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71.
72.
Suellen Christtine da Costa Sanches Flávio de Vasconcelos Carlos Emmerson Ferreira da Costa Patrícia Santana Barbosa Marinho Marcos R. Guilherme Eraldo José Madureira Tavares José Antônio Picanço Diniz Júnior José Otávio Carréra Silva Júnior Roseane Maria Ribeiro-Costa 《Journal of Thermal Analysis and Calorimetry》2015,120(1):991-999
73.
Rolff Ferreira Spindola Hudson Zanin Cleidivan Silva Macena André Contin Rita de Cássia Silva Luz Flávio Santos Damos 《Journal of Solid State Electrochemistry》2017,21(4):1089-1099
A novel platform for electroanalysis of isoniazid based on graphene-functionalized multi-walled carbon nanotube as support for iron phthalocyanine (FePc/f-MWCNT) has been developed. The FePc/f-MWCNT composite has been dropped on glassy carbon forming FePc/f-MWCNT/GC electrode, which is sensible for isoniazid, decreasing substantially its oxidation potential to +200 mV vs Ag/AgCl. Electrochemical and electroanalytical properties of the FePc/f-MWCNT/GC-modified electrode were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, scanning electrochemical microscopy, and amperometry. The sensor presents better performance in 0.1 mol L?1 phosphate buffer at pH 7.4. Under optimized conditions, a linear response range from 5 to 476 μmol L?1 was obtained with a limit of detection and sensitivity of 0.56 μmol L?1 and 0.023 μA L μmol?1, respectively. The relative standard deviation for 10 determinations of 100 μmol L?1 isoniazid was 2.5%. The sensor was successfully applied for isoniazid selective determination in simulated body fluids. 相似文献
74.
Thierry Cazenave Flávio Dickstein Fred B. Weissler 《Journal of Dynamics and Differential Equations》2007,19(3):789-818
In this paper, we construct solutions u(t,x) of the heat equation on such that has nontrivial limit points in as t → ∞ for certain values of μ > 0 and β > 1/2. We also show the existence of solutions of this type for nonlinear heat equations.
相似文献
75.
X. Fabian F. Mauger G. Quéméner Ph. Velten G. Ban C. Couratin P. Delahaye D. Durand B. Fabre P. Finlay X. Fléchard E. Liénard A. Méry O. Naviliat-Cuncic B. Pons T. Porobic N. Severijns J. C. Thomas 《Hyperfine Interactions》2015,232(1-3):87-95
We performed classical molecular dynamics (MD) simulations in order to search the conditions for efficient sympathetic cooling of highly charged ions (HCIs) in a linear Paul trap. Small two-component ion Coulomb crystals consisting of laser-cooled ions and HCIs were characterized by the results of the MD simulations. We found that the spatial distribution is determined by not only the charge-to-mass ratio but also the space charge effect. Moreover, the simulation results suggest that the temperature of HCIs do not necessarily decrease with increasing the number of laser-cooled ions in the cases of linear ion crystals. We also determined the cooling limit of sympathetically cooled 165Ho14+ ions in small linear ion Coulomb crystals. The present results show that sub-milli-Kelvin temperatures of at least 10 Ho14+ ions will be achieved by sympathetic cooling with a single laser-cooled Be+. 相似文献
76.
E. Liénard G. Ban C. Couratin P. Delahaye D. Durand X. Fabian B. Fabre X. Fléchard P. Finlay F. Mauger A. Méry O. Naviliat-Cuncic B. Pons T. Porobic G. Quéméner N. Severijns J. C. Thomas Ph. Velten 《Hyperfine Interactions》2015,234(1-3):1-7
The experimental achievements and the results obtained so far with the LPCTrap device installed at GANIL are presented. The apparatus is dedicated to the study of the weak interaction at low energy by means of precise measurements of the β ? ν angular correlation parameter in nuclear β decays. So far, the data collected with three isotopes have enabled to determine, for the first time, the charge state distributions of the recoiling ions, induced by shakeoff process. The analysis is presently refined to deduce the correlation parameters, with the potential of improving both the constraint deduced at low energy on exotic tensor currents (6He1+) and the precision on the V u d element of the quark-mixing matrix (35Ar1+ and 19Ne1+) deduced from the mirror transitions dataset. 相似文献
77.
