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31.
Saddam Saqib Wajid Zaman Fazal Ullah Imran Majeed Asma Ayaz Muhammad Farooq Hussain Munis 《应用有机金属化学》2019,33(11)
The ever‐increasing resistance of plant microbes towards fungicides and bactericides has been causing serious threat to plant production in recent years. For the development of an effective antifungal agent, we introduce a novel hydrothermal protocol for synthesis of chitosan iron oxide nanoparticles (CH‐Fe2O3 NPs) using acetate buffer of low pH 5.0 for intermolecular interaction of Fe2O3 NPs and CH. The composite structure and elemental elucidation were carried out by using X‐ray power diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X‐ray (EDX), Transmission Electron Microscopy (TEM), Fourier Transformed Infrared Spectroscopy (FTIR) and Ultraviolet Visible Absorption Spectroscopy (UV–vis spectroscopy). Additionally, antifungal activity was evaluated both In vitro and In vivo against Rhizopus oryzae which is causing fruit rot disease of strawberry. We compared different concentrations (0.25%, 0.50%, 075% and 1%) of CH‐Fe2O3 NPs and 50% synthetic fungicide (Matalyxal Mancozab) to figure out suitable concentration for application in the field. XRD analysis showed a high crystalline nature of the NPs with average size of 52 nanometer (nm). SEM images revealed spherical shape with size range of 50–70 nm, whereas, TEM also revealed spherical shape, size ranging from 0 nm to 80 nm. EDX and FTIR results revealed presence of CH on surface of Fe2O3 NPs. The band gap measurement showed peak 317–318 nm for bare Fe2O3 NPs and CH‐Fe2O3 NPs respectively. Antifungal activity in both In vitro and In vivo significantly increased with increase in concentration. The overall results revealed high synergetic antifungal potential of organometallic CH‐Fe2O3 NPs against Rhizopus oryzae and suggest the use of CH‐Fe2O3 NPs against other Phyto‐pathological diseases due to biodegradable nature. 相似文献
32.
33.
Inam ul Haq Raja Jae Yeol Lee In Tae Kim So Ha Lee 《Monatshefte für Chemie / Chemical Monthly》2008,139(7):725-737
Much effort has been devoted to the design and synthesis of polymers for use in flat panel display, solid state lighting,
transistors, and photovoltaic devices. Especially, development of white light emitting polymeric materials has recently attracted
much interest owing to their possible use in lighting application and backlights for flat panel displays. White emission has
been obtained from polymeric molecules, small organic molecules, organometallic molecules, and phosphor-based or quantum dot-based
inorganic molecules. Among materials used in white light emitting diodes, we summarize the white light emitting polymeric
materials synthesized and published till December 2007.
Correspondence: In Tae Kim, Department of Chemistry, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Ku, Seoul 139-701, Korea,
So Ha Lee, Life Sciences Research Division, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130-650,
Korea. 相似文献
34.
Tanveer ul Haq Zia Ahmad Nawaz Khan Majid Hussain Ibrar Hassan Iftikhar Hussain Gul 《高分子科学》2016,34(12):1500-1509
The dielectric and mechanical properties of hybrid polymer nanocomposites of polystyrene/polyaniline/carbon nanotubes coated with polyaniline(PCNTs) have been investigated using impedance analyzer and extensometer. The blends of PS/PANI formed the heterogeneous phase separated morphology in which PCNTs are dispersed uniformly. The incorporation of a small amount of PCNTs into the blend of PS/PANI has remarkably increased the dielectric properties. Similarly, the AC conductivity of PS/PANI is also increased five orders of magnitude from 1.6 × 10~(-10) to 2.0 × 10~(-5) S·cm~(-1) in the hybrid nanocomposites. Such behavior of hybrid nanocomposites is owing to the interfacial polarization occurring due to the presence of multicomponent domains with varying conductivity character of the phases from insulative PS to poor conductor PANI to highly conductive CNTs. Meanwhile, the tensile modulus and tensile strength are also enhanced significantly up to 55% and 160%, respectively, without much loss of ductility for three phase hybrid nanocomposites as compared to the neat PS. Thereby, the hybrid nanocomposites of PS/PANI/_P CNTs become stiffer, stronger and tougher as compared to the neat systems. 相似文献
35.
