首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10453篇
  免费   445篇
  国内免费   128篇
化学   7376篇
晶体学   92篇
力学   510篇
综合类   3篇
数学   1274篇
物理学   1771篇
  2024年   24篇
  2023年   93篇
  2022年   474篇
  2021年   434篇
  2020年   360篇
  2019年   445篇
  2018年   450篇
  2017年   370篇
  2016年   606篇
  2015年   420篇
  2014年   572篇
  2013年   1068篇
  2012年   816篇
  2011年   774篇
  2010年   558篇
  2009年   451篇
  2008年   496篇
  2007年   439篇
  2006年   311篇
  2005年   318篇
  2004年   193篇
  2003年   192篇
  2002年   160篇
  2001年   83篇
  2000年   55篇
  1999年   64篇
  1998年   41篇
  1997年   52篇
  1996年   48篇
  1995年   35篇
  1994年   39篇
  1993年   20篇
  1992年   37篇
  1991年   33篇
  1990年   30篇
  1989年   36篇
  1988年   33篇
  1987年   34篇
  1986年   30篇
  1985年   37篇
  1984年   35篇
  1983年   21篇
  1982年   28篇
  1981年   19篇
  1980年   23篇
  1979年   20篇
  1978年   18篇
  1977年   13篇
  1976年   15篇
  1974年   16篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
Compared to classical spatially separated multiple antenna system, cross-polarized co-located antenna systems are an interesting way to reduce equipment size while reducing the inter-antenna correlation. In this paper the spectrum sensing of a Cognitive Radio (CR) system taking advantage of polarization diversity under Rayleigh fading is investigated and compared to an equivalent system using spatial diversity. This analysis is based on a theoretical formulation applied to a real-world scenario. For this purpose, an outdoor-to-indoor measurement campaign at a frequency of 3.5 GHz is realized, where an indoor secondary user senses the signals received from an outdoor primary base station. The signals received at each antenna are first combined and then applied to an energy detector. The theoretical expressions are simulated in the measurement context. The detection probability behavior as a function of distance between the Primary Transmitter (PTx) and the Secondary Terminal (STE) and the inter-antenna correlation effect on the sensing performance are studied.  相似文献   
72.
We study brane inflation in a warped deformed conifold background that includes general possible corrections to the throat geometry sourced by coupling to the bulk of a compact Calabi–Yau space. We focus specifically, on the perturbation by chiral operator of dimension 3/2 in the CFT. We find that the effective potential in this case can give rise to required number of e-foldings and the spectral index nSnS consistent with observation. The tensor to scalar ratio of perturbations is generally very low in this scenario. The COBE normalization, however, poses certain difficulties which can be circumvented provided model parameters are properly fine tuned. We find the numerical values of parameters which can give rise to enough inflation, observationally consistent values of density perturbations, scalar to tensor ratio of perturbations and the spectral index nSnS.  相似文献   
73.
Ali Dogan 《哲学杂志》2019,99(3):267-283
Because of the increasing complexity and cost of experiments carried out, the data for the multi-component alloy systems have frequently been obtained by numerical modelling. It is clear that the related calculations require reliable data dealing with the pure components and binary alloy systems. Selecting the reliable data concerning the pure components from the literature, the viscosities for the SAC and (SAC)1?x Cox solder alloys have been calculated using different viscosity models (geometric and physical). The viscosity decreases as the amount of tin content increases in the SAC387 alloy while the addition of the cobalt to SAC387 solder results in the increasing of the viscosity. Moreover, by computing the root mean square values between theoretical and experimental viscosities, it can be concluded that the lowest value among all models is that of obtained by Kaptay equation.  相似文献   
74.
Sulphate and chloride concentrations in the shallow Pleistocene aquifer systems in the lower Jordan valley area indicate a general trend of increasing salinity eastward and southward. This study was conducted in one of the important sub-basins feeding the Pleo–Pleistocene aquifer in the Jericho area in the southern part of the valley using S and O isotopes of dissolved sulphate. The results show that sulphate has mainly two contributions to the groundwater. One is the surface seepage, which is present as a salty leachate form with the positive δ34Ssulphate values of primary gypsum in Lisan and Samara formations, and the second is the upwelling saline water which was in contact with a deep secondary gypsum, aragonites and salty rocks and rose up under heavy abstraction with depleted 34S in sulphate and relatively high sulphate and chloride content. The latest was clearly shown in the Arab Project wells to the east that is undergoing a continuous heavy abstraction. The isotopic signatures of S and O in these wells to the east show that this depleted 34S and highly concentrated sulphate might also indicate a dissolved sulphate originating from pyrite oxidation that results from the interaction with a pyrite-rich aquifer, which can well up with salty water under heavy abstraction and is oxidised in the upper aerobic shallow aquifer.  相似文献   
75.
