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971.
New Pd(II) and Pt(II) 3,6-bis(2′-pyridyl)pyridazine (dppn) mononuclear complexes of the type M(dppn)Cl2 were prepared and characterized. From M(dppn)Cl2, the bimetallic homonuclear complexes M(dppn)MCl4 were prepared by reaction with Pd(PhCN)2Cl2 or K2PtCl4. Bimetallic heteronuclear species of the type M(dppn)M′Cl4, were prepared reacting the mononuclear complexes with the stoichiometric amount of M′Cl2 (M′ = Cu, Co, Ni). All the described reaction give product in high yield. The isolated compounds, almost completely insoluble in most organic solvents, were characterized by elemental analysis, IR, ESR, reflectance spectra, and magnetic moment measurements. On the basis of these data the geometries around the metals are discussed. 相似文献
972.
In 1979 Kazhdan and Lusztig defined, for every Coxeter group W, a family of polynomials, indexed by pairs of elements of W, which have become known as the Kazhdan-Lusztig polynomials of W, and which have proven to be of importance in several areas of mathematics. In this paper, we show that the combinatorial concept of a special matching plays a fundamental role in the computation of these polynomials. Our results also imply, and generalize, the recent one in [Adv. in Math. 180 (2003) 146-175] on the combinatorial invariance of Kazhdan-Lusztig polynomials. 相似文献
973.
Combinatorial Expansions of Kazhdan-Lusztig Polynomials 总被引:2,自引:0,他引:2
We introduce two related families of polynomials, easily computableby simple recursions into which any KazhdanLusztig (andinverse KazhdanLusztig) polynomial of any Coxeter groupcan be expanded linearly, and we give combinatorial interpretationsto the coefficients in these expansions. This yields a combinatorialrule for computing the KazhdanLusztig polynomials interms of paths in a directed graph, and a completely combinatorialreformulation of the nonnegativity conjecture [15, p. 166]. 相似文献
974.
Properties of blends of semicrystalline perfluoropolymers in fluoroelastomers strongly depend on the size of the dispersed phase and are at the best when dispersed phase dimension is well below 0.1 μm, i.e. in the nano-scale region. This fine dispersion is obtained with an innovative mixing technology based on microemulsion polymerization. Further increase of properties can be obtained by generating chemical links between fluoroelastomer and semicrystalline fluoropolymer. Nano-blends combine the performing properties of fluoroelastomers with those of semicrystalline perfluoropolymers. For example, these nano-blends have at the same time the sealing and mechanical properties of fluoroelastomers and the exceptional thermal and chemical resistance, low permeability and low friction coefficient of semicrystalline perfluoropolymers. In addition, as dispersed phase size is below visible light wavelength, finished items made with these nano-blends are optically transparent even when they contain as much as 40 wt.% of semicrystalline perfluoropolymer. 相似文献
975.
976.
Girolamo Cirrincione Anna Maria Almerico Gaetano Dattolo Enrico Aiello Patrizia Diana Francesco Mingoia 《Journal of heterocyclic chemistry》1992,29(5):1309-1312
Rearrangement under acidic conditions of the pyrrolylbenzotriazinone 7 afforded the pyrrolylbenzamides 10 and 11 . By thermal rearrangement instead, the first fully aromatic derivative of the pyrrolo[3,4-c]isoquinoline ring system 9 was obtained. 相似文献
977.
Riccardo d'Agostino Francesco Cramarossa Santolo De Benedictis 《Plasma Chemistry and Plasma Processing》1984,4(1):21-31
Discharges fed with C3F8-H2 mixtures have been studied by means of mass spectrometry in a tubular reactor operated at 0.5 torr and 50 W. Comparison of the results with those obtained with emission actinometry give additional evidence that emission actinometry and mass spectrometry are powerful diagnostic tools to monitor stable and unstable species in discharges utilized for dry etching and polymer depositions. Mechanisms for end product formation and polymer deposition are also discussed. 相似文献
978.
Using simple known methods and results of classical perturbation theory, especially those due to Nekhoroshev and Neishtadt, we study the energy exchanges between the rotational and the translational degrees of freedom in a particular model representing the planar motion of a rigid body in a bounded analytic potential. We prove that, if the angular velocity is initially large, then the energy exchanges are small,O(
–1), for times growing exponentially with, |t|exp. We also deduce that in a scattering process from a (smooth) potential barrier, the overall change in the rotational energy of the incoming body is exponentially small in, exp(–. The results are interpreted in the light of an old conjecture by Boltzmann and Jeans on the existence of very large time scales for equilibrium in statistical systems containing high-frequency degrees of freedom (purely classical freezing of the high-frequency degrees of freedom); the rotating object is, in this interpretation, a (classical) molecule, which moves in an external field, or collides with the wall of a container. Two different limits of large are considered, namely the limit of large rotational energy, and (as is interesting for the molecular interpretation) the limit of point mass, at finite rotational energy. 相似文献
979.
Joshua Avossa Francesco Branda Francesco Marulo Giuseppe Petrone Stefano Guido Giovanna Tomaiuolo Aniello Costantini 《高分子科学》2018,36(12):1368-1374
Light polymeric soundproofing materials(density = 63 kg/m~3) of interest for the transportation industry were fabricated through electrospinning. Blankets of electrospun polyvinylpyrrolidone(average fiber diameter =(1.6 ± 0.5) or(2.8 ± 0.5) μm) were obtained by stacking disks of electrospun mats. The sound absorption coefficients were measured using the impedance tube instrument based on ASTM E1050 and ISO 10534-2. For a given set of disks(from a minimum of 6) the sound absorption coefficient changed with the frequency(in the range 200–1600 Hz) following a bell shape curve with a maximum(where the coefficient is greater than 0.9) that shifts to lower frequencies at higher piled disks number and greater fiber diameter. This work showed that electrospinning produced sound absorbers with reduced thickness(2–3 cm) and excellent sound-absorption properties in the low and medium frequency range. 相似文献
980.
Francesco Carulli Wojciech Mróz Elisa Lassi Cristina Sandionigi Benedetta Squeo Lorenzo Meazza Guido Scavia Silvia Luzzati Mariacecila Pasini Umberto Giovanella Francesco Galeotti 《Chemical Papers》2018,72(7):1753-1759
Interfacial engineering provides an important tool for optimizing the performances of optoelectronic devices. We show that poly[(2,7-(9,9′-dioctyl)fluorene)-alt-(2,7-(9,9′-bis(5″-trimethylammonium bromide)pentyl)fluorene)])], an alcohol-soluble π-conjugated polymer based on polyfluorene backbone and ammonium groups on the alkyl side chains, is capable of modifying the interface between the organic layer and the metal cathode in both organic solar cells and light-emitting diodes based on commercial materials and conventional architectures, improving their performances. The introduction of the cathode interlayer enhances the efficiency of a red-emitting phosphorescent OLED by 15% and decreases its turn-on voltage. The same polymer improves the power conversion efficiency of a PTB7/PC71BM solar cell by 55% and shows a beneficial effect in terms of device stability. 相似文献