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181.
182.
J. W. Niemantsverdriet J. van Grondelle A. M. van der Kraan 《Hyperfine Interactions》1986,28(1-4):867-870
Mössbauer spectra of SiO2-supported bimetallic FeM (M=Ru, Rh, Pd, Ir, and Pt) with FeM=15 arter treatments such as reduction, exposure to CO and passivation in air are described and compared with previous results obtained on 11 FeM/SiO2 catalysts. 相似文献
183.
H. W. Gronert D. M. Herlach A. Schröder R. van den Berg H. von Löhneysen 《Zeitschrift für Physik B Condensed Matter》1986,63(2):173-178
Low-temperature measurements of the thermal conductivity (0.3KT5K) and of the specific heatC (0.07KT3.5K) of splat-cooled amorphous superconducting Zr0.67Ni0.33(T
c
2.7K) after different annealing stages are reported. increases progressively (up to 55%) after annealing. An analysis of with the help of normal-state measurements belowT
c
in an overcritical field shows that the phonon-electron scattering remains unaltered after annealing. Hence the increase in must be entirely attributed to structure-induced (intrinsic) scattering, i.e. by two-level tunneling states (TLS) at low temperatures (T1K). The specific heat shows a small decrease aboveT
c
(by 8%) which is attributed to a small diminution of the electronic density of states at the Fermi level and to a small increase in the Debye temperature. ForTT
c
where TLS dominate, the specific heatC decreases less upon annealing than expected from the increase of in the standard tunneling model. This points to a change in the TLS relaxation time spectrum upon annealing, as observed previously for Zr
x
Cu1–x
glasses. 相似文献
184.
A. M. van der Kraan R. C. H. Nonnekens J. W. Niemantsverdriet 《Hyperfine Interactions》1986,28(1-4):899-902
A series of TiO2-supported bimetallic FeRu catalysts with different Fe:Ru ratios (; 101; 31; 11; 13) has been studied by means of in situ Mössbauer spectroscopy. The influence of reduction and Fischer-Tropsch synthesis on the state of iron in the FeRu/TiO2 catalysts will be derived. 相似文献
185.
T. Rösel P. Schlemmer J. Röder L. Frost K. Jung H. Ehrhardt 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1992,23(4):359-363
A new method, and first results for an impact energy 2 eV above the threshold of ionisation of helium, are presented for the measurement of absolute triple differential cross sections (TDCS) in a crossed beam experiment. The method is based upon measurement of beam/target overlap densities using known absolute total ionisation cross sections and of detection efficiencies using known absolute double differential cross sections (DDCS). For the present work the necessary absolute DDCS for 1 eV electrons had also to be measured. Results are presented for several different coplanar kinematics and are compared with recent DWBA calculations. 相似文献
186.
Leonard S Van Schepdael A Iványi T Lázár I Rosier J Vanstockem M Vermeersch H Hoogmartens J 《Electrophoresis》2005,26(3):627-632
A capillary electrophoretic (CE) method was developed for the separation of diastereoisomers of a new human immunodeficiency virus (HIV) protease inhibitor TMC114. In total 16 isomers of this drug have been synthesized (eight pairs of enantiomers). We succeeded in the separation of the eight diastereoisomers, but no enantiomers could be separated. Because of the high similarity and water-insolubility of these isomers, the separation is a real challenge. Different CE modes were tried out: capillary zone electrophoresis (CZE), nonaqueous capillary electrophoresis (NACE), micellar electrokinetic capillary chromatography (MEKC), and microemulsion electrokinetic capillary chromatography (MEEKC). Only MEEKC offered resolution of these compounds. 相似文献
187.
Heilemann M Tinnefeld P Sanchez Mosteiro G Garcia Parajo M Van Hulst NF Sauer M 《Journal of the American Chemical Society》2004,126(21):6514-6515
We demonstrate the synthesis and spectroscopic characterization of an unidirectional photonic wire based on four highly efficient fluorescence energy-transfer steps (FRET) between five spectrally different chromophores covalently attached to double-stranded DNA. The DNA-based modular conception enables the introduction of various chromophores at well-defined positions and arbitrary interchromophore distances. While ensemble fluorescence measurements show overall FRET efficiencies between 15 and 30%, single-molecule spectroscopy performed on four spectrally separated detectors easily uncovers subpopulations that exhibit overall FRET efficiencies of up to approximately 90% across a distance of 13.6 nm and a spectral range of approximately 200 nm. Fluorescence trajectories of individual photonic wires show five different fluorescence intensity patterns which can be ascribed to successive photobleaching events. 相似文献
188.
By means of potentiometric pH and pAg measurements, the stability constants and the stoichiometric composition of the silver(I) complexes of some N-methyl-substituted 4-H-diethylenetriamines, in aqueous medium of ionic strength 1.3 and at a temperature of 25.00 degrees , have been determined. In addition to mononuclear and polynuclear complexes, together with their protonated forms, some hydroxo complexes are formed. The values of the stability constants are discussed in terms of possible structures. 相似文献
189.
2-Deoxy-2-[18F]fluoro-D-glucose ([18F] FDG), the most popular positron emitting radiopharmaceutical, may oxidise by autoradiolysis in aqueous solution. The aim of this work was to use LC-MS for determination of the oxidation products of fluorodeoxyglucose and glucose (Glc) obtained by oxidation with Fenton's reagent. Asahipak NH2P-50 polyamide silica column and acetonitrile-0.025% aqueous ammonium formate (80:20 (v/v)) eluent were utilised with an Agilent 1100 HPLC-MS instrument. Ten major oxidation products of FDG and Glc were separated and identified by mass spectrometry: 2-fluorogluconic acid, 2-fluoroglucuronic acid, 2-oxoerythronic acid, arabinose, arabonic acid, araburonic acid, erythrose, erythrulose, gluconic acid, and glucuronic acid. The most intensive electrospray ionisation signals were found in the negative ion spectra and were due to HCOO- adducts, the other acids being in their lactone forms. 相似文献
190.
Thermogravimetric analysis is used to determine the amounts of Mg(OH)2 and Mg(CH3COO)2in a mixture thereof. The application and suitability of different analysis methods are discussed. In the first method the
mass losses in the temperature ranges as indicated by the decomposition of the pure compounds were used. Results obtained
using these temperature ranges were unusable. The percentage mass losses due to the decomposition of Mg(OH)2 and Mg(CH3COO)2 were then determined in a second method using the minimum in the derivative mass vs. temperature curves. The results obtained
by this method compared well with the actual values for mixtures containing more than 15% magnesium acetate. The third method
employed the total experimental mass loss of both decomposition reactions. The results obtained using this method compared
well to the actual values, giving a R
2 value of more than 0.99. This method of using the total mass losses can however only be used for binary mixtures that consist
only of magnesium hydroxide and magnesium acetate.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献