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81.
Sergey V. Rashchenko Tatyana B. Bekker Vladimir V. Bakakin Yurii V. Seryotkin Alexander E. Kokh Peter Gille Arthur I. Popov Pavel P. Fedorov 《Journal of Applied Crystallography》2013,46(4):1081-1084
A comprehensive study of the BaF2–Ba3(BO3)2 phase diagram has revealed a significant difference between the two intermediate phases Ba5(BO3)3F and Ba7(BO3)4−yF2+3y. The latter exhibited (BO3)3−↔ 3F− anionic substitution which, unusually, strongly influences the solidus temperature. A comparison of the Ba5(BO3)3F and Ba7(BO3)4−yF2+3y crystal structures, along with consideration of other compounds demonstrating (BO3)3−↔ 3F− isomorphism, allows for the disclosure of the mechanism of (BO3)3−↔ 3F− heterovalent anionic substitution in fluoride borates via [(BO3)F]4− tetrahedral groups being replaced by four fluoride anions. No exception to this mechanism has been discovered among all known phases with (BO3)3−↔ 3F− substitution. 相似文献
82.
83.
Fedorov S. N. Kuzmich A. S. Agafonova I. G. Sabutskii Yu. E. Guzii A. G. Popov R. S. Ogurtsov V. A. Rakitin O. A. Polonik S. G. 《Russian Chemical Bulletin》2022,71(3):489-495
Russian Chemical Bulletin - Nucleophilic substitution of the chlorine atom in 4,5-dichloro-1,2-dithiol-3-one using 1-thio-β-d-glucopyranose and its 2,3,4,6-tetra-O-acetyl derivative in... 相似文献
84.
Sorokin N. I. Gaynutdinov R. V. Voronov V. V. Chernova E. V. Fedorov P. P. 《Crystallography Reports》2021,66(1):126-129
Crystallography Reports - The electrical conductivity of natural samples of exogenous silicides has been studied. In the temperature range of 515?700 K, the conductivity increases from 1.1... 相似文献
85.
N. V. Tepliakov M. Yu. Leonov A. V. Baranov A. V. Fedorov I. D. Rukhlenko 《Optics and Spectroscopy》2017,122(1):101-105
We have considered the broadening of optical absorption spectra of ensembles of randomly oriented nanorods and nanoplatelets that is caused by the action of a static electric field. It has been found that the linewidth in the spectra of the considered nanocrystals depends nonlinearly on the field strength and attains saturation in fields on the order of 100 kV/cm. We show that, due to a weak confinement, the electrooptical response of nanoplatelets is stronger than that of nanorods, which leads to a number of distinctive features in the field-induced broadening of the spectra of nanoplatelets and gives grounds to state that nanoplatelets are the most promising objects for use in electrooptical devices. 相似文献
86.
The response of the electrons of an fcc copper (001) film to an external electrostatic field is calculated. In order to determine the distribution of the screening charge, the equations of the electron density-functional theory are solved self-consistently by an original method. The position of the “image plane,” which is involved in a correct asymptotic expression for the exchange-correlation potential in the vacuum region, is first determined when performing a quantum-mechanical calculation for an anisotropic crystal film. The nonlinear electron response is characterized by the evolution of the “center of gravity” of the induced charge, which is also investigated. The calculations take into account the crystal structure of the film, and the results differ essentially from the predictions of the “jelly” model. 相似文献
87.
88.
V. V. Fedorov 《Computational Mathematics and Modeling》1992,3(1):1-10
Translated from Vychislitel'nye Kompleksy i Modelirovanie Slozhnykh Sistem, pp. 55–70, Moscow State University, 1989. 相似文献
89.
Complexes of weakly coupled moving solitons are found by numerical solution of the generalized Ginzburg-Landau equation for the transversely one-dimensional scheme of a wide-aperture A-class laser with saturable absorption. As distinct from the case of complexes of motionless solitons, the phase difference between the neighboring moving solitons is close to 7π/2. 相似文献
90.
Technical Physics - In this paper, we present the results of numerical simulation of explosive formation of a high-speed compact element from copper, steel, and aluminum cumulative liners combining... 相似文献