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91.
Partially oxidized Si(111) surfaces and surfaces of highly oriented pyrolytic graphite (HOPG) were studied by two different ultrahigh vacuum scanning tunneling microscope (UHV-STM) systems and by an STM system working under ambient conditions, respectively. The STM current images of partially oxidized Si(111) surfaces and HOPG surfaces were analyzed by one/two-dimensional fast Fourier transformation (1D-FFT/2D-FFT). The phenomenon of temporal oscillations of tunneling current on the partially oxidized Si(111) surfaces was detected with both UHV-STM systems. Temporal as well as spatial oscillations of tunneling current appeared in highly resolved STM current images of the Si(111) surfaces simultaneously, but both kinds of oscillations could be discriminated according to their different influence on the 2D-FFT spectra of the current images, while varying the scanning range and rate. On clean HOPG surfaces only spatial oscillations of tunneling current induced by the surface structure were observed.  相似文献   
92.
Landauer's principle states that the erasure of one bit of information requires thefree energy kT ln 2. We argue that the reliability of the bit erasure process isbounded by the accuracy inherent in the statistical state of the energy source(the resources) driving the process. We develop a general framework describingthe thermodynamic worth of the resources with respect to reliable bit erasureor good cooling. This worth turns out to be given by the distinguishability of theresource's state from its equilibrium state in the sense of a statistical inferenceproblem. Accordingly, Kullback—Leibler relative information is a decisivequantity for the worth of the resource's state. Due to the asymmetry of relativeinformation, the reliability of the erasure process is bounded rather by the relativeinformation of the equilibrium state with respect to the actual state than by therelative information of the actual state with respect to the equilibrium state (whichis the free energy up to constants).  相似文献   
93.
Concentric-shell fullerenes, also called carbon onions, produced by carbon ion implantation into silver thin films, and subsequently deposited on a silica substrate, were studied by optical transmission spectroscopy in the wavelength range 0.2 - 1.2 μm. In this interval, the strongest absorption is due to the π-plasmon of sp2-like carbon. The position of the plasmon absorption band clearly evolved from 265 nm at low fluence to 230 nm at high implantation fluences. A simulation of the optical spectra based on dielectric models of the concentric-shell fullerenes layer allowed us to identify the first peak as due to disordered graphite and the latter to the carbon onions. The concentration of residual graphite and the filling fraction of the carbon onions produced at high fluences could be estimated by fitting the optical spectra with computed transmittance curves. Received 13 July 2000  相似文献   
94.
Time and spatially resolved absorption measurements of Xe* particle number densities performed at an X-ray preionized self-sustained XeCl*-laser discharge were used to investigate the reaction kinetics of such discharges and to test the validity of the commonly-made assumption that they are fit well by spatially homogeneous numerical models. It turned out that the Xe* density distribution over the discharge cross section remains homogeneous for less than 100 ns only. Comparing the experimental results of the homogeneous discharge phase with zero-dimensional model calculations, we conclude that induced emission modeled using two excited xenon levels must be taken into account for the quantitative interpretation of the absorption measurements. For the interpretation of the Xe 6s-6p absorption measurements even a multilevel model will be necessary. Further we conclude from the relative courses and the absolute values of the Xe* particle number densities that realistic HCl kinetics should contain three vibrationally excited levels and stepwise excitation processes as proposed by Dem'yanov et al. [8].  相似文献   
95.
We use tunable UV laser light in the region 200–320 nm, produced by frequency doubling the output of a dye laser, for the decomposition of organometallic compounds. This method has been applied to TMA, trimethylaluminum Al(CH3)3. Only the TMA monomer absorbs UV light for >220 nm. TMA decomposes by one-photon absorption mainly into two channels: aluminum atoms Al plus organic fragments, and aluminummonomethyl AlCH3 molecules plus organic fragments. The ratio [Al]/[AlCH3] is wavelength dependent. We present a mechanism to explain the photolysis of trimethyl compounds of group III elements (Al, Ga, In).  相似文献   
96.
The conventional thin-film deposition equipment of pulsed laser deposition (PLD) has been modified for the preparation of individual thin solid films and nanometer-layer stacks of uniform thickness across 100-mm substrates. The planar target configuration was replaced by a cylindrical one and the target motion regime has been improved to provide precise spatial control of the plasma plume orientation. During thin-film deposition, substrate translation is preferred instead of the usual rotation technique. With this arrangement the emission characteristic of the plasma source can be computer controlled and the desired coating can be tailored via a stepper-motor-driven manipulator for the desired layer thickness profile across an extended substrate. Thus, for example, a homogeneous film thickness is obtained even for lower target/substrate distances, and an appropriate deposition rate can be maintained. In a second version, this cylinder geometry principle of plasma plume control by target surface morphology is extended to a spatial solution. The hemispherical target surface becomes the basic element for inside-wall coating of tubes or even of more complex hollow bodies. First applications of the equipment are explained and compared with typical results of the conventional technique.  相似文献   
97.
Electron-energy loss spectra of potassium permanganate (KMnO4) with primary electron energies 25 eV<=E0<=500 eV show 7 peaks in the energy-loss range 1 eV<=ΔE<=10eV and are successfully analysed with a superposition of 7 independent Gaussians. The intensity of these lines follow roughly a power-law dependence on the primary energy I∝E 0 . There are two groups of lines, the first with an exponent α≈0.5, while the lines in the second group decay much stronger with increasingE 0 corresponding to a value 0.9<=α<=1.3. The 4 lines in the first group are identified as dipole allowed transitions by comparison to recent first principle molecular-orbital calculations for the (MnO4) molecule by H. Nakai et al. The dipole-allowed excitation spectrum obtained from this analysis agrees very well with these first principle calculations.  相似文献   
98.
We investigate the cluster consensus problem in directed networks of nonlinearly coupled multi-agent systems by using pinning control. Depending on the community structure generated by the group partition of the underlying digraph, various clusters can be made coherently independent by applying feedback injections to a fraction of the agents. Sufficient conditions for cluster consensus are obtained using algebraic graph theory and matrix theory and some simulations results are included to illustrate the method.  相似文献   
99.
Following the initial synthesis of the fuchsones1I, (α, η -diphenyl-1,4-benzoquinone methides), numerous substituted members of this series have been described by workers interested in triphenylmethane dyes. The fuchsones have been synthesized by the sulfuric acid condensation of benzilic acid and appropriate phenol1, by dehydration of 4-hydroxytriphenylcarbinol2, by oxidation 4-hydroxytri-phenylmethane and by photochemically induced reactions benzophenones with 2,6-dialkylphenols4.  相似文献   
100.
The earlier reported matrix system methylacetate/ H2O/Ar has been reinvestigated by IR spectroscopy. The complex band pattern of the ester ν c=0 and the water ν3, ν1 and ν2 modes can be explained by the coexistence of 1:1, linear 1:2 and linear 2:1 H-bonded complexes. The study of methyl benzoate/H2O/Ar supports the proposed interpretation.  相似文献   
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