Evaluation of grinding methods for pellets preparation aiming at the analysis of plant materials by laser induced breakdown spectrometry 总被引:1,自引:0,他引:1
It has been demonstrated that laser induced breakdown spectrometry (LIBS) can be used as an alternative method for the determination of macro (P, K, Ca, Mg) and micronutrients (B, Fe, Cu, Mn, Zn) in pellets of plant materials. However, information is required regarding the sample preparation for plant analysis by LIBS. In this work, methods involving cryogenic grinding and planetary ball milling were evaluated for leaves comminution before pellets preparation. The particle sizes were associated to chemical sample properties such as fiber and cellulose contents, as well as to pellets porosity and density. The pellets were ablated at 30 different sites by applying 25 laser pulses per site (Nd:YAG@1064 nm, 5 ns, 10 Hz, 25 J cm−2). The plasma emission collected by lenses was directed through an optical fiber towards a high resolution echelle spectrometer equipped with an ICCD. Delay time and integration time gate were fixed at 2.0 and 4.5 μs, respectively. Experiments carried out with pellets of sugarcane, orange tree and soy leaves showed a significant effect of the plant species for choosing the most appropriate grinding conditions. By using ball milling with agate materials, 20 min grinding for orange tree and soy, and 60 min for sugarcane leaves led to particle size distributions generally lower than 75 μm. Cryogenic grinding yielded similar particle size distributions after 10 min for orange tree, 20 min for soy and 30 min for sugarcane leaves. There was up to 50% emission signal enhancement on LIBS measurements for most elements by improving particle size distribution and consequently the pellet porosity. 相似文献
78.
Ferraz RC Fontana CR Ribeiro AP Trindade FZ Bartoloni FH Baader JW Lins EC Bagnato VS Kurachi C 《Journal of photochemistry and photobiology. B, Biology》2011,103(2):87-92
The photodynamic therapy (PDT) is a combination of using a photosensitizer agent, light and oxygen that can cause oxidative cellular damage. This technique is applied in several cases, including for microbial control. The most extensively studied light sources for this purpose are lasers and LED-based systems. Few studies treat alternative light sources based PDT. Sources which present flexibility, portability and economic advantages are of great interest. In this study, we evaluated the in vitro feasibility for the use of chemiluminescence as a PDT light source to induce Staphylococcus aureus reduction. The Photogem? concentration varied from 0 to 75 μg/ml and the illumination time varied from 60 min to 240 min.The long exposure time was necessary due to the low irradiance achieved with chemiluminescence reaction at μW/cm2 level. The results demonstrated an effective microbial reduction of around 98% for the highest photosensitizer concentration and light dose. These data suggest the potential use of chemiluminescence as a light source for PDT microbial control, with advantages in terms of flexibility, when compared with conventional sources. 相似文献
79.
da Silva AS Fernandes FC Tognolli JO Pezza L Pezza HR 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(5):1881-1885
This article describes a simple, inexpensive, and environmentally friendly method for the monitoring of glyphosate using diffuse reflectance spectroscopy. The proposed method is based on reflectance measurements of the colored compound produced from the spot test reaction between glyphosate and p-dimethylaminocinnamaldehyde (p-DAC) in acid medium, using a filter paper as solid support. Experimental designs were used to optimize the analytical conditions. All reflectance measurements were carried out at 495 nm. Under optimal conditions, the glyphosate calibration graphs obtained by plotting the optical density of the reflectance signal (AR) against the concentration were linear in the range 50-500 μg mL(-1), with a correlation coefficient of 0.9987. The limit of detection (LOD) for glyphosate was 7.28 μg mL(-1). The technique was successfully applied to the direct determination of glyphosate in commercial formulations, as well as in water samples (river water, pure water and mineral drinking water) after a previous clean-up or pre-concentration step. Recoveries were in the ranges 93.2-102.6% and 91.3-102.9% for the commercial formulations and water samples, respectively. 相似文献
80.
Ronaldo S. Nunes Gilbert Bannach José M. Luiz Flávio J. Caires Claudio T. Carvalho Massao Ionashiro 《Journal of Thermal Analysis and Calorimetry》2011,106(2):525-529
Solid-state compounds of general formula Ln2L3·nH2O, where L represents 1,4-bis(3-carboxy-3-oxo-prop-1-enyl)benzene and Ln = La, Ce, Pr, Nd, Sm, were synthesized. Complexometric
titrations with EDTA, thermogravimetry (TG), differential thermal analysis (DTA), differential scanning calorimetry (DSC),
X-ray powder diffractometry, elemental analysis and infrared spectroscopy have been employed to characterize and to study
the thermal behavior of these compounds in dynamic air atmosphere. The results led to information about the composition, dehydration,
crystallinity, and thermal decomposition of the synthesized compounds. 相似文献