Signal Processing and Analysis Applied to Powder Behavior in a Rotating Drum

Previous studies of the flow of granular materials in a rotating drum have described the observed time sequences of angle of repose or time to avalanche. The time between avalanches approach has been incorporated into a commercially available powder flow analysis tool. In the present study, the time to avalanche analysis was complemented with a Fourier Transform power spectrum and phase space analysis of the angle of repose time series and avalanche size variability determination. The avalanche size variability approach was found to most readily differentiate between the flow properties of powders across material types. A model was constructed to provide an explanation for the utility of this method.     

Absolute Asymmetric Synthesis: The Origin, Control, and Amplification of Chirality

Biomolecular homochirality, the origin of which is still a puzzle, has challenged scientists to design chemical systems that provide chiral molecules through absolute asymmetric synthesis and to amplify a small stereochemical bias in such systems. The photoresolution of the enantiomers of helical-shaped, sterically overcrowded alkene 1 with circularly polarized light and the transduction of the stereochemical information by triggering the helical arrangement of a large collection of achiral molecules in a twisted nematic liquid crystalline phase (2) are examples of control and amplification of chirality.     

Standardization for oxygen isotope ratio measurement - still an unsolved problem

Numerous organic and inorganic laboratory standards were gathered from nine European and North American laboratories and were analyzed for their delta(18)O values with a new on-line high temperature pyrolysis system that was calibrated using Vienna standard mean ocean water (VSMOW) and standard light Antartic precipitation (SLAP) internationally distributed reference water samples. Especially for organic materials, discrepancies between reported and measured values were high, ranging up to 2 per thousand. The reasons for these discrepancies are discussed and the need for an exact and reliable calibration of existing reference materials, as well as for the establishment of additional organic and inorganic reference materials is stressed. Copyright 1999 John Wiley & Sons, Ltd.     

Multiplicity dependence of the pion source in S+A collisions at the CERN SPS

The emission of pions from relativistic heavy-ion collisions of S+S, S+Ag and S+Pb at 200 GeV/nucleon is characterized using two-particle interferometry. The multiplicity dependence of the pion source parameters near midrapidity is studied. The transversal (R _t) and longitudinal (R _l) pion source parameters are independent of the initial nuclei in the interaction and increase with increasing multiplicity. This suggests that the freeze-out process is governed mainly by the particle multiplicity. The multiplicity dependence is weaker than that expected from a simple model of a freeze-out at a constant density.     

Observation of Psi(3770)-->gammachi(c1)-->gammagammaJ/Psi

From e(+)e(-) collision data acquired with the CLEO detector at the Cornell Electron Storage Ring, we observe the non-DD(_) decay Psi(3770))-->gammachi(c1) with a statistical significance of 6.6 standard deviations, using the two-photon cascades to J/Psi and J/Psi-->l(+)l(-). We determine sigma(e(=)e(-)-->Psi(3770))xBeta(Psi(3770)-->gammachi(c1))=(18.0 +/- 3.3 +/- 2.5) pb and branching fraction Beta(Psi(3770)-->gammachi(c1)=(2.8 +/- 0.5+/-0.4) x 10(-3). We set 90% C.L. upper limits for the transition to chi(c2) (chi(c0)): sigma x Beta<5.7 pb (<282 pb) and Beta<0.9 x 10(-3) (<44 x 10(-3)). We also determine Gamma(Psi(3770)gammachi(c1))/Gamma(Psi(3770)-->pi(+)pi(-)J/Psi)=1.5 +/- 0.3 +/- 0.3 (>1.0 at 90% C.L.), which bears upon the interpretation of X(3872).