Atta‐ur‐Rahman Zaheer‐ul‐Haq Asaad Khalid Shazia Anjum M.Riaz Khan M.Iqbal Choudhary 《Helvetica chimica acta》2002,85(2):678-688
Phytochemical investigation of Sarcococca saligna by extensive bioassay‐guided fractionation resulted in the isolation of the pregnane‐type steroidal alkaloids 1 – 15 , i.e. of the five new compounds 1 – 5 and the ten known alkaloids 6 – 15 . The structures of the new alkaloids salignenamide C ( 1 ), salignenamide D ( 2 ), 2β‐hydroxyepipachysamine D ( 3 ), salignenamide E ( 4 ), and salignenamide F ( 5 ) were elucidated with the help of modern spectroscopic techniques, while the known alkaloids axillarine C ( 6 ), axillarine F ( 7 ), sarcorine ( 8 ), N3‐demethylsaracodine ( 9 ), saligcinnamide ( 10 ), salignenamide A ( 11 ), vaganine A ( 12 ), axillaridine A ( 13 ), sarsalignone ( 14 ), and sarsalignenone ( 15 ) were identified by comparing their spectral data with those reported earlier. Inhibition of electric‐eel acetylcholinesterase (EC 3.1.1.7) and horse‐serum butyrylcholinesterase (EC 3.1.1.8) by alkaloids 1 – 15 were investigated. These new cholinesterase inhibitors may act as potential leads in the discovery of clinically useful inhibitors for nervous‐system disorders, particularly by reducing memory deficiency in Alzheimer's disease patients by potentiating and effecting the cholinergic transmission process. These compounds were found to inhibit both enzymes in a concentration‐dependent fashion with the IC50 values ranging from 5.21–227.92 μM against acetylcholinesterase and 2.18–38.36 μM against butyrylcholinesterase. 相似文献
36.
Bushra Hafeez Kiani Nazif Ullah Ihsan-ul Haq Bushra Mirza 《Arabian Journal of Chemistry》2019,12(8):2644-2654
The rol genes have been shown to enhance the production of secondary metabolites in plants. This report examines the effect of trans-genes (rol ABC) on possible high production of biologically important phytochemicals and enhanced pharmacological activities. Three transgenic lines (1, 2 and 3) of Artemisia dubia WALL (transformed with Agrobacterium tumefaciens harboring rol ABC genes) were subjected to phytochemical analysis and pharmacological studies. A great variation in phytochemistry and the pharmacological activities was observed not only between the transgenic and non-transgenic control plants but also among the transgenic lines itself. Comparative chemical profile obtained via HPLC, TLC and spectrophotometry showed high degree of variations in the quantity of phytochemicals. An increased production of total flavonoids (71.1% in transgenic line 2) and total phenolics (110.8% in transgenic line 1), increase in caffeic acid and catechin and a decrease in gallic acid content in the extracts of transformed plants compared to the untransformed control plants was decreased. In case of pharmacological activities, moderate to high level increase in antimicrobial (antibacterial and antifungal) activities, cytotoxicity (14.1%), antitumor (29%) and antioxidant activities (23.9%) was observed (in transgenic line 2). In general all the three transgenic lines under study showed improvement in their pharmacological activities in the order of transgenic line 2 > 1 > 3 > control. The implication of these findings will help to meet the increasing demand of pharmacologically important compounds. 相似文献
37.
We assume generalized ghost Pilgrim dark energy (GGPDE) model in the presence of cold dark matter in flat FRW universe. With suitable choice of interaction term between GGPDE and cold dark matter, we investigate the nature of equation of state parameter for GGPDE. Also, we investigate the natures of dynamical scalar field models (such as quintessence, tachyon, k-essence, and dilaton dark energy) and concerned potentials through the correspondence phenomenon between GGPDE and these models. 相似文献
38.
A. Nadeem M. Nawaz S. U. Haq S. Shahzada M. A. Baig 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2009,53(2):147-151
We report term energies and quantum defects of highly excited even-parity states of mercury in the 83 876–84 140 cm-1 energy range, employing a two-step laser excitation scheme via the S0↦6s6p3P1 inter-combination transition. Two dye lasers, pumped by a common Nd:YAG laser, were frequency doubled by BBO crystals and
used to record the spectra in conjunction with a thermionic diode ion detector. Our new observations include the much extended
D2 (22 ≤n ≤52) series and a few members of the S1 (24 ≤n ≤30) Rydberg series. Members of the D2 Rydberg series with such a high n value are reported for the first time. The relative intensities of the D2 and S1 transitions (m = 4, 5 and 6) of group II-B elements excited from the P1 inter-combination states are also discussed. 相似文献
39.
Fazal M. Mahomed I. Naeem Asghar Qadir 《Nonlinear Analysis: Real World Applications》2009,10(6):3404-DECMA
We provide linearizability criteria for a class of systems of two third-order ordinary differential equations that is cubically nonlinear in the first derivative, by differentiating a system of second-order quadratically nonlinear ordinary differential equations and using the original system to replace the second derivatives. The procedure developed splits into two cases: those for which the coefficients are constant and those for which they are variables. Both cases are discussed and examples given. 相似文献
40.
The present article investigates the dual nature of the solution of the magneto- hydrodynamic (MHD) stagnation-point flow of a Prandtl fluid model towards a shrinking surface. The self-similar nonlinear ordinary differential equations are solved numerically by the shooting: method. It is found that the dual solutions of the flow exist for cer- tain values of tile velocity ratio parameter. The special case of the first branch solutions (the classical Newtonian fluid model) is compared with the present numerical results of stretching flow. The results are found to be in good agreement. It is also shown that the boundary layer thickness for the second solution is thicker than that for the first solution. 相似文献