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Sabrina M. Nobre Mauro N. Muniz Marcus Seferin Wagner M. da Silva Adriano L. Monteiro 《应用有机金属化学》2011,25(4):289-293
We have developed a sequential and selective Pd‐catalyzed double‐Heck arylation of ethylene that results in non‐symmetrical nitro‐stilbene analogs of trans‐resveratrol at excellent yields. A catalytic system consisting of Pd(OAc)2 and P(o‐tolyl)3 permitted us to carry out the two consecutive Heck arylations without losing activity from the first to the second Heck reaction. After the first Heck arylation of ethylene, no isolation or additional catalyst loading is required for the second Heck arylation reaction. This protocol was applied to the synthesis of methylated trans‐resveratrol, which was obtained at a 65% overall yield. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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Fernandes Felipe Hugo Alencar Boylan Fabio Salgado Hérida Regina Nunes 《Journal of Thermal Analysis and Calorimetry》2018,132(3):1923-1931
Journal of Thermal Analysis and Calorimetry - The solid–liquid phase equilibrium for binary system of 2,4,6-trimethylphenol (TMP) and 2,5-dimethylphenol (DMP) was built by differential... 相似文献
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Felipe Conzuelo María GamellaSusana Campuzano A. Julio ReviejoJosé M. Pingarrón 《Analytica chimica acta》2012
The preparation and performance of a disposable amperometric magneto-immunosensor, involving the use of a selective capture antibody immobilized on the surface of protein G-functionalized magnetic beads (ProtG-MBs) and screen-printed carbon electrodes (SPCEs), for the specific detection and quantification of tetracyclines (TCs) residues in milk is reported. A direct competitive immunoassay using a tracer with horseradish peroxidase (HRP) for the enzymatic labeling was performed. The amperometric response measured at −0.2 V vs. the silver pseudo-reference electrode of the SPCE upon the addition of H2O2 in the presence of hydroquinone (HQ) as redox mediator was used as transduction signal. The developed methodology showed very low limits of detection (in the low ppb level) for 4 tetracycline antibiotics tested in untreated milk samples, and a good selectivity against other antibiotic residues frequently detected in milk and dairy products. The usefulness of the magneto-immunosensor was demonstrated by analyzing UHT whole milk samples spiked with 44 ng mL−1 tetracycline (TC) as well as a reference milk containing a certified oxytetracycline (OTC) content. These features, together with the short analysis time (30 min), the simplicity, and easy automation and miniaturization of the required instrumentation make the developed methodology a promising alternative in the development of devices for on-site analysis. 相似文献
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Felipe BertelliElisangela S. Meza Pedro R. GoulartNoé Cheung Rudimar RivaAmauri Garcia 《Optics and Lasers in Engineering》2011,49(4):490-497
A 3D heat transfer mathematical model based on the finite element method is applied to the laser surface remelting (LSR) process with a view to simulating temperature fields and melt pool dimensions. The theoretical predictions furnished by the model are validated against LSR experimental results from tests carried out in the present study with Al-1.5 wt%Fe alloy samples. The work also encompasses an analysis of microstructural and microhardness variations throughout the resulting treated and untreated zones. A remarkable effect of the LSR treatment on the mechanical and corrosion resistance of the treated samples is shown. 相似文献
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In recent years, a number of articles proposed mathematical models for emergent phenomena. This is the case, for instance for the flocking of birds or the schooling of fish. In particular, in [F. Cucker, S. Smale, Emergent behavior in flocks, IEEE Trans. on Autom. Control 52 (2007) 852–862], a model was proposed for flocking and it was proved that under certain conditions on the initial positions and velocities of the birds, flocking occurs. In this paper we modify this model by adding random noise to it. We prove that, under conditions similar to those just mentioned, (nearly) flocking occurs in finite time with a certain confidence. 相似文献