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61.
62.
Attanasi OA Berretta S Favi G Filippone P Mele G Moscatelli G Saladino R 《Organic letters》2006,8(19):4291-4293
2,4,4,6-Tetrabromo-3-n-pentadecyl-2,5-cyclohexadienone (TBPCO) has been synthesized and used as a new efficient, convenient, and environmentally friendly brominating agent. 相似文献
63.
Altable M Filippone S Martín-Domenech A Güell M Solà M Martín N 《Organic letters》2006,8(26):5959-5962
[Structure: see text] Thermal treatment of 1,6-fullerenynes bearing an alkyl group on the terminal carbon of the alkyne moiety leads quantitatively to new allenes through a reaction mechanism involving an intramolecular ene process. This reaction outcome is in contrast to that recently found for free terminal alkynes which form cyclobutene derivatives through a [2+2] cyclization mechanism. 相似文献
64.
Liu J Mendenhall MP Holley AT Back HO Bowles TJ Broussard LJ Carr R Clayton S Currie S Filippone BW García A Geltenbort P Hickerson KP Hoagland J Hogan GE Hona B Ito TM Liu CY Makela M Mammei RR Martin JW Melconian D Morris CL Pattie RW Pérez Galván A Pitt ML Plaster B Ramsey JC Rios R Russell R Saunders A Seestrom SJ Sondheim WE Tatar E Vogelaar RB VornDick B Wrede C Yan H Young AR;UCNA Collaboration 《Physical review letters》2010,105(18):181803
A precise measurement of the neutron decay β asymmetry A? has been carried out using polarized ultracold neutrons from the pulsed spallation ultracold neutron source at the Los Alamos Neutron Science Center. Combining data obtained in 2008 and 2009, we report A? = -0.119?66±0.000?89{-0.001?40}{+0.001?23}, from which we determine the ratio of the axial-vector to vector weak coupling of the nucleon g{A}/g{V}=-1.275?90{-0.004?45}{+0.004?09}. 相似文献
65.
Airapetian A Akopov N Akopov Z Amarian M Ammosov VV Aschenauer EC Avakian H Avakian R Avetissian A Avetissian E Bailey P Baturin V Baumgarten C Beckmann M Belostotski S Bernreuther S Bianchi N Blok HP Böttcher H Borissov A Bouhali O Bouwhuis M Brack J Brauksiepe S Brüll A Brunn I Bulten HJ Capitani GP Cisbani E Ciullo G Court GR Dalpiaz PF De Leo R De Nardo L De Sanctis E Devitsin E de Witt Huberts PK Di Nezza P Düren M Ehrenfried M Elbakian G Ellinghaus F Elschenbroich U Ely J Fabbri R 《Physical review letters》2003,90(9):092002
66.
Brunetti FG Herrero MA Muñoz Jde M Giordani S Díaz-Ortiz A Filippone S Ruaro G Meneghetti M Prato M Vázquez E 《Journal of the American Chemical Society》2007,129(47):14580-14581
We report a new approach that uses microwaves to rapidly functionalize carbon nanotubes by using 1,3-dipolar cycloaddition of aziridines, well-known precursors to azomethine ylides, in solvent-free conditions. The efficiency of our microwave-mediated protocol is confirmed by comparison to a similar protocol in classical conditions for the azomethine ylides in DMF. Under these latter conditions, the reaction proceeds in 5 days (against 1 h under microwave irradiation), and the functionalization degree is much lower, as confirmed by thermogravimetric analysis and Raman spectroscopy. With our procedure, we easily scale-up the reaction up to 250 mg of functionalized MWNT in 1 h. We also provide an indirect proof of the covalent sidewall functionalization of the tubes. 相似文献
67.
Attanasi OA Davoli P Favi G Filippone P Forni A Moscatelli G Prati F 《Organic letters》2007,9(17):3461-3464
Michael-type addition of aziridinecarboxylates to 1,2-diaza-1,3-butadienes under solvent-free conditions (SFC) resulted in the formation of alpha-aziridinohydrazone adducts. In toluene under reflux, alpha-aziridinohydrazones gave imidazoles in moderate to good yields. Such a reactivity pattern is explained by 1,5-electrocyclization of azavinyl azomethine ylide generated through thermal ring opening of alpha-aziridinohydrazones. 相似文献
68.
OrazioA. Attanasi Lucia DeCrescentini Paolino Filippone Fabio Mantellini Stefania Santeusanio 《Helvetica chimica acta》2001,84(8):2379-2386
3‐{[(tert‐Butoxy)carbonyl]diazenyl}but‐2‐enoates react in tetrahydrofuran at room temperature with aromatic 1,2‐diamines to give 3‐methylquinoxaline‐2‐carboxylates. These products were also obtained in solid‐phase synthesis, by using polymer‐bound 3‐diazenylbut‐2‐enes. 相似文献
69.
Orazio A. Attanasi Paolino Filippone Amedeo Mei Francesca Romana Perrulli Franco Serra-zanetti 《合成通讯》2013,43(11):1411-1421
Pyrrole and several its derivatives have been subjected to extensive chemical investigations, while substituted 1-aminopyrroles remain a class of compounds about which relatively little is known due to the far from trivial problem sposed by their syntheis. In fact, 1-aminopyrroles appear to be prepared mainly by direct reactionfrom conjugated azoalkenes,2 that unfortunately represent a class of relatively little 相似文献
70.
Competitive retro‐cycloaddition reactions in heterocyclic fullerene bis‐adducts ions: selective removal of the heterocyclic moieties
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