmetric synthesis of the (6R,7S)-7-tert-butoxycarbonylamino-2-ketocarbacepham is described. The key step involves the hetero Diels-Alder reaction of the benzylimine derived from the enantiomer of Garner's aldehyde with Danishefsky's diene. 相似文献
29.
A simple spectrofluorimetric method for the determination of the fungicide benomyl in grapes is described. Benomyl is rapidly solvolysed in organic solvents to give the highly fluorescent metabolite carbendazim. Solvent effects on the spectral shape and their influence on analytical performance are studied. DMF was found to be the best solvent. The method is sensitive to 12 ng/ml benomyl, and has an RSD at the 0.5 g/ml level of 2.2%. The method is suitable for determining benomyl in spiked grapes, with recoveries in the range 97 to 104%. 相似文献
30.
Francisco García-Montelongo María J. Sánchez Miguel A. Rodríguez 《Mikrochimica acta》1989,98(4-6):259-265
A spectrophotometric method for cyanide based on its inhibition of the colour formation reaction between nickel(II) and 3-(4,5-dimethyl-2-thiazolylazo)-2,6-dihydroxybenzoic acid has been developed, and allows the determination of down to 0.1 g of cyanide. Most of the interferences can be avoided by displacement of the hydrogen cyanide using an arsine generator. 相似文献