Strontium-90 determination in fish from the Brazilian coast

A radiochemical procedure for low level strontium-90 analysis in fish samples as well as the levels of this radionuclide in fish collected along the Brazilian coast are presented. The method developed was applied in reference samples from the IAEA in order to verify the precision and accuracy of the methodology established. Results obtained for strontium and yttrium yields were about 90%. Strontium-90 levels in fish bones varied from 3 to 12 mBq.g^–1 Ca and these data are reference values to our country.     

Pyrazolino[60]fullerene-oligophenylenevinylene dumbbell-shaped arrays: synthesis, electrochemistry, photophysics, and self-assembly on surfaces

Symmetrically substituted oligophenylenevinylene (OPV) derivatives bearing terminal p-nitrophenylhydrazone groups have been prepared and used for the synthesis of dumbbell-shaped bis(pyrazolino[60]fullerene)-OPV systems. In these triad arrays, the OPV-type fluorescence is dramatically quenched as a consequence of ultrafast OPV-->C60 singlet energy transfer. In its turn the fullerene singlet state is quenched by pyrazoline-->C60 electron transfer, in line with the behavior of the corresponding reference fullerene molecule. The occurrence of electron transfer in the multicomponent arrays is evidenced by recovery of fullerene fluorescence at 77 K in CH2Cl2 and in toluene at 298 K. Under these conditions the OPV-->C60 energy transfer is unaffected. The rate of this process turns out to be higher for the OPV trimer than for the corresponding pentameric OPV arrays, in agreement with energy-transfer theory expectations. Scanning tunneling microscopy (STM) and scanning force microscopy (SFM) revealed that the bis(pyrazolino[60]fullerene)-OPV can self-assemble into ordered layered crystalline architectures on the basal plane of highly oriented pyrolitic graphite.     

Coupled Nonlinear Schrödinger Equations with a Gauge Potential: Existence and Blowup

We study solutions of the Cauchy problem for nonlinear Schrödinger system in with nonlinear coupling and linear coupling modeling synthetic magnetic field in spin‐orbit coupled Bose–Einstein condensates. Three main results are presented: a proof of the local existence, a proof of the sufficient condition for the blowup result in finite time for some solutions, and the persistence of the nonlinear dynamics in the limit where the spin‐orbit coupling converges to zero.     

Arsenic and cadmium content in edible mushrooms from São Paulo,Brazil determined by INAA and GF AAS

Arsenic and cadmium contents in eight edible mushroom species (Agaricus bisporus, Agaricus sp, Pleurotus ostreatus, Pleorotus florida, Pleorotus eryngui, Pleurotus osteatus, Pleurotus salmoneostramineus, Lentinula edodes) consumed by Brazilian population were determined by instrumental neutron activation analysis (INAA) and graphite furnace atomic absorption spectrometry (GF AAS), respectively. Arsenic concentrations varied from 0.009 mg/kg in P. eryngui to 0.210 mg/kg dry weight in L. edodoes and Cd from 0.011 g/kg in P. eryngui to 0.229 mg/kg dw in P. salmoneostramineus. The consumption of mushrooms in São Paulo-Brazil may be considered safe from a toxicological point of view as As and Cd presented levels of ingestion are below the maximum levels recommended by the World Health Organization.     

Bone Tissue Disorders: Healing Through Coordination Chemistry

Osteoporosis, Paget's disease and osteosarcoma are a few examples of bone tissue disorders that affect millions of people worldwide. These conditions can strictly limit the lifestyle of patients and may even lead to their demise. To prevent this or, at least, try to manage the situation, there are several treatments available on the market. Notwithstanding, research has been driven by the possibility to improve the existing therapies, as well as to find new approaches that could better respond to these diseases. In this Review the path is shown through which, in recent years, coordination compounds have been prepared and manufactured to be applied in the management of bone tissue disorders. Starting with the design and preparation of the coordination compounds with various dimensionalities, two approaches have been used: (1) they are prepared as three-dimensional cages that can act as delivery systems for therapeutic substances, or (2) they are constructed/prepared from compounds with intrinsic therapeutic properties. Following this, several strategies have been explored to manufacture the effective delivery to the patients. The versatility of coordination compounds has allowed their use in the preparation of drug tablets, coatings for titanium implants, or even scaffolds for bone tissue engineering. In the end, it becomes clear that these compounds can be a valuable approach to reach a better treatment for bone tissue disorders. Nonetheless, along the road, a few bumps have appeared concerning the therapeutic profile, such as the effect of the structural arrangement or particle size.     

On the computation of all supported efficient solutions in multi-objective integer network flow problems

This paper presents a new algorithm for identifying all supported non-dominated vectors (or outcomes) in the objective space, as well as the corresponding efficient solutions in the decision space, for multi-objective integer network flow problems. Identifying the set of supported non-dominated vectors is of the utmost importance for obtaining a first approximation of the whole set of non-dominated vectors. This approximation is crucial, for example, in two-phase methods that first compute the supported non-dominated vectors and then the unsupported non-dominated ones. Our approach is based on a negative-cycle algorithm used in single objective minimum cost flow problems, applied to a sequence of parametric problems. The proposed approach uses the connectedness property of the set of supported non-dominated vectors/efficient solutions to find all integer solutions in maximal non-dominated/efficient facets.     

5‐Phenyl‐3,4‐dihydro‐2H‐pyrrole: the first example of a planar monosubstituted 1‐pyrroline

In the title compound, C₁₀H₁₁N, the molecules assemble as pseudo‐dimers through π–π interactions, each dimer being rotated by about 90° with respect to its neighbours. The relative positioning of the dimers and C—H...π interactions give, when seen along a, a supramolecular zigzag arrangement. The compound contains a planar pyrroline ring and, as a whole, its molecular conformation is also planar, which represents the first example of a totally planar 2‐substituted 1‐pyrroline and the simplest ever reported by X‐ray diffraction.     

Modeling centrality measures in social network analysis using bi-criteria network flow optimization problems

Centrality measures play an important role in the field of network analysis. In the particular case of social networks, the flow represents the way in which information passes through the network nodes. Freeman et al. (1991) were the first authors to relate centrality measures to network flow optimization problems in terms of betweenness, closeness, and the influence of one node over another one. Such measures are single dimensional and, in general, they amalgamate several heterogeneous dimensions into a single one, which is not suitable for dealing with most real-world problems. In this paper we extend the betweenness centrality measure (or concept) to take into account explicitly several dimensions (criteria). A new closeness centrality measure is defined to deal not only with the maximum flow between every ordered pair of nodes, but also with the cost associated with communications. We shall show how the classical measures can be enhanced when the problem is modeled as a bi-criteria network flow optimization problem.