全文获取类型
收费全文 | 15471篇 |
免费 | 2568篇 |
国内免费 | 1864篇 |
专业分类
化学 | 11580篇 |
晶体学 | 184篇 |
力学 | 789篇 |
综合类 | 97篇 |
数学 | 1384篇 |
物理学 | 5869篇 |
出版年
2024年 | 53篇 |
2023年 | 276篇 |
2022年 | 524篇 |
2021年 | 573篇 |
2020年 | 653篇 |
2019年 | 647篇 |
2018年 | 572篇 |
2017年 | 477篇 |
2016年 | 768篇 |
2015年 | 721篇 |
2014年 | 866篇 |
2013年 | 1208篇 |
2012年 | 1382篇 |
2011年 | 1350篇 |
2010年 | 931篇 |
2009年 | 935篇 |
2008年 | 1045篇 |
2007年 | 944篇 |
2006年 | 849篇 |
2005年 | 757篇 |
2004年 | 616篇 |
2003年 | 523篇 |
2002年 | 570篇 |
2001年 | 396篇 |
2000年 | 291篇 |
1999年 | 304篇 |
1998年 | 249篇 |
1997年 | 221篇 |
1996年 | 200篇 |
1995年 | 164篇 |
1994年 | 140篇 |
1993年 | 109篇 |
1992年 | 107篇 |
1991年 | 102篇 |
1990年 | 69篇 |
1989年 | 56篇 |
1988年 | 39篇 |
1987年 | 30篇 |
1986年 | 34篇 |
1985年 | 34篇 |
1984年 | 20篇 |
1983年 | 16篇 |
1982年 | 14篇 |
1981年 | 17篇 |
1980年 | 9篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1973年 | 5篇 |
1971年 | 4篇 |
1936年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
S. G. Hutchison C. M. Wai J. Dong R. J. Kearney 《Plasma Chemistry and Plasma Processing》1995,15(2):353-367
The feasibility of producing titanium metal from titanium tetrachloride in a thermal plasma under equilibrium and adiabatic expansion conditions has been theoretically investigated. Free energy minimization and adiabatic expansion calculations to simulate a nozzle expansion were used to study the practicality of production. The crucial requirements for the production of titanium powder from TiCl4 and H2 appear to be rapid quenching of the plasma gas at high temperature (e.g., 3700 K) and appropriate reactant concentrations. Quenching of tire plasma gas and production of titanium powder can be achieved by adiabatic expansion through a nozzle. Preliminary experimental data indicate that titanium powder of approximately 5 nm in size can be produced in an argon plasma rising a nozzle expansion approach. 相似文献
92.
Dong H. Kim 《Journal of heterocyclic chemistry》1992,29(1):11-16
Syntheses of 5,6,8,9,14,14a-hexahydroisoquino[1,2-b][3]benzazepine-2,3,11,12-tetrol and related compounds are described. Key steps involve an initial construction of the isoquinoline ring under the Bischler-Napieralski conditions, which is followed by the building of the azepine ring via an intramolecular lactam formation on to the isoquinoline nucleus. 相似文献
93.
为建立快速、简便、灵敏的分光光度法测定血清锌 ,在表面活性剂TritonX -1 0 0存在下 ,用 2 -(5 -溴 -2 -吡啶偶氮 ) -5 -[N ,N -二羧基甲基 ]苯酚 (5 -Br-PADCAP)作显色剂 ,不去蛋白分光光度法测定血清锌。结果表明 ,锌络合物最大吸收波长为 5 5 7nm ,线性范围 0~ 5 0 0μmol L ,摩尔吸光系数为 1 1 2× 1 0 5L·mol-1·cm-1。回收率为 99 9% ,批内变异系数 (CV)为2 1 % ,批间变异系数为 2 9% ,与原子吸收分光光度法 (x)比较具有良好的相关性 ,y =1 0 1 0x-0 1 5 4,r=0 991 8,P >0 0 5。可见本法测定血清锌不必去蛋白、用血量少、方法简便、灵敏可靠 ,适合临床应用 相似文献
94.
95.
Zhanglin Liu Dong Tian Fei Shen Lulu Long Yanzong Zhang Gang Yang Yongmei Zeng Jing Zhang Jinsong He Ying Zhu Shihuai Deng 《中国化学快报》1990,30(12):2221-2224
Four distinct biochars were employed to remove three typical pollutants, meanwhile, path analysis, a multi-statistical regression method, was performed to elucidate the dominant factors of biochar adsorption. This work can provide a new insight to prepare a targeted biochar as adsorbents. 相似文献
96.
Xiao Zhen Liu Fei Wang Dong Dong Luo Xing Guo Guang Qing Lei 《中国化学快报》2007,18(11):1339-1341
The hydroxyl group of carbocyclic nucleosides was inversed when the compounds were treated with Me_3SiCl,KCN and a catalytic amount of NaI in DMF/CH_3CN. 相似文献
97.
A new Li-containing quaternary nitride, Li4Sr3Ge2N6, was obtained as single crystals from constituent elements in molten Na. It crystallizes in space group C2/m (No. 12) with a=6.1398(7) Å, b=10.021(1) Å, c=6.3130(7) Å, β=91.279(2)°, and Z=2. It contains the first example of isolated nitridogermanate anions of Ge2N610−, which is also the first example of edge-sharing tetrahedral [GeN4]. 相似文献
98.
发现某些含二维液晶基元的热致液晶高分子容易产生反向壁织构与含有高强度有错点(│S│大于1)的向列态纹影织构。这类液晶高分子的织构与形态学特点与含一维棒状液晶基元的其他液晶高分子不同。 相似文献
99.
Norikazu Nishiyama Yong-Rong Dong Tao Zheng Yasuyuki Egashira Korekazu Ueyama 《Journal of membrane science》2006,280(1-2):603-609
Microporous carbon membranes were prepared on an -alumina support by a pyrolysis of cationic tertiary amine/anionic polymer composites. The precursor solutions contain a thermosetting resorcinol/formaldehyde (RF) polymer and a cationic tertiary amine. Three types of cationic tertiary amines with different chain lengths were used, such as tetramethlammonium bromide (TMAB), tetrapropylammonium bromide (TPAB) and cetyltrimethylammonium bromide (CTAB). A porous structure was produced by a decomposition of the amine and the resulting pores assisted the further gasification of the RF polymer at high temperature. The carbon/alumina membranes have thin and continuous carbon top layers with a thickness of 1 μm. Gas permeation tests were performed using single gases of CO2, O2, N2, CF4, n-C4H10 and i-C4H10, as well as binary mixtures of CH4/n-C4H10 and N2/CF4 at different temperatures between 23 and 150 °C. The carbon membrane prepared using TMAB showed separation factors higher than 650 for the CH4/n-C4H10 mixtures and higher than 8100 for the N2/CF4 mixture. From the permeation of pure gases with different molecular sizes, the pore sizes of the carbon membrane prepared using TMAB, TPAB and CTAB are estimated to be 4.0, 5.0 and larger than 5.5 Å, respectively, indicating that the micropore size of the carbon membranes is controllable by using different amines. 相似文献
100.
The influence of additives such as sodium salicylate and sodium chloride on the water solubilization capacity of AOT in n-pentanol solutions has been investigated. The water solubilization capacity is enhanced by sodium salicylate and decreased by sodium chloride. The percolation behavior of the water/AOT/n-pentanol system is studied by modifying the water concentration and temperature. No percolation threshold induced by water or temperature is detected either in the absence or in the presence of additives. The values of ln sigma have a linear correlation with temperature in the range of 5-40 degrees C. The activation energy is also estimated and discussed. 相似文献