全文获取类型
收费全文 | 221篇 |
免费 | 2篇 |
专业分类
化学 | 97篇 |
力学 | 5篇 |
数学 | 45篇 |
物理学 | 76篇 |
出版年
2022年 | 2篇 |
2021年 | 2篇 |
2019年 | 3篇 |
2016年 | 2篇 |
2015年 | 4篇 |
2014年 | 3篇 |
2013年 | 40篇 |
2012年 | 5篇 |
2011年 | 8篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 8篇 |
2006年 | 5篇 |
2005年 | 12篇 |
2004年 | 6篇 |
2002年 | 5篇 |
2001年 | 6篇 |
2000年 | 10篇 |
1999年 | 2篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 8篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 8篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1969年 | 1篇 |
1959年 | 1篇 |
1934年 | 2篇 |
1933年 | 2篇 |
1910年 | 1篇 |
1899年 | 1篇 |
排序方式: 共有223条查询结果,搜索用时 15 毫秒
111.
Today's analytical laboratory uses a large number of different instruments that are connected in networks. Together with increasing automation, data are produced at a rate that can easily reach gigabytes per month, which generates the problem of systematic archival. In addition, working under Good Laboratory Practice requires that archival of raw data be performed in such a way that they can be readily retrieved upon request, even years later. While systematic archival of data is already performed in most laboratories, it is the retrieval of saved information that is often far from straightforward. This paper describes a simple but systematic approach for both archival and retrieval of data files and related electronic documents. It consists of an unambiguous scheme for the naming of electronic files, an efficient backup strategy, a simple database holding information about any data acquired, and a convenient interface to this database that can be accessed from any workplace while assuring restricted access. The system is capable of handling several databases concurrently and is used in our facility to archive data from several workgroups. The use of freely available software such as the Linux operating system made it possible to implement a fast and stable solution at exceptionally low cost. 相似文献
112.
Douglas P. Hoffmann Andrew Proctor Martin J. Fay David M. Hercules 《Mikrochimica acta》1990,100(5-6):327-341
Boron modified Co/Al2O3 catalysts, previously characterized by ESCA, are examined by EXAFS. A method of data analysis based on cross-correlation of the (E) spectra is used to determine the relative amounts of Co3O4 and cobalt surface phase present on the catalysts. The results are compared with those obtained previously by ESCA. The EXAFS analysis agrees well with the ESCA results. No gas-phase reactions were required to elucidate the relative proportion of cobalt species by EXAFS as is necessary for the ESCA analysis. 相似文献
113.
Seery MK Fay N McCormac T Dempsey E Forster RJ Keyes TE 《Physical chemistry chemical physics : PCCP》2005,7(19):3426-3433
The interactions between luminophore [Ru(bpy)3]2+, and the lacunary Dawson heteropolyanions, [P2W17O61(FeOH2)]7-, [P2W17O61(FeBr)]6- and [P2W17O61]10- were investigated using a combination of photophysics, optical and Raman spectroscopy. Extensive quenching of the excited state of [Ru(bpy)3]2+ was observed in each case. Quenching is attributed to the formation of association complexes between [Ru(bpy)(3)]2+ and the heteropolyanions in which the charge on the heteropolyanions is fully compensated for by the ruthenium polypyridyl species. The interaction appears to be principally electrostatic in nature producing [Ru(bpy)3]3.5[P2W17O61(FeOH2)], [Ru(bpy)3]3[P2W17O61(FeBr)] and [Ru(bpy)3]5[P2W17O61]10-. The association constants for formation of the clusters were obtained from photophysical studies and surprisingly, despite the electrostatic nature of the interaction, there was no correlation between the charge on the polyoxometallate and the association constant. In particular, the unsubstituted lacunary, [P2W17O61]10-, showed considerably weaker association compared to the transition metal substituted lacunaries, in spite of its 10- charge. Difference absorption spectroscopy revealed a new transition at ca. 480 nm for each of the cluster complexes. From resonance Raman spectroscopy the origin of this transition was found to involve the polyoxometallate. Unlike previously reported adducts, the cluster complexes formed were not luminescent. In all cases the cluster complexes exhibit remarkable photostability, with no photodecomposition or photo-induced ligand exchange reactions evident in acetonitrile, under conditions where [Ru(bpy)3]2+ alone exhibits considerable photolability. 相似文献
114.
115.
116.
Gerbaux P Dechamps N Flammang R Nam PC Nguyen MT Djazi F Berruyer F Bouchoux G 《The journal of physical chemistry. A》2008,112(24):5418-5428
The C2H4NO(+) system has been examined by means of quantum chemical calculations using the G2 and G3B3 approaches and tandem mass spectrometry experiments. Theoretical investigation of the C2H4NO(+) potential-energy surface includes 19 stable C2H4NO(+) structures and a large set of their possible interconnections. These computations provide insights for the understanding of the (i) addition of the nitrosonium cation NO(+) to the ethylene molecule, (ii) skeletal rearrangements evidenced in previous experimental studies on comparable systems, and (iii) experimental identification of new C2H4NO(+) structures. It is predicted from computation that gas-phase nitrosation of ethylene may produce C2H4(*)NO(+) adducts, the most stable structure of which is a pi-complex, 1, stabilized by ca. 65 kJ/mol with respect to its separated components. This complex was produced in the gas phase by a transnitrosation process involving as reactant a complex between water and NO(+) (H2O.NO(+)) and the ethylene molecule and fully characterized by collisional experiments. Among the other C 2H 4NO (+) structures predicted by theory to be protected against dissociation or isomerization by significant energy barriers, five were also experimentally identified. These finding include structures CH3CHNO(+) (5), CH 3CNOH (+) ( 8), CH3NHCO(+) (18), CH3NCOH(+) (19), and an ion/neutral complex CH2O...HCNH(+) (12). 相似文献
117.
We use numerical integrations to study the asymptotical behaviour of a homogeneous but anisotropic Bianchi type IX model in General Relativity with a massive scalar field. As it is well known, for a Brans-Dicke theory, the asymptotical behaviour of the metric functions is ruled only by the Brans-Dicke coupling constant 0 with respect to the value –3/2. In this paper we examine if such a condition still exists with a massive scalar field. We also show that, contrary to what occurs for a massless scalar field, the singularity oscillatory approach may exist in the presence of a massive scalar field having a positive energy density. 相似文献
118.
Assuming fast spatial energy diffusion among the donor ions, the rate equations are shown to yield the linear concentration dependence of the quenching rate observed in highly concentrated rare earth compounds, such as NdP5O14. This concentration dependence is not related to the particular form of the interionic interaction responsible for the quenching. We also supply new experimental data confirming the linear behavior in NdxRE1?xP5O14 (RE = La, Eu, Tb) for 0.01 ? x ?1. 相似文献
119.
120.