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41.
Invariant subspaces and eigenfunctions of regular Hecke operators acting on spaces spanned by products of even number of Igusa theta constants with rational characteristics are constructed. For some of the eigenfunctions of genuses g=1 and g=2, corresponding zeta functions of Hecke and Andrianov are explicitly calculated. 相似文献
42.
43.
Selberg-type integrals that can be turned into constant term identities for Laurent polynomials arise naturally in conjunction with random matrix models in statistical mechanics. Built on a recent idea of Karasev and Petrov we develop a general interpolation based method that is powerful enough to establish many such identities in a simple manner. The main consequence is the proof of a conjecture of Forrester related to the Calogero–Sutherland model. In fact we prove a more general theorem, which includes Aomoto's constant term identity at the same time. We also demonstrate the relevance of the method in additive combinatorics. 相似文献
44.
In 1997 Lampert and Slater introduced parallel knock-out schemes, an iterative process on graphs that goes through several rounds. In each round of this process, every vertex eliminates exactly one of its neighbors. The parallel knock-out number of a graph is the minimum number of rounds after which all vertices have been eliminated (if possible). The parallel knock-out number is related to well-known concepts like perfect matchings, hamiltonian cycles, and 2-factors.We derive a number of combinatorial and algorithmic results on parallel knock-out numbers: for families of sparse graphs (like planar graphs or graphs of bounded tree-width), the parallel knock-out number grows at most logarithmically with the number n of vertices; this bound is basically tight for trees. Furthermore, there is a family of bipartite graphs for which the parallel knock-out number grows proportionally to the square root of n. We characterize trees with parallel knock-out number at most 2, and we show that the parallel knock-out number for trees can be computed in polynomial time via a dynamic programming approach (whereas in general graphs this problem is known to be NP-hard). Finally, we prove that the parallel knock-out number of a claw-free graph is either infinite or less than or equal to 2. 相似文献
45.
Laura Gherardi Daniela Bettinelli Sergio Spreafico Fedor G m ry 《Physica C: Superconductivity and its Applications》1998,310(1-4):52-56
Transport AC losses measured in self-field conditions on multifilamentary Bi-2223 tapes are often found to be lower than those calculated within the framework of the critical state model for a bulk wire with elliptical cross section, though generally higher than predicted for a strip. This effect is sometimes ascribed to the non-ideal geometry of the tapes, which does not exactly reproduce either shape. Here we propose an alternative explanation assuming that the critical current density of superconducting material depends on magnetic field. In practice, we analyzed the AC loss curve and deduced different Ic values for the individual data points, using the standard Norris equation for elliptical conductor. This gives the relation between ‘calculated' Ic and the self-field associated to AC transport current, which can be regarded as an alternative way to qualify the dependence of Jc on magnetic field. Important is that this procedure covers the range of fields below the self-field at Ic where the measurement in background DC field can not be used to determine Jc(B). 相似文献
46.
Received: 17 March 1997/Revised version: 21 July 1997 相似文献
47.
Vasilii Yu. Evtushok;Olga V. Zalomaeva;Kirill P. Larionov;Irina D. Ivanchikova;Nataliya V. Maksimchuk;Fedor S. Kozulin;Yurii A. Chesalov;Oxana A. Kholdeeva; 《应用有机金属化学》2024,38(7):e7549
A mixed Ti,Zr-based metal–organic framework, PCN-415 (Porous Coordination Network), and the corresponding Ti,Zr-oxocluster [Ti8Zr2O12(CH3COO)16] have been synthesized and comprehensively characterized by powder X-Ray diffraction (PXRD), low-temperature nitrogen adsorption, scanning electron microscopy, thermogravimetric analysis, Fourier-transform infrared spectroscopy, and Raman spectroscopy. The catalytic performance of both PCN-415 and the Ti,Zr-oxocluster was evaluated in the selective oxidation of representative thioethers, alkenes, and alkylphenols using aqueous hydrogen peroxide and tert-butyl hydroperoxide as oxidants. The nature of the oxidation products formed indicates that, most likely, both Ti and Zr sites contribute to the catalytic activity of PCN-415, although the contribution of Ti seems to be more significant. Examination of PCN-415 after treatment with H2O2 using diffuse reflectance UV–vis spectroscopy indicates the formation of Ti peroxo complexes while Raman spectroscopy shows evidence for the formation of both Ti and Zr peroxo species. The potential formation of missing linker-type defects and their role in facilitating catalytic activity were addressed. The stability of the PCN-415 structure under the catalytic conditions was confirmed by PXRD. The absence of metal leaching and the heterogeneous nature of the catalysis were verified. The catalyst could be easily recovered from the reaction mixture and reused several times without loss of the catalytic properties. 相似文献
48.
Dr. Sebastian Armin Schwengers Dr. Gabriela Guillermina Gerosa Dr. Tynchtyk Amatov Dr. Naoki Yasukawa Sebastian Brunen Dr. Markus Leutzsch Benjamin Mitschke Dr. Grigory André Shevchenko Prof. Dr. Dr. h.c. Benjamin List 《Angewandte Chemie (International ed. in English)》2023,62(35):e202307081
We disclose a highly regioselective, catalytic one-step dehydrogenation of α-substituted cyclic ketones in the presence of 2,3-dichlorobenzo-5,6-dicyano-1,4-benzoquinone (DDQ). The high regioselectivity originates from a phosphoric acid-catalyzed enolization, selectively affording the thermodynamically preferred enol, followed by the subsequent oxidation event. Our method provides reliable access to several α-aryl and α-alkyl substituted α,β-unsaturated ketones. 相似文献
49.
Yuliya E. Ryzhkova Fedor V. Ryzhkov Michail N. Elinson Oleg I. Maslov Artem N. Fakhrutdinov 《Molecules (Basel, Switzerland)》2023,28(1)
Chromeno[2,3-b]pyridines are substances demanded in medicinal and material chemistry. PASE (pot, atom, and step economy) and in particular one-pot approaches are key green chemistry techniques that are applied for the synthesis of heterocyclic compounds. In this case, the PASE approach was extended with ‘component economy’, as solvent was used also as reactant (solvent-involved reaction). This approach was adopted for the one-pot synthesis of previously unknown O-substituted 5-alkoxy-5H-chromeno[2,3-b]pyridines via two-step transformation, namely the reaction of salicylaldehydes and malononitrile dimer, with the subsequent addition of alcohol. The mechanistic studies revealed the possibility of concurrent reaction. The studies aided in optimizing the reaction conditions for the best yields (77–93%). Thus, the one-pot reaction proceeds efficient and quickly, and the work-up procedure (only simple filtering) is very convenient. The structure of synthesized chromeno[2,3-b]pyridines was confirmed by 2D NMR spectroscopy. 相似文献
50.