Electrodeposition of nanocrystalline zinc from acidic sulfate solutions containing thiourea and benzalacetone as additives

Nanocrystalline zinc coatings were produced by pulse electrodeposition in acid sulfate bath containing thiourea and benzalacetone additives and characterized by X-ray diffraction and scanning electron microscopy techniques. The influence of benzalacetone concentration and pulse peak current density on the grain size and crystallographic orientation of zinc deposits was investigated. Zinc electrodeposited from additive-free solutions or with one of the two additives is not composed of nanosized crystals. The mixture additives of thiourea and benzalacetone give rise to the formation of particle-like nanocrystalline zinc with a (10ī1) random orientation. A change in peak current density from 2 to 1 A/cm² only increases the grain size from 60 to 62 nm.     

Synthesis of 1,3,4‐Oxadiazole‐Based Aromatic and Heterocyclic/Phenylpyrazole Derivatives

A new series of 1,3,4‐oxadiazole‐based aromatic and heterocyclic/phenylpyrazole derivatives 6a–c , 7a–d , and 8 were synthesized via sequential 1,3‐dipolar cyclization, hydrazidation, benzoylation, dehydrative cyclization, and the Suzuki coupling reaction. Among the derivatives, compounds 7a and 7c with the corresponding 2‐thienyl and 2‐benzo[b]thienyl (Ar) at the phenyl group located at the N‐1 position of pyrazole showed a better conjugation range.      

A Novel Simplified Column-Switching Technique for the Determination of Traces of Bromate in High Concentration Matrices

The column-switching technique has been widely used to determine trace level ions in the presence of high concentration matrix. A novel simplified column-switching method is proposed where bromate (as a model compound) was determined using this technique. The switching time window was confirmed by the retention time of determined ions. This technique can completely carry out the same function as the other column-switching technique do, but only one extra ten-way injection valve coupled to ion chromatograph was used. By using column-switching technique, it is possible to determine 0.2 μg L⁻¹ bromate in the presence of 100 mg L⁻¹ chloride by direct injection of 2000 μL without any pretreatment and the relative standard deviation (RSD) of the peak height for the eleven successive injections of 0.2 μg L⁻¹ bromate solution is 23.1%. The detection limit for bromate is 0.09 μg L⁻¹, which showed the method was very sensitive. The technique has been applied to the determination of bromate in drinking water, and the spike recovery is in the range of 96–104%.     

Direct amino acid analysis method for speciation of selenoamino acids using high-performance anion-exchange chromatography coupled with integrated pulsed amperometric detection

Speciation analysis of selenomethylcysteine (SeMeCys), selenomethionine (SeMet) and selenocystine (SeCys) has been performed using a direct amino acid analysis method with high-performance anion-exchange chromatography (HPAEC) coupled with integrated pulsed amperometric detection (IPAD). Three selenoamino acids could be baseline-separated from 19 amino acids using gradient elution conditions for amino acids and determined under new six-potential waveform. Detection limits for SeMeCys, SeMet and SeCys were 0.25, 1 and 20 microg/L (25 microL injection, 10 times of the baseline noise), respectively. The relative standard deviations (RSDs) of 200 microg/L SeMeCys, SeMet and SeCys were 3.1, 4.1 and 2.8%, respectively (n=9, 25 microL injection). The proposed method has been applied for determination of selenoamino acids in extracts of garlic and selenious yeast granule samples. No selenoamino acids were found in garlic. Both SeMet and SeCys were detected in selenious yeast tablet with the content of 45 and 129 microg Se/g, respectively. Selenoamino acids standards were spiked in garlic and yeast granule samples and the recovery ranged from 90 to 106%.     

Low-temperature growth and photoluminescence property of ZnS nanoribbons

At a low temperature of 450 degrees C, ZnS nanoribbons have been synthesized on Si and KCl substrates by a simple chemical vapor deposition (CVD) method with a two-temperature-zone furnace. Zinc and sulfur powders are used as sources in the different temperature zones. X-ray diffraction (XRD), selected area electron diffraction (SEAD), and transmission electron microscopy (TEM) analysis show that the ZnS nanoribbons are the wurtzite structure, and there are two types-single-crystal and bicrystal nanoribbons. Photoluminescence (PL) spectrum shows that the spectrum mainly includes two parts: a purple emission band centering at about 390 nm and a blue emission band centering at about 445 nm with a weak green shoulder around 510 nm.     

离子色谱法测定增味剂中的5′-肌苷酸二钠和5′-鸟苷酸二钠

 建立了增味剂中5′-肌苷酸二钠和5′-鸟苷酸二钠的离子色谱分析方法。采用lonPacASll阴离子交换色谱柱,以20mmol／LNa2CO3一体积分数为15％的甲醇溶液为淋洗液,检测波长254um。方法已用于实际样品的测定。     

Multi-walled carbon nanotubes as a solid-phase extraction adsorbent for the determination of chlorophenols in environmental water samples

Multi-walled carbon nanotubes (MWCNs) are used as adsorbent for solid-phase extraction (SPE) of several chlorophenols (CPs). CPs were adsorbed on MWCNs cartridge, then desorbed with pH 10.0 methanol, finally determined by HPLC. Under the optimized conditions, detection limits of 0.08-0.8 ng mL(-1) were obtained. The method had been applied to analyze the five CPs in tap water and river water.     

Determination of several sugars in serum by high-performance anion-exchange chromatography with pulsed amperometric detection

In this paper, a sensitive, simple and direct method for simultaneous determination of glucose, ribose, isomaltose and maltose in serum sample by high-performance anion-exchange chromatography coupled with integrated pulsed amperometric detection was developed. The four target analytes were easily and completely separated on an anion-exchange column at a flow-rate of 0.25 mL/min by binary step gradient elution in about 16 min and the two eluents were deionized water and 500 mM sodium hydroxide, respectively. The separated four analytes were detected directly by using a gold electrode and quadruple-potential waveform integrated pulsed amperometry without derivatization. Under the optimized conditions, when the injection volume was 25 microL, the detection limits (signal-to-noise ratio equal to 3) for glucose, ribose, isomaltose and maltose were 0.92, 7.50, 12.9 and 10.3 ng/mL, respectively. The calibration graphs of peak area for the four analytes were linear over two to three orders of magnitude with correlation coefficients greater than 0.998. R.S.D. of peak areas of the four analytes for five determinations were no more than 5.6%. The analytical method had been applied to the determination of glucose, ribose, isomaltose and maltose in real serum samples and good results with low relative standard deviation not more than 5.3% were obtained. The accuracy of the proposed method was tested by recovery measurements on spiked samples and good recovery results (98.1-107.9%) were obtained.     

智能建筑通信平台集约系统研究——制冷设备信号的底层通信

文中为智能建筑设计了一个通信网络系统,以实现建筑物内的低温信号采集处理和信息交换。在已有硬件设施基础上,利用基于FPGA的SOC设计技术,通过需求分析、算法设计,再到硬件开发、系统集成,实现对低温信号的处理完善,使之从系统的底层开始,为动平衡过程的所有信息交互提供服务。该系统可以满足BACNet标准和LONMARK标准,为智能建筑自控提供一套有效的信息处理模式。     

A multiplier rule on a metric space

A multiplier rule is proved for constrained minimization problems defined on a metric spaces. The proof requires a generalization of the values of a derivative in the classical case that the metric space is a normed space.