Stress relaxation in styrene-butadiene-styrene block copolymers containing unattached linear polybutadiene and styrene-butadiene diblocks

Stress relaxation has been studied in networks of styrene-butadiene-styrene triblock copolymers with spherical styrene domain structure containing 0.10 weight fraction of unattached linear polybutadiene (M_w = 389,000) or styrene-butadiene diblocks with very long butadiene segments (M = 225,000 or 510,000). The stretch ratio (uniaxial extension) was usually 1.15 and the temperature ranged from ?20 to +20°C. The contribution of the linear polybutadiene species to relaxation was essentially the same in two triblock networks with very different butadiene block lengths, as expected if the configurational rearrangements are dominated by reptation. In the diblock-triblock mixtures, in which the diblock butadiene segments are free at one end but anchored at the other and therefore incapable of reptation, there was no contribution to relaxation from the dangling butadiene segments of the diblock component; this would be expected if there are no relaxation mechanisms alternative to reptation for these very long semiattached species within the experimental time scale.     

Balance equation formulation and memory effects in retarded high field semiconductor transport

The role of the finite, non-zero collision duration in high electric fields is examined for its effect on transient and overshoot response of carrier velocity and energy. A quantum kinetic equation approach is used to develop modifications of the balance equations obtained in a drifted Maxwellian approach for treating high-field transport. These result in corrections which require convolution integrals to be evaluated on the short-time scale.     

On the existence and detection of Bloch oscillations in superlattices

While many predicted superlattice behaviors depend on the presence of Bloch oscillations, the existence of such oscillations remains problematical. Here, we consider procedures by which their existence within a superlattice could be detected. We first set upper and lower bounds on the necessary fields. We then demonstrate that while a negative differential mobility is expected, no resonant peak occurs in this mobility at the Bloch frequency. However, we provide two ways of directly observing Bloch oscillations. In the first, we note the existence of structures in the dc velocity-field characteristic when an externally applied RF field has a frequency which is harmonically related to the Bloch frequency. The second approach is to measure the velocity fluctuation noise spectra, which should have a peak at the field-tunable Bloch frequency.     

Overtone spectroscopy of some benzaldehyde derivatives

Overtone spectrum of o, m and p-nitrobenzaldehydes and p-chlorobenzaldehyde has been studied in 2000–12000 cm⁻¹ region. Vibrational frequencies and anharmonicity constants for aryl as well as alkyl CH stretch vibrations have been determined. We have also determined the internuclear distances for the aryl CH bond in the different molecules. The small variation observed in these distances is an indication of the substitution effect. It is observed that in the case of p-disubstituted benzens, the shift in aryl CH bond is proportional to sum of the Hammet σ of the substituents. However in the case of o-disubstituted benzenes it is only 80% of the para-substituted shift.     

Verbesserter Apparat zur volumetrischen Stickstoffbestimmung

Ohne Zusammenfassung(Mitteilung aus dem Institut chimique, Nancy.)     

Experimental evaluation of the pressure and temperature dependence of ion-induced nucleation

An experimental system for the study of ion-induced nucleation in a SO(2)/H(2)O/N(2) gas mixture was developed, employing a soft x-ray at different pressure and temperature levels. The difficulties associated with these experiments included the changes in physical properties of the gas mixture when temperature and pressure were varied. Changes in the relative humidity (RH) as a function of pressure and temperature also had a significant effect on the different behaviors of the mobility distributions of particles. In order to accomplish reliable measurement and minimize uncertainties, an integrated on-line control system was utilized. As the pressure decreased in a range of 500-980 hPa, the peak concentration of both ions and nanometer-sized particles decreased, which suggests that higher pressure tended to enhance the growth of particles nucleated by ion-induced nucleation. Moreover, the modal diameters of the measured particle size distributions showed a systematic shift to larger sizes with increasing pressure. However, in the temperature range of 5-20 °C, temperature increases had no significant effects on the mobility distribution of particles. The effects of residence time, RH (7%-70%), and SO(2) concentration (0.08-6.7 ppm) on ion-induced nucleation were also systematically investigated. The results show that the nucleation and growth were significantly dependent on the residence time, RH, and SO(2) concentration, which is in agreement with both a previous model and previous observations. This research will be inevitable for a better understanding of the role of ions in an atmospheric nucleation mechanism.     

Development of a microfluidic confocal fluorescence detection system for the hyphenation of nano-LC to on-line biochemical assays

One way to profile complex mixtures for receptor affinity is to couple liquid chromatography (LC) on-line to biochemical detection (BCD). A drawback of this hyphenated screening approach is the relatively high consumption of sample, receptor protein and (fluorescently labeled) tracer ligand. Here, we worked toward minimization of sample and reagent consumption, by coupling nano-LC on-line to a light-emitting diode (LED) based capillary confocal fluorescence detection system capable of on-line BCD with low-flow rates. In this fluorescence detection system, a capillary with an extended light path (bubble cell) was used as a detection cell in order to enhance sensitivity. The technology was applied to a fluorescent enhancement bioassay for the acetylcholine binding protein, a structural analog of the extracellular ligand-binding domain of neuronal nicotinic acetylcholine receptors. In the miniaturized setup, the sensitive and low void volume LED-induced confocal fluorescence detection system operated in flow injection analysis mode allowing the measurement of IC₅₀ values, which were comparable with those measured by a conventional plate reader bioassay. The current setup uses 50 nL as injection volume with a carrier flow rate of 400 nL/min. Finally, coupling of the detection system to gradient reversed-phase nano-LC allowed analysis of mixtures in order to identify the bioactive compounds present by injecting 10 nL of each mixture.     

Platinum-nanogaps for single-molecule electronics: room-temperature stability

We present the formation of single-molecule devices based on nanometre-spaced platinum electrodes. The electrodes are fabricated using a self-breaking electromigration method which yields nanogaps with long-term stability at room temperature [Prins et al., APL, 2009, 94, 123108.]. The stability at room temperature allows for detailed comparison of the device electrical properties before and after deposition of the molecules. In this way, conductance as a result of direct tunneling between the electrodes can be distinguished from conductance through the molecule. After molecule deposition, some devices display transport in the strong coupling regime while others are in the weak-coupling Coulomb blockade regime. Gated transport is observed in the latter case.     

The Wigner distribution function

In this letter, the relationship between the characteristic function for two arbitrary noncommuting observables and a generalized Wigner distribution function is established. This distribution function is shown to have no simple interpretation in the sense of probability theory but, in lieu of its special properties, can be used directly for calculating the expectation values of observables.