一种用于荧光皮秒时间分辨光谱的测试系统

本文详细描述了一种由氩离子锁模激光器、样品池、分光系统及微微秒条纹相机构成的用于测试低强度荧光微微秒时间分辨光谱的系统。给出了典型样品的测试结果:时间分辨率为10ps,光谱范围为500Å—800Å。最后对测量结果进行了分析讨论。     

掺入Eu的钛酸钡纳米晶陶瓷材料制备与电子结构特征

以Eu2O3、TiO2和BaCO3为原材料,在高温高压的极端条件下(4．0GPa,1090℃)采用固相反应法制备了结构均匀的新陶瓷材料Ba1-xEuxTiO3(x=0.1-0.4),样品显示灰黑色。当x增加到0．5时,出现ABO3型钙钛矿相和Eu2Ti2O7焦绿石相共存。X射线衍射图样显示Eu离子对A位Ba离子的均匀替代。并随着Eu含量的增加,结构向高对称性转变。通过对X射线衍射数据计算,表明材料结晶在平均粒度为几十纳米的数量级。X射线电子能谱(XPS)分析说明：在高压的作用下,Eu^3 离子部分被还原,在晶体结构中以Eu^3 离子(4f^6)和亚稳态Eu^2 离子(4f^7终态构形)稳定共存。同时在样品表面存在大量的吸附氧。Ba1-xEuxTiO3材料的电中性由亚稳态Eu^2 离子和吸附氧(O^-)共同补偿。     

OLED/LCD器件中的γ校正

阐述了OLED／LCD器件中γ校正的基本原理,通过考虑人眼视觉非线性和液晶电光非线性,得到了CRT相对于OLED／LCD的灰度级亮度特性曲线。以所设计的26．4cn VGA(行反转)的TFT—LCD为例,采用源驱动器μPD16641芯片,通过γ校正电路和输入数据、灰度级和基准电压的关系,进行了实际的γ校正。得到了驱动电路中的γ校正的外部电压设定值,将设定目标值与实际驱动测定值进行了比较,从比较的结果可以看到,两者十分接近的,解决了实际的TFT液晶驱动电路中Gamma(γ)校正问题,达到了预期的设计目的,使图像的质量满足了用户的要求。     

Experimental investigation of a seven-element hexagonal fiber coherent array

The phase noises of a 10-m polarization-maintaining （PM） fiber and a 10-W PM fiber amplifier are experimentally measured. The results indicate that the 10-m PM fiber with similar phase noise could be used to investigate the architecture of master oscillator power amplifier coherent combination. A seven-element hexagonal fiber coherent array is developed to investigate the far-field distribution and phase controlling technique of a coherently combining fiber laser array. A hexagonal prism is designed as the combining and splitting component to achieve a fill factor of 0.66. The hill climbing method is employed to detect and lock the element phase.     

Generation of a Tsunami from the Submarine Landslide Near the East Coast of Sakhalin Island

The effect of the generation of tsunami waves caused by collapse of the continental slope and by formation of a submarine landslide near the east coast of Sakhalin Island is reproduced within the framework of a hydrodynamic model. The calculations performed using the numerical hydrodynamic model showed that such a submarine landslide can generate a tsunami wave up to 18 m high on the Sakhalin coast.     

YAG复合型相位共轭腔对改善光束模式的研究

如何降低受激布里渊散射(SBS)相位共轭腔的启动阈值以及如何提高输出光束的质量一直是人们关心的课题。报道了在YAG激光器上运行一种复合型受激布里渊散射相位共轭激光腔,该腔能够输出模式优良的光束。最大能够输出13．35mJ的单纵模,脉冲半高宽度约为15ns,输出光束的发散角为0．6mrad。实验给出了不同参量条件下的输出脉宽、能量及远场光斑分布和干涉环的情况,表明利用复合型相位共轭腔是改善光束模式的一种简单有效的方法。     

Details of the structure determination of the sulfated steroids PSDS and PADS: new components of the sea lamprey (petromyzon marinus) migratory pheromone

The discovery of two new components of the migratory pheromone used by sea lamprey to guide adults to spawning grounds was recently reported. These hold promise for use in a pheromone-based control program for this species, an invasive pest in the Great Lakes. Details of the structure determination of these steroidal bis-sulfates [petromyzosterol disulfate (PSDS, 2) and petromyzonamine disulfate (PADS, 3)] are described here. Pattern matching of 1H NMR data was particularly valuable. This involved comparison of spectra of the natural samples of 2 and 3 with those of appropriate steroidal analogues [e.g., petromyzonol sulfate (PS, 1, a previously known sea lamprey bile acid derivative that is a third component of the migratory pheromone), cholesterol sulfate (6), and squalamine (8)] and model compounds containing the unprecedented aminolactam substructure present in 3. The logic underlying the iterative analyses used is presented.     

三反射系统航空遥感器像旋转分析

像旋转是影响和限制成像质量的一个重要因素.像面反射镜不随扫描反射镜同步旋转时,就会在焦平面上产生像旋转,导致地面信息丢失和图像分辨率明显下降.为了提高航空遥感相机的动态分辨率,必须对遥感相机进行像旋转分析.根据光反射矢量理论,对具有三反射光学系统的航空遥感器的成像特性进行研究.将整个遥感相机抽象为一个简单数学模型.在笛...     

具有实入瞳的远心离轴三反系统研究与设计

采用远心离轴三反成像系统的空间遥感仪器前有光束限制装置时,要求系统具有实入瞳与之匹配。为了满足这一需要,研究了孔径光阑位于主镜前与系统物方焦平面重合的离轴三反系统的设计问题,推导了主镜和三镜共面时离轴三反系统结构参数计算式及物方焦点与主镜间隔表达式,确定了实现系统物方焦点为实焦点的条件及其解法。据此,针对光谱范围为1.0～2.5μm、F数为4、有效焦距为360mm、视场为5°的设计要求,设计出整个波段全视场像质接近衍射极限的具有实入瞳的远心离轴三反系统,系统非球面最高次数为4次。设计结果表明,这种设计方法可用于实入瞳远心离轴三反成像系统的设计。     

Development of a pre-concentrator-thermo-desorber/micro-gas chromatograph/mass spectrometer coupling for on-site analyses of emissions of volatile organic compounds from landfills

The development and use of a pre-concentrator-thermo-desorber/micro-gas chromatograph/mass spectrometer (μTD/μGC/MSD) coupling for the on-site analysis of VOCs in landfill gases are presented. The coupling has the advantage of analysing compounds with two detectors operated in series: the TCD (of the μGC) initially analyses the gas without destroying it, and then the MSD identifies the compounds. Due to the TCD response, the results were quantified with reference to toluene. The reliability of the analytical chain for quantitative analysis was validated by sampling two gaseous standards, including the EPA TO14 mixture, containing 39 compounds. With the OV1?μGC column, 24 compounds were identified and 16 correctly quantified. The repeatability of the measures estimated by their standard deviation was in the order of 1–2%. The detection limit was evaluated at 0.1?ppbv, for a 40?min pre-concentration on the Tenax of the μTD. The results of VOC analyses in the air of a landfill site obtained with the μTD/μGC/MSD coupling show its potential for on-site analyses: immediate results, high sensitivity, no storage for the samples, and measurements of pollution peaks.