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41.
Long-Mei Zeng Xiong Fu Jing-Yu Su Florecita De Guzman J. Francis Schmitz M. Bilayet Hossain Dick van Der Helm 《中国化学》1991,9(2):136-143
Three pyrrololactam alkaloids have been isolated from the marine sponge Phacellia fusca Schmidt collected from the South China Sea, and their structures were determined as 1–3 , on the grounds of spectral data. This is the first report of these compounds from this sponge. The structure of 1 was confirmed by X-ray analysis. 相似文献
42.
Arjan J. H. Louter Philo A. Jones J. David Jorritsma Jolan J. Vreuls Udo A. Th. Brinkman 《Journal of separation science》1997,20(7):363-368
An automated system for derivaatization was coupled on-line with solid-phase extraction-gas-chromatography (SPE-GC). The system was optimized for the determination of phenol and chlorinated phenols in aqueous samples. The test analytes were acetylated with acetic anhydride; proper buffering of the sample was a critical factor. Next, the phenol acetates were enriched on a SPE cartridge and transferred to a GC; two appraoaches were studied. In the first approach, the derivatives were enriched on disposable C18 cartridges (ASPEC type) and desorbed with methylacetate. Aan aliquot of the final eluate was injected on-line the GC by means of a loop-type interface. In the second approach, trace enrichment was performed on 10 × 2 mm i.d. LC-type precolumn packed with polystyrenedivinylbenzene copolymer (PLRP-S) this precolumn was dried with a mitrogen purge and the phenol acetates were desorbed with ethyl acetate which was injectedon-line into the retention gap of the GC under partially concurrent solvent evaporation (PCSE) conditions. The Derivatization-SPE-GC system which was based on the loop-type interface has the advantage of simplicity and easy operation, the main drawback is the impossibility to determine phenol acetates which elute prior to trichlorophenol acetates. With the derivatization-SPE-GC approach using PCSE-based desorption, even the most volatile analyte of the test series, phenol acetate, can be determined successfully. The entire procedure, including the derivatization step, was fully automated and integrated in one set-up. The precision data for the integrated on-line derivatization-SP-FID system were fully satisfactory, with RSD values of 1–12 % at the 1 μg/1 level. When a sample volume of 2.2 ml was analyzed, The detection limits for the chlorinated phenol acetates were in the 0.1–0.3 μg/1 range. 相似文献
43.
Summary A microwave coherent backscattering experiment has been carried out on Mirabelle, a weakly ionised plasma device, with the
objective of measuring the electron density fluctuation level. The experiment is a preliminary step in order to prepare the
detection system for a microwave stimulated backscattering experiment. The incident electromagnetic wave is focused in front
of a plane grid which excites ion acoustic or electron Bernstein waves inducing fluctuations in the plasma. The backscattering
signal is collected by the launching circuit and detected by homodyne mixing. The typical ratio of the scattered power to
the incident power is about 10−12 and the relative density fluctuations are of the order of δn
e/n
e=10−3 against a background electron density ofn
e=1–5·109 cm−3. The backscattering measurement is compared with Langmuir probe measurements. The spectral width of the backscattered signal
has also been studied, by taking into account effects due to the incident wave focusing and plasma wave damping.
The authors of this paper have agreed to not receive the proofs for correction 相似文献
44.
Electrostatic spring softening is an important characteristic of electrostatically actuated dual-axis micromirror, since it lowers the resonant frequencies. This paper presents an approach based on approximating the electrostatic forces by the first-order Taylor's series expansion to investigate this characteristic. The dual-axis micromirror studied in this paper has three motion modes, two torsional (about x- and y-axis, respectively) and one translational (about z-axis). The stiffnesses of all these modes are softened by a DC bias voltage applied to the mirror plate. The resonant frequencies are lowered with the increment of the bias voltage. The relationship of the bias voltage and the resonant frequencies of all the motion modes is derived. The analytical results show that the resonant frequency curves are affected by the capacitor geometries, i.e. the gap between the mirror plate and the electrodes and the electrodes size. The lowering curves drop slowly when the bias voltage is small. While for large bias voltage, the lowering curves drop rapidly. The experiment results are consistent with those obtained by the analytical approach. 相似文献
45.
