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31.
Giovanni Cerioni Costantino Floris Giaime Marongiu Gabriele Navarra Francesca Sotgiu 《Journal of heterocyclic chemistry》1994,31(5):1151-1155
1-5-benzoxathiepine compounds are a novel class of heterocyclic rings that present interesting properties as central nervous system depressants. With the aim to contribute to the elucidation of the structure-activity relationship of this class of compounds we report a structural study of the 3-hydroxy-1,5-benzoxathiepine both in solution and in the solid state. Studies by dynamic 13C-nmr in solution show that three conformations are possible for the oxathiepin ring. A unique chair conformation characterizes the atoms in the oxathiepine ring of the crystallized molecule. The crystal structure was solved by direct methods. Values of bond distances and angles are within the expected range. 相似文献
32.
We use boundary value methods to compute consistent initial values for fully implicit nonlinear differential-algebraic equations.
The obtained algorithm uses variable order formulae and a deferred correction technique to evaluate the error. A rigorous
theory is stated for nonlinear index 1, 2 and 3 DAEs of Hessenberg form. Numerical tests on classical index 1, 2 and 3 DAE
problems are reported.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
33.
Fabiana Quaglia Giuseppe Fusco Giuseppe De Rosa Francesca Ungaro Agnese Miro Maria Immacolata La Rotonda 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):669-674
The aim of this work was to produce lycopene-containing powders from tomato products by a solvent-free method making use of
β-cyclodextrin (βCD). Powders were prepared by spray-drying a tomato concentrate (TC), one of the most bioavailable form of
lycopene, after mechanical treatment with βCD in different weight ratios. The obtained product was centrifuged to eliminate
partly food matrix and characterized for the amount of lycopene hydrodispersed/hydrosolubilized in the aqueous fraction. The
chemical antioxidant activity of sera was evaluated too. Powders obtained by spray-drying sera exhibited good flow properties,
a lycopene content between 0.4 and 1.09 mg/g and excellent water dispersability. The process developed, which makes use of
βCD for the treatment of tomato products, turns to be of great interest to obtain a bulk material for nutraceuticals displaying
superior biovailability of lycopene. 相似文献
34.
Cory J. Hill Baohua Yang Rui Q. Yang 《Physica E: Low-dimensional Systems and Nanostructures》2004,20(3-4):486
Mid-IR type-II interband cascade lasers were demonstrated in pulsed mode at temperatures up to 325 K and in continuous mode up to 200 K. At 80 K, the threshold current density was 8.9 A/cm2 and a continuous wave output power of 140 mW/facet was obtained. 相似文献
35.
文献[1]引入一类具有广泛应用前景的随机过程-Markov骨架过程。借助Markov骨架过程的方法研究GI/G/1单重休假服务系统队长,及t时刻到达顾客等待时间的瞬时概率分布。 相似文献
36.
We demonstrate a 511 W laser diode pumped composite Nd:YAG ceramic laser. The optical pumping system is consisted of five laser diode stacked arrays arranged in a pentagonal shape around the ceramic rod whose size is φ6.35×144mm. When the pumping power is 1600 W, the cw laser output up to 511 W at 1064nm can be obtained with a linear piano-piano cavity, and the optical-to-optical efficiency is 31.9%. To our knowledge, this is the highest value of laser output by using a newly invented composite Nd:YAG ceramic rod as the gain medium. 相似文献
37.
It is well known that the non-stationary wideband noise is the most difficult to be removed in speech enhancement. In this paper a novel speech enhancement algorithm based on the dyadic wavelet transform and the simplified Karhunen-Loeve transform (KLT) is proposed to suppress the non-stationary wideband noise. The noisy speech is decomposed into components by the wavelet space and KLT-based vector space, and the components are processed and reconstructed, respectively, by distinguishing between voiced speech and unvoiced speech. There are no requirements of noise whitening and SNR pre-calculating. In order to evaluate the performance of this algorithm in more detail, a three-dimensional spectral distortion measure is introduced. Experiments and comparison between different speech enhancement systems by means of the distortion measure show that the proposed method has no drawbacks existing in the previous methods and performs better shaping and suppressing of the non-stationary wideband noise for speech enhancement. 相似文献
38.
An enantioselective Michael addition of malonate to nitroalkenes is efficiently catalyzed by low loading demethylquinine salts in water; the yield range from 49% to 93% and the ee up to 90%. 相似文献
39.
Hebing Rui 《Proceedings of the American Mathematical Society》2006,134(10):2873-2880
In this note, we use generalized Tchebychev polynomials to define a trace function which satisfies certain conditions. Such a trace will be called the Markov trace. In particular, we obtain formulae for the weights of the Markov trace. As a corollary, we get a combinatorial identity. This generalizes Jones's 1983 result on Temperley-Lieb algebras.
40.
Wei‐Lie Xiao Jian‐Xin Pu Rui‐Rui Wang Liu‐Meng Yang Xiao‐Li Li Sheng‐Hong Li Rong‐Tao Li Sheng‐Xiong Huang Yong‐Tang Zheng Han‐Dong Sun 《Helvetica chimica acta》2007,90(8):1505-1513
Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1. 相似文献