Plasticity Effects in the Hole-Drilling Residual Stress Measurement in Peened Surfaces

The incremental hole-drilling technique (IHD) is a widely established and accepted technique to determine residual stresses in peened surfaces. However, high residual stresses can lead to local yielding, due to the stress concentration around the drilled hole, affecting the standard residual stress evaluation, which is based on linear elastic equations. This so-called plasticity effect can be quantified by means of a plasticity factor, which measures the residual stress magnitude with respect to the approximate onset of plasticity. The observed resultant overestimation of IHD residual stresses depends on various factors, such as the residual stress state, the stress gradients and the material’s strain hardening. In peened surfaces, equibiaxial stresses are often found. For this case, the combined effect of the local yielding and stress gradients is numerically and experimentally analyzed in detail in this work. In addition, a new plasticity factor is proposed for the evaluation of the onset of yielding around drilled holes in peened surface layers. This new factor is able to explain the agreement and disagreement found between the IHD residual stresses and those determined by X-ray diffraction in shot-peened steel surfaces.     

Weak basis transformations and texture zeros in the leptonic sector

We investigate the physical meaning of some of the texture zeros which appear in most of the ansatzes on leptonic masses and their mixing. It is shown that starting from arbitrary lepton mass matrices and making suitable weak basis transformations one can obtain some of these sets of zeros, which therefore have no physical content. We then analyse four-zero texture ansatzes where the charged lepton and neutrino mass matrices have the same structure. The four texture zeros cannot be obtained simultaneously through weak basis transformations, so these ansatzes do have physical content. We show that they can be separated into four classes and study the physical implications of each class.     

One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds

One-electron chemical reduction of 10-(dimesitylboryl)-N,N-di-p-tolylbenzo[c]phenanthrene-4-amine (3-B(Mes)₂-[4]helix-9-N(p-Tol)₂) 1 and 13-(dimesitylboryl)-N,N-di-p-tolyldibenzo[c,g]phenanthrene-8-amine (3-B(Mes)₂-[5]helix-12-N(p-Tol)₂) 2 gives rise to monoanions with extensive delocalization over the annulated helicene rings and the boron p_z orbital. Two-electron chemical reduction of 1 and 2 produces open-shell biradicaloid dianions with temperature-dependent population of the triplet states due to small singlet-triplet gaps. These results have been confirmed by single-crystal X-ray diffraction, EPR and UV/vis-NIR spectroscopy, and DFT calculations.

Stepwise chemical reduction of D–π–A triarylborane-based helicenes gives the corresponding monoanions and dianions with delocalized unpaired electrons. The structures were confirmed by single crystal X-ray diffraction.     

Full prediction of the broadband optical modulation performance of a twisted nematic liquid crystal cell

We present a procedure to obtain the physical parameters responsible of twisted nematic liquid crystal (LC) cells optical modulation. The novelty of our approach is based on the use of spectroscopic measurements of the light transmitted by the system polarizer-LC cell-analyzer, combined with a previously proposed simple physical model of the LC twist and tilt distribution along cell. The procedure involves two steps: the first one yields off-state parameters like the LC director orientation, the twist angle, and the optical path difference (cell gap); the second step yields the effective retardances of the central and edge LC layers. The use of a spectroscopic method provides a full characterization of the LC cell as a function of both the voltage and the wavelength. The complete procedure leads to a very accurate prediction of the transmitted light broadband spectrum, as well as the complex (amplitude and phase) modulation for any wavelength within the calibration range.     

Axial coding in full-field microscopy using three-dimensional structured illumination implemented with no moving parts

We report a simple optical setup to produce both axial and lateral structured illumination through a single objective lens. With a minimum of six full-field images obtained without moving either the sample or the microscope objective, 100 nm diameter fluorescent beads can be localized axially with an accuracy of 50 nm in a 1.76-microm-thick layer. We show that this axial localization improvement can easily be combined with classical lateral structured illumination, so that lateral resolution enhancement by a factor of 2 is maintained.     

Optimization of an acoustic test chamber involving the fluid-structure interaction by FEM and experimental validation

The aim of this work is to determine the optimal design of two acoustic test chambers using systems of optimization by means of finite elements. In this way, we have modelled a set of tests composed of a source chamber and a receiving chamber according to the basic requirements of the standard rule. The constructive element whose acoustical behaviour is being evaluated is placed between both chambers. Applying the finite element method (FEM), a two-dimensional coupled finite element model with fluid-structure interaction has been made, using finite elements of the fluid-type both for the air and fluid-structure interface, and finite elements of solid-type with its elastic properties for a multilayered wall. The geometry of the chambers has been parameterized as design variables (DVs) and an objective function has been defined from the absolute value of the difference between the transmission loss (TL) values of the laboratory test and the TL of the numerical simulation in order to minimize it. To find an optimal design of the geometry of the acoustic chamber, a new cascade optimization procedure has been successfully developed. Finally, the numerical simulation results are compared with the acoustic laboratory results, and conclusions are exposed.     

