Energetic and structural characterization of 2‐R‐3‐methylquinoxaline‐1,4‐dioxides (R = benzoyl or tert‐butoxycarbonyl): experimental and computational studies

The gaseous standard molar enthalpies of formation of two 2‐R‐3‐methylquinoxaline‐1,4‐dioxides (R = benzoyl or tert‐butoxycarbonyl), at T = 298.15 K, were derived using the values for the enthalpies of formation of the compounds in the condensed phase, measured by static bomb combustion calorimetry, and for the enthalpies of sublimation, measured by Knudsen effusion, using a quartz crystal oscillator. The three dimensional structure of 2‐tert‐butoxycarbonyl‐3‐methylquinoxaline‐1,4‐dioxide has been obtained by X‐ray crystallography showing that the two N? O bond lengths in this compound are identical. The experimentally determined geometry in the crystal is similar to that obtained in the gas‐phase after computations performed at the B3LYP/6‐311 + G(2d,2p) level of theory. The experimental and computational results reported allow to extend the discussion about the influence of the molecular structure on the dissociation enthalpy of the N? O bonds for quinoxaline 1,4‐dioxide derivatives. As found previously, similar N? O bond lengths in quinoxaline‐1,4‐dioxide compounds are not linked with N? O bonds having the same strength. Copyright © 2007 John Wiley & Sons, Ltd.     

The unfair consequences of equal opportunities: Comparing exchange models of wealth distribution

Simple agent based exchange models are a commonplace in the study of wealth distribution of artificial societies. Generally, each agent is characterized by its wealth and by a risk-aversion factor, and random exchanges between agents allow for a redistribution of the wealth. However, the detailed influence of the amount of capital exchanged has not been fully analyzed yet. Here we present a comparison of two exchange rules and also a systematic study of the time evolution of the wealth distribution, its functional dependence, the Gini coefficient and time correlation functions. In many cases a stable state is attained, but, interesting, some particular cases are found in which a very slow dynamics develops. Finally, we observe that the time evolution and the final wealth distribution are strongly dependent on the exchange rules in a nontrivial way.     

Compact three-dimensional camera for robot and vehicle guidance

A very compact 3-D range sensor for robot and vehicle guidance is described. A dual aperture mask in a camera lens is used to transform a small commercially available CCD video camera into a ranging sensor. An active system using a projected laser beam provides a 360° range map which can be used to plan trajectories, either for robots or autonomous vehicles. Good quality panoramic intensity and 3-D images were obtained. Accuracy, speed of acquisition, and cost are discussed. Experimental results are presented.     

The Mean-Field Limit for a Regularized Vlasov-Maxwell Dynamics

The present work establishes the mean-field limit of a N-particle system towards a regularized variant of the relativistic Vlasov-Maxwell system, following the work of Braun-Hepp [Commun Math Phys 56:101–113, 1977] and Dobrushin [Func Anal Appl 13:115–123, 1979] for the Vlasov-Poisson system. The main ingredients in the analysis of this system are (a) a kinetic formulation of the Maxwell equations in terms of a distribution of electromagnetic potential in the momentum variable, (b) a regularization procedure for which an analogue of the total energy—i.e. the kinetic energy of the particles plus the energy of the electromagnetic field—is conserved and (c) an analogue of Dobrushin’s stability estimate for the Monge-Kantorovich-Rubinstein distance between two solutions of the regularized Vlasov-Poisson dynamics adapted to retarded potentials.     

Differentiation of aminomethyl corrole isomers by mass spectrometry

Two new isomeric aminomethyl corrole derivatives of [5,10,15-tris(pentafluorophenyl)corrolato]gallium(III) were synthesized with pyridine (py) molecules as axial ligands. When investigated by electrospray ionization mass spectrometry, in the positive and the negative ion modes, these compounds showed an unusual gas-phase behavior that could be used for their differentiation. In the positive ion mode, the differentiation was achieved through the formation of diagnostic fragment ions formed from [M-py?+?H](+) precursors, by (CH(3) )(2) NH and HF losses. An unusual addition of water to the main fragment ions provides an alternative route for isomer identification. Semi-empirical calculations were performed to elucidate the structures and stabilities of the main ionic species formed in the positive ion mode. In the negative ion mode isomer discrimination is accomplished via the fragmentation of the methoxide adduct ions [M-py?+?CH(3) O](-) through (CH(3) )(2) N(.) and HF losses.     

Observation and properties of the orbitally excited B_(s2)(*) meson

We report the direct observation of the excited L=1 state B_(s2)(*) in fully reconstructed decays to B+K-. The mass of the B_(s2)(*) meson is measured to be 5839.6+/-1.1(stat)+/-0.7(syst) MeV/c(2), and its production rate relative to the B+ meson is measured to be [1.15+/-0.23(stat)+/-0.13(syst)]%.     

Dynamics of atom-field entanglement in a bimodal cavity

In this paper we investigate some aspects of the dynamics and entanglement of bipartite quantum system (atom-quantized field), coupled to a third “external” subsystem (quantized field). We make use of the Raman coupled model; a three-level atom in a lambda configuration interacting with two modes of the quantized cavity field. We consider the far off resonance limit, which allows the derivation of an effective Hamiltonian of a two-level atom coupled to the fields. We also make a comparison with the situation in which one of the modes is treated classically rather than prepared in a quantum field (coherent state).     

K-Dependence and temperature dependence of N2-, H2-, and He-broadening coefficients for the J = 12-11 transition of acetonitrile CH3CN located near 220.7 GHz

Extensive experiments on the K = 3 component of the J = 12-11 rotational transition of acetonitrile CH₃C¹⁴N, located near 220.7 GHz, were performed at different temperatures in the range 235-350 K. They allow determining the N₂-, H₂-, and He-broadening coefficients, as well as their temperature dependences. More specific measurements on all the K-components of the involved transition perturbed by N₂ at 303 K allow to point out a clear decreasing of the broadening coefficient with increasing K. Narrowing effects are clearly observed, and experimental lines were analysed both with Voigt and speed dependent Voigt profiles; but no exhaustive lineshape study was carried out. All the experimental parameters are compared with results derived from a semiclassical calculation of collisional interactions, including electrostatic, induction, and dispersion energy contributions.