New upper bounds on the smallest size of a complete arc in a finite Desarguesian projective plane

In the projective planes PG(2, q), more than 1230 new small complete arcs are obtained for ${q \leq 13627}$ and ${q \in G}$ where G is a set of 38 values in the range 13687,..., 45893; also, ${2^{18} \in G}$ . This implies new upper bounds on the smallest size t ₂(2, q) of a complete arc in PG(2, q). From the new bounds it follows that $$t_{2}(2, q) < 4.5\sqrt{q} \, {\rm for} \, q \leq 2647$$ and q = 2659,2663,2683,2693,2753,2801. Also, $$t_{2}(2, q) < 4.8\sqrt{q} \, {\rm for} \, q \leq 5419$$ and q = 5441,5443,5449,5471,5477,5479,5483,5501,5521. Moreover, $$t_{2}(2, q) < 5\sqrt{q} \, {\rm for} \, q \leq 9497$$ and q = 9539,9587,9613,9623,9649,9689,9923,9973. Finally, $$t_{2}(2, q) <5 .15\sqrt{q} \, {\rm for} \, q \leq 13627$$ and q = 13687,13697,13711,14009. Using the new arcs it is shown that $$t_{2}(2, q) < \sqrt{q}\ln^{0.73}q {\rm for} 109 \leq q \leq 13627\, {\rm and}\, q \in G.$$ Also, as q grows, the positive difference ${\sqrt{q}\ln^{0.73} q-\overline{t}_{2}(2, q)}$ has a tendency to increase whereas the ratio ${\overline{t}_{2}(2, q)/(\sqrt{q}\ln^{0.73} q)}$ tends to decrease. Here ${\overline{t}_{2}(2, q)}$ is the smallest known size of a complete arc in PG(2,q). These properties allow us to conjecture that the estimate ${t_{2}(2,q) < \sqrt{q}\ln ^{0.73}q}$ holds for all ${q \geq 109.}$ The new upper bounds are obtained by finding new small complete arcs in PG(2,q) with the help of a computer search using randomized greedy algorithms. Finally, new forms of the upper bound on t ₂(2,q) are proposed.     

Quantitative Voronovskaja formulae for generalized Durrmeyer sampling type series

We give for generalized Durrmeyer type series and their linear combinations quantitative Voronosvskaja formulae in terms of the classical Peetre K‐functional. Finally we apply the general theory to various kernels     

Vibrational spectroscopy of triacetone triperoxide (TATP): anharmonic fundamentals, overtones and combination bands

The vibrational spectrum of triacetone triperoxide (TATP) is studied by the correlation-corrected vibrational self-consistent field (CC-VSCF) method which incorporates anharmonic effects. Fundamental, overtone, and combination band frequencies are obtained by using a potential based on the PM3 method and yielding the same harmonic frequencies as DFT/cc-pVDZ calculations. Fundamentals and overtones are also studied with anharmonic single-mode (without coupling) DFT/cc-pVDZ calculations. Average deviations from experiment are similar for all methods: 2.1-2.5%. Groups of degenerate vibrations form regions of numerous combination bands with low intensity: the 5600-5800 cm(-1) region contains ca. 70 overtones and combinations of CH stretches. Anharmonic interactions are analyzed.     

Constructions of Small Complete Caps in Binary Projective Spaces

In the binary projective spaces PG(n,2) k-caps are called large if k > 2^n-1 and smallif k ≤ 2^n-1. In this paper we propose new constructions producing infinite families of small binary complete caps.AMS Classification: 51E21, 51E22, 94B05