Microwave-assisted multicomponent synthesis of julolidines using silica-supported calix[4]arene as heterogeneous catalyst

The application of immobilizing calixarene onto the surface of silica using a sol-gel method, as an efficient heterogeneous catalyst (CX4SO₃HSi(n)) for multicomponent Povarov reaction has been described. Catalytic activity of the CX4SO₃HSi(n) for the synthesis of julolidines under greener and environmentally benign conditions in simple and efficient method was explored. Notably, only 0.5 mol% of the catalyst is sufficient to catalyze the Povarov solvent-free reaction under microwave-assistance. Besides, this protocol allows the construction of four new C–C bonds and two C–N bonds in a single step. To the best of our knowledge, this consists the first silica support calix[4]arene as a heterogeneous catalyst for multicomponent synthesis of julolidines.     

In situ Electroreduction of Graphene Oxide: Increased Sensitivity for the Determination of NADH

A novel and useful method to catalyze the electro‐oxidation of nicotinamide adenine dinucleotide (NADH) over a glassy carbon electrode (GCE) modified with graphene oxide (GO) is presented. Based on the presence of oxygen moieties in GO, which can be easily reduced, an in situ electrochemical generation of reduced graphene oxide (denoted as erGO) applying a sufficient negative potential. A potential of ?1.000 V was selected to generate the erGO/GCE as a pretreatment potential before the detection of NADH. The in situ generated erGO/GCE system produces a decrease in the overpotential of NADH oxidation from +0.720 V to +0.230 V compared with GCE. The process also produced an important increase in current signals. The modified electrode was characterized by scanning electron (SEM) and electrochemical microscopies (SECM), cyclic voltammetry and by Raman spectroscopy. Amperometric detection of NADH via this straightforward electrocatalytic method provides a wide linear range between 10 and 100 μM, a lower detection limit of 0.36 μM and an excellent sensitivity of (1.47±0.09) μA mM^?1.     

Bond‐Strengthening Backdonation in Aminoborylene‐Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes

Singly NHC‐coordinated (aminoboryl)aminoborenium salts react with Na₂[Fe(CO)₄] to yield stable coordination complexes of aminoborylene‐stabilized aminoborylenes, which exhibit exceptional σ‐donor properties. Upon photolytic CO extrusion from the metal center, the diboron ligand adopts a novel η³‐BBN coordination mode, where bond‐strengthening backdonation from the metal center into the vacant B?B π‐orbital is observed. This bonding situation can be alternatively described as a Fe‐diaminodiborene complex. In a related reduction of CAAC‐stabilized (aminoboryl)aminoborenium with KC₈, the reduced species can be captured with nucleophiles to form three‐coordinate (diaminoboryl)borylenes, where both amino groups have migrated to the distal boron atom. Collectively, these reactions illustrate the isomeric flexibility imparted by amino groups on this reduced diboron system, thus opening multiple avenues of novel reactivity.     

Effect of Diets,Familial History,and Alternative Therapies on Genomic Instability of Breast Cancer Patients

This study evaluates a correlation between family history, micronutrients intake, and alternative therapies with genetic instability, before and during breast cancer treatment. For this study, a total of 150 women were selected. Among those, 50 women were breast cancer patients on chemotherapy, while 50 breast cancer patients were on radiotherapy, and 50 were healthy females. All the participants signed the informed consent form and answered the public health questionnaire. Samples of buccal epithelial and peripheral blood cells were collected and analyzed through micronucleus and comet assays. The cells were evaluated for apoptosis and DNA damage. Results showed the association of patients’ family history with an increase in toxicogenetic damage before and during cancer therapy. On the other hand, patients with late-onset cancer also presented genetic instability before and during therapy, along with those who did not take sufficient vegetables and alternative therapies. A positive correlation was observed between the genetic instability and alternative therapies, while inverse correlation was recorded with the vegetable consumption. Results clearly explain that the nutritional aspects and alternative therapies influence the genetic instability before and during cancer therapies especially in radiotherapy treated patients. Our data could be used for the monitoring therapies and management of breast cancer patients.