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91.
We study models of continuous time, symmetric, ℤd-valued random walks in random environments. One of our aims is to derive estimates on the decay of transition probabilities in a case where a uniform ellipticity assumption is absent. We consider the case of independent conductances with a polynomial tail near 0 and obtain precise asymptotics for the annealed return probability and convergence times for the random walk confined to a finite box.  相似文献   
92.
We study the threshold θ ≥ 2 contact process on a homogeneous tree of degree κ = b + 1, with infection parameter λ ≥ 0 and started from a product measure with density p. The corresponding mean-field model displays a discontinuous transition at a critical point and for it survives iff , where this critical density satisfies , . For large b, we show that the process on has a qualitatively similar behavior when λ is small, including the behavior at and close to the critical point . In contrast, for large λ the behavior of the process on is qualitatively distinct from that of the mean-field model in that the critical density has . We also show that , where 1 < Φ2 < Φ3 < ..., , and . The work of L.R.F. was partially supported by the Brazilian CNPq through grants 307978/2004-4 and 475833/2003-1, and by FAPESP through grant 04/07276-2. The work of R.H.S. was partially supported by the American N.S.F. through grant DMS-0300672.  相似文献   
93.
We review the 5th non-LTE kinetics code comparison workshop, held in November 2007. Both steady-state and time-dependent cases for elements ranging from carbon to gold were examined in detail. Calculations of radiative power losses and specific spectra were requested in addition to typical plasma quantities such as the ionization balance. Non-Maxwellian electrons, external Planckian radiation and opacity effects in spectra were also included in the comparisons. We discuss the organization of the workshop and present a set of representative results. The particular case of a tungsten plasma at tokamak operating densities was considered for the first time. Due to its importance to the ITER project, more detailed results of these comparisons will be published elsewhere.  相似文献   
94.
In this work, we address investment decisions in production systems by using real options. As is standard in literature, the stochastic variable is assumed to be normally distributed and then approximated by a binomial distribution, resulting in a binomial lattice. The methodology establishes a discrete-valued lattice of possible future values of the underlying stochastic variable (demand in our case) and then, computes the project value. We have developed and implemented stochastic dynamic programming models both for fixed and flexible capacity systems. In the former case, we consider three standard options: the option to postpone investment, the option to abandon investment, and the option to temporarily shut-down production. For the latter case, we introduce the option of corrective action, in terms of production capacity, that the management can take during the project by considering the existence of one of the following: (i) a capacity expansion option; (ii) a capacity contraction option; or (iii) an option considering both expansion and contraction. The full flexible capacity model, where both the contraction and expansion options exist, leads, as expected, to a better project predicted value and thus, investment policy. However, we have also found that the capacity strategy obtained from the flexible capacity model, when applied to specific demand data series, often does not lead to a better investment decision. This might seem surprising, at first, but it can be explained by the inaccuracy of the binomial model. The binomial model tends to undervalue future decreases in the stochastic variable (demand), while at the same time tending to overvalue an increase in future demand values.  相似文献   
95.
The main objective of this paper was to characterize the voltammetric profiles of the Pt/C,Pt/C-ATO,Pd/C and Pd/CATO electrocatalysts and study their catalytic activities for methane oxidation in an acidic electrolyte at 25 ℃ and in a direct methane proton exchange membrane fuel cell at 80 ℃. The electrocatalysts prepared also were characterized by X-ray diffraction( XRD) and transmission electron microscopy( TEM). The diffractograms of the Pt/C and Pt/C-ATO electrocatalysts show four peaks associated with Pt face-centered cubic( fcc) structure,and the diffractograms of Pd/C and Pd/C-ATO show four peaks associated with Pd face-centered cubic( fcc) structure. For Pt/C-ATO and Pd/C-ATO,characteristic peaks of cassiterite( SnO_2) phase are observed,which are associated with Sb-doped SnO_2( ATO) used as supports for electrocatalysts. Cyclic voltammograms( CV) of all electrocatalysts after adsorption of methane show that there is a current increase during the anodic scan. However,this effect is more pronounced for Pt/C-ATO and Pd/C-ATO. This process is related to the oxidation of the adsorbed species through the bifunctional mechanism,where ATO provides oxygenated species for the oxidation of CO or HCO intermediates adsorbed in Pt or Pd sites. From in situ ATR-FTIR( Attenuated Total Reflectance-Fourier Transform Infrared) experiments for all electrocatalysts prepared the formation of HCO or CO intermediates are observed,which indicates the production of carbon dioxide. Polarization curves at 80 ℃in a direct methane fuel cell( DMEFC) show that Pd/C and Pt/C electroacatalysts have superior performance to Pd/C-ATO and Pt/C-ATO in methane oxidation.  相似文献   
96.