Kinetic studies of PET glycolysis by diethylene glycol (DEG), dipropylene glycol (DPG), glycerol (Gly) and mixtures of these glycols have shown, in a previous study, that the order of reactivity of the glycols differs according to the conditions of temperature and catalysis. Indeed, their global reactivity depends both on their chemical reactivity and physico-chemical properties.Glycolysis of model polyesters which are liquid at the reaction temperature, which allows us to overcome the problem of the polyesters' solubility, were studied to compare the chemical reactivity of these glycols. Three oligoesters were synthesized from dimethyl terephthalate and three different glycols namely triethylene glycol, ethylene glycol and hexanediol to form, respectively, PE3T, OET and PTHD.Results showed that the order of reactivity of the glycols is the same for PET, OET and PTHD but different for PE3T. Indeed, DPG without catalyst has a particular and unexpected behaviour: its reactivity seems to be strongly influenced by the presence of oxygen atoms in the chain. 相似文献
46.
We present anO(p · n) algorithm for the problem of finding disjoint simple paths of minimum total length betweenp given pairs of terminals on oriented partial 2-trees withn nodes and positive or negative arc lengths. The algorithm is inO(n) if all terminals are distinct nodes. We characterize the convex hull of the feasible solution set for the casep=2.We gratefully acknowledge the referee's many helpful suggestions to improve the presentation of this paper. 相似文献
47.
Th. Mühge Yu. V. Goryunov K. Theis-Bröhl K. Westerholt H. Zabel I. A. Garifullin 《Applied magnetic resonance》1998,14(4):567-582
Magnetic and superconducting properties of Fe/Nb epitaxial bilayers have been studied. Single crystal Fe/Nb (110) bilayers with a Nb thicknessd Nb in the range from 250 to 650 Å and with a Fe thicknessd Fe in the range from 7 to 27 Å were prepared using molecular beam epitaxy techniques. Magnetization measurements showed the existence of a magnetically “dead” Fe-interface layer with a thicknessd NM varying strongly with minor modifications of the growth conditions. For bilayers with a small magnetic layer thicknessd M and a smalld NM the FMR measurements revealed an anomalous decrease of the effective magnetization 4πM eff of the ferromagnetic Fe layer below the superconducting transition temperatureT c. The absolute change of 4πM eff belowT c depends strongly on the actual values ofd M andd NM: upon decreasing bothd M andd NM the effect increases considerably. As a possible mechanism for the anomalous temperature dependence of 4πM eff belowT c we discuss a spatial modulation of ferromagnetic order due to a modification of the RKKY inter-action in the superconducting state. 相似文献
48.
49.
Th. Brückel Y. Chernenkov B. Dorner V. P. Plakhty O. P. Smirnov 《Zeitschrift für Physik B Condensed Matter》1990,79(3):389-395
We have measured the spin wave spectrum for the garnet Ca3Cr2Ge3O12 by means of inelastic neutron scattering. The data can be well described in the framework of linear spin wave theory if we assume a Heisenberg model with two exchange parameters up to the next nearest neighbours (J
1 andJ
2) and a staggered anisotropy field (A). A least squares fit to the observed dispersion relations yield the following values for these parameters: J
1=–0.582(8)K,J
2=0.416(4)K,A=0.25(8)K. Although symmetry requires that two nearest neighbour exchange constantsJ
1 andJ
1
'
must be distinguished, only the average J
1=(J
1+3J
1
'
)/4 and the condition –0.35 K <J
1=J
1-J
1
'
<0.50 K could be deduced from the experiment. The most striking result is the positive value ofJ
2. We discuss the implications for an understanding of superexchange mediated by more than one oxygen atom. In an extension of the conventional analysis we have calculated the integrated intensities in order to check the eigenvectors directly. Good agreement between observed and calculated intensities was obtained. 相似文献
50.