Effectiveness of initiation in the reaction of cumene hydeopeeoxide with paramethoxyphenol

Conclusions It was shown by a study of the kinetics of the oxidation of cumene in the presence of the hyeroperoxide and p-methoxyphenol that in the reaction of the hydroperoxide with p-methoxyphenol, radicals are formed with an efficiency equal to 0.54 (120°).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2191–2194, October, 1972.     

Synthesis and properties of silacyclobutylsilazanes

Ammonolysis of silacyclobutanes {ie305-01} (R=Cl, CH₃) gives silacyelobutane di- and polysilazanes. Reaction of the disilazane {ie305-02} with 1-chloro-1-methyl-1-silacyelobutane at 20–80° gives a trisilyl-substituted amine {ie305-03}. Trisilyl-substituted amines with one silacyclobutyl group, are obtained by reacting silacyclobutanes {ie305-04} (R=CH₃, C₆H₅). with sodium or potassium silylamides prepared from hexamethyldisilazane. It is shown that it is possible to obtain silylamides by reacting disilazanes directly with potassium metal at 90–100°.     

Aggregation des menschlichen Serumalbumins unter den Bedingungen der W ärmedenaturierung

Ohne Zusammenfassung     

Controlled vesicle self-assembly in microfluidic channels with hydrodynamic focusing

Traditional liposome preparation methods are based on mixing of bulk phases, leading to inhomogeneous chemical and/or mechanical conditions during formation; hence liposomes are often polydisperse in size and lamellarity. Here we show the formation of liposomes that encapsulate reagents in a continuous two-phase flow microfluidic network with precision control of size from 100 to 300 nm by manipulation of liquid flow rates. We demonstrate that by creating a solvent-aqueous interfacial region in a microfluidic format that is homogeneous and controllable on the length scale of a liposome, we can facilitate the fine control of liposome size and polydispersity.     

Unusual Thermolysis of Diisobutyl Polysulfides

Russian Journal of Organic Chemistry -