We consider the Ising model on \(\mathbb Z\times \mathbb Z\) where on each horizontal line \(\{(x,i), x\in \mathbb Z\}\) , called “layer”, the interaction is given by a ferromagnetic Kac potential with coupling strength \(J_{ \gamma }(x,y)={ \gamma }J({ \gamma }(x-y))\) , where \(J(\cdot )\) is smooth and has compact support; we then add a nearest neighbor ferromagnetic vertical interaction of strength \({ \gamma }^{A}\) , where \(A\ge 2\) is fixed, and prove that for any \(\beta \) larger than the mean field critical value there is a phase transition for all \({ \gamma }\) small enough.  相似文献   
97.
We study a class of continuous time Markov processes, which describes ± 1 spin flip dynamics on the hypercubic latticeℤ d , d≥ 2, with initial spin configurations chosen according to the Bernoulli product measure with density p of spins + 1. During the evolution the spin at each site flips at rate c= 0, or 0 < α≤ 1, or 1, depending on whether, respectively, a majority of spins of nearest neighbors to this site exists and agrees with the value of the spin at the given site, or does not exist (there is a tie), or exists and disagrees with the value of the spin at the given site. These dynamics correspond to various stochastic Ising models at 0 temperature, for the Hamiltonian with uniform ferromagnetic interaction between nearest neighbors. In case α= 1, the dynamics is also a threshold voter model. We show that if p is sufficiently close to 1, then the system fixates in the sense that for almost every realization of the initial configuration and dynamical evolution, each site flips only finitely many times, reaching eventually the state + 1. Moreover, we show that in this case the probability q(t) that a given spin is in state − 1 at time t satisfies the bound: for arbitrary ɛ > 0, q(t) ≤ exp(−t (1/ d ) −ɛ), for large t. In d= 2 we obtain the complementary bound: for arbitrary ɛ > 0, q(t) ≥ exp(−t (1/2) +ɛ), for large t. Received: 12 July 2001 / Accepted: 1 February 2002  相似文献   
98.
Conformational and thermal behavior of self-assembled structures of three phosphonic acids, OPA (octadecylphosphonic acid), TPA (tetradecylphosphonic acid), and OcPA (octylphosphonic acid), with different alkyl chain lengths are investigated and compared. The orientation of self-assembled bilayers depends on whether the substrate is nonpolar (graphite) or polar (mica). For nonpolar substrates, bilayers lay parallel to the surface, and for polar substrates, bilayers lay perpendicular to the surface. Thermal behaviors of these structures on mica and graphite are also investigated, showing that, depending on the temperature they are submitted to, molecules stack, unstack, or agglomerate on mica and form larger domains on graphite.  相似文献   
99.
100.
Alumina nanotube was synthesized by hydrolysis of aluminum isopropoxide followed by gelation and drying under hypercritical condition. The influence of temperature on the structural, textural, and morphological properties of the material was studied by powder X-ray diffraction, infrared spectroscopy, nitrogen adsorption, thermal analysis, scanning and transmission electronic microscopy. The as-prepared alumina (300°C) was formed by boehmite crystallites. Its structure collapsed after heating (500–1200 °C) yielding γ, δ and θ alumina nanophases. The aerogel surface area changed from 254 to 99 m2 g−1 in this heating range. The formation of alumina nanotubes was verified by transmission microscopy analysis at the heating range.  相似文献   
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