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21.
Lung transplantation is a necessary step for the patients with the end stage of chronic obstructive pulmonary disease. The use of artificial lungs is a promising alternative to natural lung transplantation which is complicated and is restricted by low organ donations. For successful lung engineering, it is important to choose the correct combination of specific biological cells and a synthetic carrier polymer. The focus of this study was to investigate the interactions of human lung epithelial cell line NCl-H292 that is involved in lung tissue development with the biodegradable poly(ε-caprolactone) before and after its chemical modification to evaluate potential for use in artificial lung formation. Also, the effect of polymer chemical modification on its mechanical and surface properties has been investigated. The poly(ε-caprolactone) surface was modified using aminolysis followed by immobilization of gelatin. The unmodified and modified polymer surfaces were characterized for roughness, tensile strength, and NCl-H292 metabolic cell activity. The results showed for the first time the possibility for NCI-H292 cells to adhere on this polymeric material. The resazurin assay showed that the metabolic activity at 24?h postseeding of 80% in the presence of the unmodified and greater than 100% in the presence of the modified polymer was observed. The roughness of the poly(ε-caprolactone) increased from 4 to 26?nm and the film strength increased from 0.01 to 0.045 kN when the material was chemically modified. The results obtained to date show potential for using modified poly(ε-caprolactone) as a scaffold for lung tissue engineering. 相似文献
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23.
Luke J. Batchelor Emma Fitzgerald Dr. Joanna Wolowska Dr. Joseph J. W. McDouall Prof. Eric J. L. McInnes 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(36):11082-11088
The synthesis, structural and magnetic characterisation of [VIII3O(tmme)2(diimine)2Cl] [diimine=2,2′‐bipyridine ( 1 ) or 1,10‐phenanthroline ( 2 )] and (HNEt3)2[VIII4O(tmme)4] ( 3 ) is reported, in which H3tmme is tris(mercaptomethyl)ethane, MeC(CH2SH)3, the thiol analogue of the famous tripodal alcohol ligands typified by H3thme [tris(hydroxymethyl)ethane, MeC(CH2OH)3]. Complexes 1 and 3 have “T‐shaped” and square topologies, respectively, and the latter is centred on a rare example of a square‐planar oxide. The tri‐thiolate ligands bind the periphery of the clusters and provide such strong antiferromagnetic exchange pathways that in both cases only a single total spin state is occupied up to room temperature, in the absence of metal–metal bonding. Magnetic data, electronic structure calculations and electrochemical data are reported. 相似文献
24.
We study the scattering of a scalar plane wave from a two-dimensional, randomly rough surface, on which the Dirichlet boundary condition is satisfied. The scattering amplitude is obtained in the form of the Fourier transform of an exponential, in which the exponent is written as an expansion in powers of the surface profile function. It is shown that the latter expansion can be written in such a way that the corresponding scattering matrix is manifestly reciprocal. Numerical results for the reflectivity, and for the contribution to the mean differential reflection coefficient from the incoherent component of the scattered field, are obtained and compared with the predictions of small-amplitude perturbation theory and the Kirchhoff approximation. As the wavelength of the incident wave is varied continuously the results of the phase-perturbation theory change continuously from those of the small-amplitude perturbation theory to those of the Kirchhoff approximation. 相似文献
25.
We report on unique measurements of multiple microsecond-duration arrest periods during the propagation of high speed (>1
km s−1) cracks in micromachined single-crystal silicon specimens. These events were recorded electronically and in physical features
remaining on the fracture plane. Using time-of-flight calculations, we have determined that these arrest patterns are due
to the interference of boundary-reflected stress waves with the propagating crack tip. The specimen size, the measurement
method, and the low acoustic attenuation in cyrstalline silicon facilitated the observation of these phenomena. 相似文献
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27.
M. Fitzgerald J. Khachan S. Bosi 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,39(1):35-39
Highly resolved Doppler shifted peaks of the hydrogen
Balmer lines, resulting from charge exchange of H+, H2+,
and H3+ with an H2 gas target, were obtained without the
need for a deconvolution procedure. This enabled the unambiguous
determination of the chemistry of these hydrogen species in the
units of mTorr pressure range. This was obtained from a gaseous
discharge using a biconical hollow cathode that yielded a well
collimated and monoenergetic beam. 相似文献
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30.
Using the high energy resolution of the Mössbauer effect, the elastic and inelastic scattering of gamma-rays from single crystals of HF-doped IceI
h has been distinguished. The crystals were studied in the region of 100 K, since measurements by previous workers have suggested the possibility of an order-disorder transition at this temperature. Marked anomalies in the scattered intensity were observed between 106 and 125 K, and these were shown to depend on the thermal history of the crystals. 相似文献