A blend/clay nanocomposites of 50/50 (wt%) NR/SBR was prepared via mixing the latex of a 50/50 NR/SBR blend with an aqueous clay dispersion and co‐coagulating the mixture. The structure of the nanocomposite was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Nanocomposites containing less than 10 phr clay showed a fully exfoliated structure. After increasing the clay content to 10 phr, both nonexfoliated (stacked layers) and exfoliated structures were observed in the nanocomposites. The results of mechanical tests showed that the nanocomposites presented better mechanical properties than clay‐free NR/SBR blend vulcanizate. Furthermore, tensile strength, tensile strain at break, and hardness (shore A) increased with increasing clay content, up to 6 phr, and then remained almost constant.  相似文献   
76.
The growth of silver iodide nanoparticles on silk fiber was achieved by sequential dipping in an alternating bath of potassium iodide and silver nitrate under ultrasound irradiation. Some parameters such as effect of pH, concentration and numerous sequential dipping in growth of the nanocrystal have been studied. The samples were characterized with powder X-ray diffraction (XRD), scanning electron microscopy (SEM), ICP, TGA and solid state UV–vis spectroscopy.  相似文献   
77.
 Through the differential equation describing the behavior of the nonlinear polarization of a medium with respect to an incident field, the Maxwell field equations and the boundary conditions of the field inside a resonator, the relationship between the output and the incident fields is obtained, describing a bistability phenomena. The effect of the spectral profile of the incident field and its spectral halfwidth on the bistability phenomena is studied.  相似文献   
78.
The structural, electronic and optical properties of tungsten-doped TiO2 have been investigated using density functional theory with plane wave basis sets and ultrasoft pseuodopotential. Substitutional W doping at Ti sites create W 5d states just below the conduction band minimum while interstitial W doping gives isolated W 5d states in the middle of forbidden region. Averaged bond lengths show that W doping at Ti sites produce minimum structural distortion as compared to the interstitial W-doped TiO2. Substitutional W-doped TiO2 has better visible light absorption compared to interstitial W-doped TiO2 and has stable configuration which provide reasonable explanation for the experimental findings. Tungsten doping in TiO2 with different doping concentrations is investigated as an enabling concept for enhancing the visible light absorption. Optical properties show that optimal W doping concentration would improve the visible light absorption. 2.08% W doping concentration gives strong visible and ultraviolet light absorption among all doped models found consistent with experiments.  相似文献   
79.
The effect of the counterpoise correction on the geometries, stabilization energies, and vibrational harmonic frequencies of some hydrogen- and halogen-bonded systems (B?=?CH3CN,?HCN,?NH3,?N2,?CO,?H2O,?H2S,?PH3;?HX?=?HF,?HCl,?HBr,?HCN,?HCF3; XY?=?Br2,?BrCl,?BrF,?Cl2,?ClF,?F2) has been analysed at the MP2 level of theory using the popular 6-311++G(d,p) basis set. The optimized B?···?H and B?···?X bond lengths increase with counterpoise (CP) correction. In some cases standard values and in other cases CP-corrected values are close to experimental data. The absolute values of complexation energies of CP-corrected structures are higher than standard by inclusion of BSSE correction. The effect of CP correction on intermolecular bond lengths and complexation energies of B?···?XY series are usually higher than B?···?HX. Also, this effect is higher for H2S and PH3 groups. The CP correction changes the vibrational harmonic frequencies by 0–100%. The changes are frequently lower than 20% for frequencies higher than 300?cm?1.  相似文献   
80.
Cyclic [n]paraphenyleneacetylenes ([n]CPPAs) are potentially useful compounds for molecular electronics. In this article, a homodesmotic reaction scheme coupled with density functional theory has been used to estimate theoretically strain energies and heats of formation of [n]CPPAs. Calculations have been done for a series of [n]CPPAs, containing up to ten phenylacetylene units. Strain energies of [n]CPPAs decrease, while heats of formation increase steadily with the increase in the number of phenylacetylene units using homodesmotic reaction schemes. B3LYP and mPW1PW91 functionals have been used with the Pople basis set 6-31G* to analyze the trends. The results are sensitive to the scheme of homodesmotic reaction chosen, thereby necessitating careful chemical consideration before spending considerable computational resources for higher [n]CPPAs not considered here. Computational estimates for the ring diameter of [n]CPPAs and absolute entropy have also been obtained here. The HOMO-LUMO gaps of the belt shaped [n]CPPAs show an odd–even difference. In addition, the HOMOs of the [3]CPPA, [5]CPPA, [7]CPPA and [9]CPPA are doubly degenerate.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号