Tween-80胶束萃取硫氰酸钼(Ⅴ)配合物研究

本文研究了用Tween-80作萃取剂取硫氰酸钼（Ⅴ），在0.1%浓度下即可达到94％的萃取率，而同样条件下对硫氰酸钨（Ⅲ）基本不萃取，因此可将二者很好的分离。其萃取机理可能为胶束萃取，属超分子范畴。     

用近贴式软X射线光刻术研究DCPA光刻胶的曝光性能

采用软X射线近贴式光刻术,对DCPA光刻胶的曝光性能进行了系统研究,得到了一些新的实验结果。     

LD泵浦Nd∶YVO_4晶体LBO倍频457 nm蓝色激光器

用国产半导体激光二极管泵浦Nd∶YVO4晶体,在室温下获得914nm激光连续输出,用Ⅰ类临界位相匹配LBO腔内倍频获得457nm蓝色激光输出当泵浦注入功率为1.7W时倍频蓝激光最大输出达20mW,光光转换效率为1.2%,功率稳定性24h内优于±3%     

光谱信息数据压缩方法—二真值线性预测法

本文针对线性预测压缩存在的游长短、压缩比低、恢复精度差等问题,提出了一种新的压缩方法—“二真值线性预测法”,其特点是恢复精度高、压缩比大、算法简捷、实时性好,适用于可由线性逼近表示的测量过程的实时压缩。经对典型光谱数据压缩实验表明,平均游长一般比线性预测压缩高1倍,在压缩恢复过程中可保留光谱特征信息,在1%恢复精度时,压缩后数据未编码的情况下一般可获得大于2:1的压缩比,编码后可获得4:1～5:1的压缩比。     

Cobalt-catalyzed photopromoted carbonylation of chloroalkanes in the presence of KI

<正>The photopromoted carbonylation of chloroalkanes with carbon monoxide catalyzed by cobalt compounds[Co(OAc)_2,CoCl_2] in the presence of KI was carried out under ambient conditions.The results revealed that the catalytic activity of Co(OAc)_2 was higher than that of CoCl_2.A basic additive NaOAc was beneficial to the reaction.Interestingly,with NaOAc as an additive, Co(OAc)_2 and CoCl_2 exhibited similar catalytic activity.Preliminary work showed that the role of iodide ion was initially to form active iodoalkanes via substituting chloride ion in chloroalkanes in situ,and then,the carbonylation of iodoalkanes proceeded under irradiation.     

Toric anti-self-dual Einstein metrics via complex geometry

Using the twistor correspondence, we give a classification of toric anti-self-dual Einstein metrics: each such metric is essentially determined by an odd holomorphic function. This explains how the Einstein metrics fit into the classification of general toric anti-self-dual metrics given in an earlier paper (Donaldson and Fine in Math Ann 336(2):281–309, 2006). The results complement the work of Calderbank–Pedersen (J Differential Geom 60(3):485–521, 2002), who describe where the Einstein metrics appear amongst the Joyce spaces, leading to a different classification. Taking the twistor transform of our result gives a new proof of their theorem.     

Toric Anti-self-dual 4-manifolds Via Complex Geometry

Using the twistor correspondence, this article gives a one-to-one correspondence between germs of toric anti-self-dual conformal classes and certain holomorphic data determined by the induced action on twistor space. Recovering the metric from the holomorphic data leads to the classical problem of prescribing the ?ech coboundary of 0-cochains on an elliptic curve covered by two annuli. The classes admitting Kähler representatives are described; each such class contains a circle of Kähler metrics. This gives new local examples of scalar flat Kähler surfaces and generalises work of Joyce [Duke. Math. J. 77(3), 519–552 (1995)] who considered the case where the distribution orthogonal to the torus action is integrable.     

Benzylation of arenes and heteroarenes catalyzed by HfCl_4/HfO_2

A highly efficient benzylation of arenes and heteroarenes catalyzed by HfCl_4/HfO_2 has been developed.Broad scope of benzylation reagents have been used in this process with high yields under mild condition.Additionally,the HfO_2 can be re-used after the reaction.     

短波近红外光谱的整粒小麦蛋白质PLS方法的定量分析

利用漫反射法获得的整粒小麦短波近红外光谱(833～1111nm),采用化学计量学中的偏最小二乘法(PLS)方法,选取不同的波长范围对光谱进行信息提取和分析,给出了不同因子数时PLS方法进行蛋白质分析的结果及其因子数与预测标准偏差平方和(PRESS)关系曲线,确定了最佳回归因子数。并通过选取最佳回归因子和不同波段,对整粒小麦的蛋白质成分进行了定量分析,比较了不同波长范围对分析的影响,并从中获得了较好的预测结果,实验表明,合理选择光谱范围可减少非主要信息的干扰,并以此来提高成分分析精度的方法是切实可行的,在实际应用中有一定的参考价值。     

MOCVD-Ga0.4In0.6As0.85P0.15/InP分布布喇格反射镜的反射率

采用MOCVD方法在InP衬底上制备了高质量的四元合金Ga0.4In0.6As0．85P0.15和InP外延层,用椭圆偏光仪测得Ga0.4In0.6As0.85P0.15和InP外延层的折射率。由这两种具有不同折射率的半导体材料交替生长构成不同周期的分布布喇格反射镜(DBR)。研究了不同周期的DBR结构的反射率与波长及反射率与DBR结构周期数的关系。根据多层膜增反原理,当中心波长为1．55um时,反射率随周期数增加迅速增加,周期数为23时,反射率可达99．97％。利用MOCVD技术,通过Ga0.4In0.6As0.85P0.15/InP的交替生长,成功地获得周期数分别为3,4,7,11,15,19,23的分布布喇格反射镜(DBR)。实验结果表明,已获得表面如镜面状的二元InP外延层,而组分x,y分别为0．4,0．85的四元合金,因其处于混溶隙,外延层表面较粗糙,未获得镜面状表面。反射率的测量结果表明,反射镜的反射率随周期数的增加而升高,当DBR的周期数为23时,反射率为54．44％,与理论结果尚存在一定差距。