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991.
992.
Aram Arutyunov Valeriano Antunes de Oliveira Fernando Lobo Pereira Evgeniy Zhukovskiy 《Applicable analysis》2015,94(1):129-143
In the paper, the set-valued covering mappings are studied. The statements on solvability, solution estimates, and well-posedness of inclusions with conditionally covering mappings are proved. The results obtained are applied to the investigation of differential inclusions unsolved for the unknown function. The statements on solvability, solution estimates, and well-posedness of these inclusions are derived. 相似文献
993.
On a paper of Edmunds and Opic on limiting interpolation of compact operators between spaces
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Fernando Cobos Luz M. Fernández‐Cabrera Antón Martínez 《Mathematische Nachrichten》2015,288(2-3):167-175
We show abstract versions for Banach couples of several limiting compact interpolation theorems established by Edmunds and Opic for couples of spaces. 相似文献
994.
Heitor Fernando Nunes de Oliveira Christophe Farès Roberto Rinaldi 《Chemical science》2015,6(9):5215-5224
In this report, 1-butyl-3-methylimidazolium chloride ([C4C1im]Cl) is demonstrated to enhance the kinetics of acid-catalysed hydrolysis of 1,4-β-glucans in binary solvent mixtures. [C4C1im]Cl plays other roles in the reaction beyond acting as a solvent for cellulose, as currently accepted. In fact, the presence of the IL increases the Hammett acidity of the catalyst dissolved in the reaction medium. The kinetic data from cellobiose and cellulose hydrolysis directly correlate with the acid strength found for p-toluenesulfonic acid in the different reaction media studied here. The current report identifies neglected, but yet very important phenomena occurring in cellulose depolymerisation. 相似文献
995.
Rubí Zamudio-Vázquez Sa?ka Ivanova Miguel Moreno Maria Isabel Hernandez-Alvarez Ernest Giralt Axel Bidon-Chanal Antonio Zorzano Fernando Albericio Judit Tulla-Puche 《Chemical science》2015,6(8):4537-4549
The synthesis of a new small library of quinoxaline-containing peptides is described. After cytotoxic evaluation in four human cancer cell lines, as well as detailed biological studies, it was found that the most active compound, RZ2, promotes the formation of acidic compartments, where it accumulates, blocking the progression of autophagy. Further disruption of the mitochondrial membrane potential and an increase in mitochondrial ROS was observed, causing cells to undergo apoptosis. Given its cytotoxic activity and protease-resistant features, RZ2 could be a potential drug candidate for cancer treatment and provide a basis for future research into the crosstalk between autophagy and apoptosis and its relevance in cancer therapy. 相似文献
996.
Ana Lucía Campaa Amaimen Guilln Ricardo Rivas Veronica Akle Juan C. Cruz Johann F. Osma 《Molecules (Basel, Switzerland)》2021,26(14)
This study presents the feasibility of using various functionalized substrates, Fe3O4 nanoparticles (NPs) and Al2O3 spheres, for the removal of Cd from aqueous solution. To improve the materials’ affinity to Cd, we explored four different surface modifications, namely (3-Aminopropyl) triethoxysilane (APTES), L-Cysteine (Cys) and 3-(triethoxysilyl) propylsuccinic anhydride (CAS). Particles were characterized by FTIR, FIB-SEM and DLS and studied for their ability to remove metal ions. Modified NPs with APTES proved to be effective for Cd removal with efficiencies of up to 94%, and retention ratios up to 0.49 mg of Cd per g of NPs. Batch adsorption experiments investigated the influence of pH, contact time, and adsorbent dose on Cd adsorption. Additionally, the recyclability of the adsorbent and its potential phytotoxicity and animal toxicity effects were explored. The Langmuir, Freundlich, pseudo-first-order and pseudo-second-order models were applied to describe the behavior of the Cd adsorption processes. The adsorption and desorption results showed that Fe3O4 NPs modified with APTES are promising low-cost platforms with low phytotoxicity for highly efficient heavy metal removal in wastewater. 相似文献
997.
Javier Galeano Miguel-ngel Gomez Fernando Rivas Javier M. Buldú 《Entropy (Basel, Switzerland)》2021,23(7)
The aim of the current study was twofold: (i) to investigate the distribution of the strike positions of badminton players while quantifying the corresponding standard entropy and using an alternative metric (spatial entropy) related to winning and losing points and random positions; and (ii) to evaluate the standard entropy of the receiving positions. With the datasets of 259 badminton matches, we focused on the positions of players’ strokes and the outcome of each point. First, we identified those regions of the court from which hits were most likely to be struck. Second, we computed the standard entropy of stroke positions, and then the spatial entropy, which also considers the order and clustering of the hitting locations in a two-dimensional Euclidean space. Both entropy quantifiers revealed high uncertainty in the striking position; however, specific court locations (i.e., the four corners) are preferred over the rest. When the outcome of each point was taken into account, we observed that the hitting patterns with lower entropy were associated with higher probabilities of winning points. On the contrary, players striking from more random positions were more prone to losing the points. 相似文献
998.
999.
Fernando Silva Lopes Osmar Antunes Junior Ivano G.R. Gutz 《Electrochemistry communications》2010,12(10):1387-1390
Successful coupling of electrochemical preconcentration (EPC) to capillary electrophoresis (CE) with contactless conductivity detection (C4D) is reported for the first time. The EPC–CE interface comprises a dual glassy carbon electrode (GCE) block, a spacer and an upper block with flow inlet and outlet, pseudo-reference electrode and a fitting for the CE silica column, consisting of an orifice perpendicular to the surface of a glassy carbon electrode with a bushing inside to ensure a tight press fit. The end of the capillary in contact with the GCE is slant polished, thus defining a reproducible distance from the electrode surface to the column bore. First results with EPC–CE–C4D are very promising, as revealed by enrichment factors of two orders of magnitude for Tl, Cu, Pb and Cd ion peak area signals. Detection limits for 10 min deposition time fall around 20 nmol L?1 with linear calibration curves over a wide range. Besides preconcentration, easy matrix exchange between accumulation and stripping/injection favors procedures like sample cleanup and optimization of pH, ionic strength and complexing power. This was demonstrated for highly saline samples by using a low conductivity buffer for stripping/injection to improve separation and promote field-enhanced sample stacking during electromigration along the capillary. 相似文献
1000.