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31.
Electronic and magnetic properties of diluted B1−xMnxN alloys are calculated by means of the full potential linearized augmented plane wave (FP-LAPW) method and the generalized gradient approximation (GGA). A half-metallic state is predicted for a composition of 6.25%. The spin majority being metallic and minority being semiconducting. We found a total magnetic moment of 2 μB (Bohr-magnetons) per supercell, in agreement with the half-metallic behaviour. The main contribution of the cell magnetic moment is localized at the transition metal site Mn, with a local moment of 1.24 μB. 相似文献
32.
First-principles calculations have been performed to investigate the high pressure phase transitions and dynamical properties of the less known lead polonium compound. The calculated ground state parameters for the NaCl phase show good agreement with the experimental data. The obtained results show that the intermediate phase transition for this compound is the orthorhombic Pnma phase. The PbPo undergoes from the rocksalt to Pnma phase at 4.20 GPa. Further structural phase transition from intermediate to CsCl phase has been found at 8.5 GPa. In addition, phonon dispersion spectra were derived from linear-response to density functional theory. In particular, we show that the dynamical properties of PbPo exhibit some peculiar features compared to other III–V compounds. Finally, thermodynamics properties have been also addressed from quasiharmonic approximation. 相似文献
33.
Osman Canko Ahmet ErdinçFerhat Ta?k?n Ali Fuat Y?ld?r?m 《Journal of magnetism and magnetic materials》2012,324(4):508-513
The magnetization of a cylindrical Ising nano-tube is investigated by the use of the effective field theory with correlations. The effects of the crystal field couplings at the surface shell to the order parameters, susceptibility, internal energy, specific heat and free energy are investigated. Some characteristic phenomena are examined in the thermal variations, depending on crystal field term. Moreover, tricritical and critical points are found on the (D/J,kT/J) plane, where D/J and kT/J are reduced crystal-field and temperature, respectively. 相似文献
34.
Umit H. Kaynar İsrafil Şabikoğlu 《Journal of Radioanalytical and Nuclear Chemistry》2018,318(2):823-834
The amorphous SiO2 (200–300 nm) was synthesized as an absorbent and thorium adsorption of SiO2 was investigated using experimental and RSM method. The SiO2 particles were made for the adsorption of thorium from aqueous solutions, and characterized by particle size measurement, XRD and SEM. The adsorption of thorium process was optimized with RSM method. The correlation between four variables was modeled and studied. Under optimum conditions, the adsorption capacity of SiO2 particles was found to be 134.4 mg/g, the correlation coefficient (R2) and the F value was obtained 0.96 and 1.98?×?10?6, respectively. In addition, the adsorption isotherms were examined. 相似文献
35.
Fatih Güleç Aysun Özen Aysel Niftaliyeva Ayşe Aydın Emir Hüseyin Şimşek Ali Karaduman 《Research on Chemical Intermediates》2018,44(1):55-67
2,6-Dimethylnaphthalene is an important dimethylnaphthalene isomer which can be used in the production of polyethylene naphthalate. The novelty of this study is to reveal Langmuir–Hinshelwood and Eley–Rideal reaction rate equations for the methylation of naphthalene over Fe/ZSM-5 zeolite catalysts besides the proposed reaction rate equation. To investigate the kinetics and mechanisms of naphthalene methylation, the methylation experiments were carried out in a gas–solid catalytic fixed-bed reactor in the presence of Fe/ZSM-5 zeolite catalysts at two different temperatures (450 and 500 °C) and five different weight hourly space velocities (0.5, 1.0, 1.5, 2.0, 2.5, 3.0 h?1). A naphthalene:methanol:1,2,4-trimethyl benzene mixture having a 1:3:10 molar ratio was used as a feed stream. The methylation products were identified by using GC–MS. For the methylation kinetics of naphthalene, the reaction rates depending on the naphthalene and methanol concentration were determined. Furthermore, the effects of temperature and weight hourly space velocity on the conversion of naphthalene, the selectivity of 2,6-dimethylnaphthalene, and the ratio of 2-methylnaphthalene/1-methylnaphthalene were determined. The results of this study demonstrate that the Langmuir–Hinshelwood reaction mechanism for naphthalene methylation is more compatible at 450 °C and the Eley–Rideal reaction mechanism at 500 °C. Moreover, in addition to 2,6-dimethylnaphthalene, other dimethylnaphthalene and tri-methylnaphthalene isomers were formed in the methylation of naphthalene. The conversion of naphthalene reached approximately 70%. Moreover, the highest selectivity of 2,6-dimethylnaphthalene was almost 40%. The ratios of 2-methylnaphthalene/1-methylnaphalene demonstrate that the methylation of naphthalene to 2-methynaphthalene is much higher than to 1-methynaphthalene. 相似文献
36.
Ferhat Can Özkaya Weaam Ebrahim Maximilian Klopotowski Zhen Liu 《Natural product research》2018,32(7):840-843
The anti-neuroinflammatory meroterpenoid citreohybridonol was isolated for the first time from a sponge-derived fungus Penicillium atrovenetum. In this study, in addition to isolation and structure featuring, its unambiguous absolute configuration was determined exclusively by single crystal X-ray diffraction. The C-17-keto tautomer was clearly observed in X-ray analysis. The substance crystallises in the monoclinic space group P21 with a = 10.7496(5) Å, b = 14.3286(7) Å, c = 17.4909(8) Å, β = 103.235(2)°, V = 2622.5(2) Å3, Z = 2, Dcalcd = 1.280 g/cm3. The chirality of the asymmetric carbon atoms was as follows: C3 (S), C5 (R), C6 (S), C8 (S), C9 (R), C10 (R), C13 (R), C14 (R). 相似文献
37.
We give another elementary proof for the majorization principle for Wright-convex functions. This inequality is due to Ng. 相似文献
38.
A poorly crystallized apatite is prepared by co-precipitation at room temperature and dried by lyophilization. The electrical
properties, in terms of ionic conductivity, improve after a second compression of the sample under 15 t/cm2. Characterization by X-ray diffraction, infrared spectroscopy and conductivity spectra show that this improved conductivity
following the compression processing could be related to the establishment of order within the apatitic network.
Electronic Publication 相似文献
39.
The steric hindrance of the 7α-OR group in bile acid derivatives is very different from the 12α-OR group. The effect of this difference in steric hindrance on the synthesis of cyclocholates has been evaluated with support from AM1 and MM2 calculations. The 13C NMR parameters for cheneodeoxycholic acid-based cyclocholates have been determined. 相似文献
40.
Bılal Günes˛ Emel Nergız Semra Ide Ertan S˛ahın Sevıl Irıs˛lı 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(11):1282-1284
The asymmetric unit of the title compound, [Pt(C25H22P2)(C27H26P2)]Br2 or [Pt(dppm)(dppp)]Br2, where dppm is bis(diphenylphosphino)methane and dppp is 1,3-bis(diphenylphosphino)propane, consists of a discrete [Pt(dppm)(dppp)]2+ cation and two Br− anions at van der Waals distances. This is the first reported platinum(II) complex containing both dppm and dppp ligands. Noticeable features are that the coordination of platinum by the differing dppm and dppp ligands produces a distorted coordination geometry with differing ligand bite angles (and to a lesser extent bond distances), and that the strain induced by the formation of the four-membered dppm chelate ring has a marked effect upon the bond angles at the P atoms of this ligand. 相似文献