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161.
Y. Martinez Palenzuela L. Felipe Ruiz A. Karpov W. Greiner 《Bulletin of the Russian Academy of Sciences: Physics》2012,76(11):1165-1171
Decay properties and stability of heaviest nuclei with Z ?? 132 are studied within the macro-microscopical approach for nuclear ground-state masses. We use phenomenological relations for the half-lives with respect to ??-decay, ??-decay and spontaneous fission. Our calculations demonstrate that the ??-stable isotopes 291Cn and 293Cn with a half-life of about 100 years are the longest-living superheavy nuclei located on the first island of stability. We found the second island of stability of superheavy nuclei in the region of Z ?? 124 and N ?? 198. It is separated from the ??continent?? by the ??gulf?? of short-living nuclei with half-lives shorted than 1 ??s. 相似文献
162.
163.
Let G be a finite group and N be a normal subgroup of G. Suppose that the set of G-conjugacy class sizes of N is {1, m, n}, with m?<?n and m does not divide n. In this paper, we show that N is solvable, and we determine the structure of these subgroups. 相似文献
164.
Silva CA Nobre TM Pavinatto FJ Oliveira ON 《Journal of colloid and interface science》2012,365(1):289-295
Thermoplastics have been increasingly used for fabricating microfluidic devices because of their low cost, mechanical/biocompatible attributes, and well-established manufacturing processes. However, there is sometimes a need to integrate such a device with components made from other materials such as polydimethylsiloxane (PDMS). Bonding thermoplastics with PDMS to produce hybrid devices is not straightforward. We have reported our method to modify the surface property of a cyclic olefin copolymer (COC) substrate by using corona discharge and grafting polymerization of 3-(trimethoxysilyl)propyl methacrylate; the modified surface enabled strong bonding of COC with PDMS. In this paper, we report our studies on the surface modification mechanism using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and contact angle measurement. Using this bonding method, we fabricated a three-layer (COC/PDMS/COC) hybrid device consisting of elastomer-based valve arrays. The microvalve operation was confirmed through the displacement of a dye solution in a fluidic channel when the elastomer membrane was pneumatically actuated. Valve-enabled microfluidic handling was demonstrated. 相似文献
165.
Carrillo N León-Silva U Avalos T Nicho ME Serna S Castillon F Farias M Cruz-Silva R 《Journal of colloid and interface science》2012,369(1):103-110
The chemical and enzymatic deposition of polyaniline (PANI) films by in situ polymerization was studied and the resulting films were characterized. The film formation and polymerization processes were simultaneously monitored by the evolution of the open circuit potential and quartz-crystal microbalance measurements. Different substrates, such as Indium-Tin oxide electrodes and gold-coated quartz-crystal electrodes were used as substrates for PANI deposition. Electroactive PANI films were successfully deposited by in situ enzymatic polymerization at low oxidation potential. The electrogravimetric response of the enzymatically deposited PANI film was studied by cyclic voltammetry in monomer-free acidic medium. The morphology of the films was observed by scanning electron microscopy, revealing a granular structure in enzymatically deposited PANI. The PANI films were also characterized by thermogravimetric analysis, electrochemical impedance spectroscopy, and X-ray photoelectron and Fourier-transformed infrared spectroscopy. The simultaneous use of quartz crystal microbalance and open circuit potential is presented as a very useful technique to monitor enzymatic reactions involving oxidoreductases. 相似文献
166.
Joana Monterrosa José Daniel Martínez Mary Lorena Araujo Felipe Brito Giuseppe Lubes Mildred Rodríguez Lino Hernández Vito Lubes 《Journal of solution chemistry》2012,41(4):589-598
We studied speciation of the mixed-ligand complex formation equilibria of vanadium(III) with both 2,2??-bipyridine (Bipy) and the amino acids glycine (HGly), proline (HPro), ??-alanine (H??Ala), and ??-alanine (H??Ala) by means of electromotive forces measurements emf(H) using 3.0?mol?dm?3 KCl as the ionic medium at 25 °C. The experimental data were analyzed by means of the computational least-squares program LETAGROP, taking into account the hydrolysis of the vanadium(III) cation, the respective stability constants of the binary complexes, and the acid/base reactions of the ligands which were kept fixed during the analysis. In all four amino acid systems studied we observed the complexes [V2O(Bipy)(B)]3+, [V2O(Bipy)2(B)2]2+, [V(OH)(Bipy)(B)2] and [V(OH)2(Bipy)(B)], where B represents the deprotonated form of the amino acids studied in this work. The respective stability constants were determined and the species distribution diagrams as a function of pH are briefly discussed. 相似文献
167.
Two different D‐dimer disposable amperometric immunosensing designs based on indirect competitive or sandwich formats and the use of carboxylic acid‐modified magnetic beads (COOH‐MBs) and screen‐printed carbon electrodes (SPCEs) have been developed and compared. In both approaches, the resulting modified MBs were magnetically captured on the surface of a SPCE which was used as the transducer for the electrochemical detection at ?0.20 V upon addition of H2O2, and hydroquinone (HQ). Both configurations exhibited linear ranges of clinical usefulness and detection limits quite below the clinical threshold (0.5 µg mL?1 D‐dimer). The sandwich configuration has been successfully tested with serum samples. 相似文献
168.
We prove that a form of finite Galois descent obstruction is the only obstruction to the existence of integral points on integral
models of twists of modular curves over function fields. 相似文献
169.
170.
The same shot-peening treatment was applied to five steels with different mechanical properties. The induced residual stress profiles were analyzed using X-ray diffraction and incremental hole drilling (IHD). The results of both techniques showed that IHD can still be successfully used for measuring shot-peening residual stresses, even if these exceed the yield strength of the bulk material. Expected errors due to the plasticity effect are reduced by the strain hardening of the surface. For an assessment of the reliability of IHD data, strain-hardening variation was quantified by microhardness measurements to estimate the yield strength of the plastified layer. All the main calculation methods for IHD were applied. The results were compared and discussed with respect to the characteristics of each method. 相似文献