Secondary ion mass spectrometry and X-ray photoelectron spectroscopy investigation on chemical vapor deposited CeO(2-)ZrO(2)-TiO(2) thin films

Mixed CeO(2)-ZrO(2) systems have attracted widespread interest for their use in three-way catalyst (TWC) technology for automotive exhaust conversion to non-toxic products. In this work, CeO(2)-ZrO(2) thin films were deposited, via chemical vapor deposition, in order to obtain nanoscale materials with a high surface-to-volume ratio, with precise control of system properties. The addition of TiO(2) as buffer layer was also investigated. Cordierite was chosen as substrate, being the usual refractory material for catalytic mufflers. The multilayers were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS). In particular, the combination of SIMS and XPS allowed us to investigate both surface and in-depth chemical composition, studying also film-intermixing phenomena induced by annealing processes.     

Search for supermassive magnetic monopoles with the MACRO detector at the gran sasso laboratory

We present the results of the search for supermassive magnetic monopoles with the MACRO experiment. Our detector is equipped with three independent subdetectors (liquid scintillation counters, limited streamer tubes and nuclear track detectors), operating in different ranges of monopole velocity. In several years of data taking no candidates were found; the present flux upper limits are the level of half the Parker Bound for β > 10⁻⁴; for 10⁻⁴ < β < 5 × 10⁻² the limit is the best existing.     

Hysteresis loops for para–ferromagnetic phase transitions

In this paper, by an extension of the Ginzburg–Landau theory, we propose a mathematical model describing hard magnets within which we are able to explore the para–ferromagnetic transition and by using the Landau–Lifshitz–Gilbert equation, to study the 3D evolution of magnetic field. Finally, the hysteresis loops are obtained and represented by numerical implementations.     

Derivatives of Wronskians with applications to families of special Weierstrass points

Let be a flat proper family of smooth connected projective curves parametrized by some smooth scheme of finite type over . On every such a family, suitable derivatives along the fibers" (in the sense of Lax) of the relative wronskian, as defined by Laksov and Thorup, are constructed. They are sections of suitable jets extensions of the -th tensor power of the relative canonical bundle of the family itself.

The geometrical meaning of such sections is discussed: the zero schemes of the -th derivative () of a relative wronskian correspond to families of Weierstrass Points (WP's) having weight at least .

The locus in , the coarse moduli space of smooth projective curves of genus , of curves possessing a WP of weight at least , is denoted by . The fact that has the expected dimension for all was implicitly known in the literature. The main result of this paper hence consists in showing that has the expected dimension for all . As an application we compute the codimension Chow (-)class of for all , the main ingredient being the definition of the -th derivative of a relative wronskian, which is the crucial tool which the paper is built on. In the concluding remarks we show how this result may be used to get relations among some codimension Chow (-)classes in (), corresponding to varieties of curves having a point with a suitable prescribed Weierstrass Gap Sequence, relating to previous work of Lax.

     

The (100), (111) and (110) surfaces of diamond: an ab initio B3LYP study

We present an accurate ab initio study of the structure and surface energy of the low-index (100), (111) and (110) diamond faces, by using the hybrid Hartree–Fock/density functional B3LYP Hamiltonian and a localised all-electron Gaussian-type basis set. A two-dimensional periodic slab model has been adopted, for which convergence on both structural and energetic parameters has been thoroughly investigated. For all the three surfaces, possible relaxations and reconstructions have been considered; a detailed geometrical characterisation is provided for the most stable structure of each orientation. Surface energy is discussed for all the investigated faces.     

Hydrophobic siloxane paper coatings: the effect of increasing methyl substitution

Paper is an organic material widely used in cultural heritage and mainly composed of cellulose mixed with lignin, hemicellulose and small amounts of additives. This paper deals with siloxane coatings on pure cellulose paper, applied by sol–gel dipping in sols prepared with different siloxane precursors (tetraethoxysilane, methyl triethoxysilane, dimethyl diethoxysilane, trimethyl monoethoxysilane). The coated samples were characterized using various techniques (Fourier Transform Infrared Spectroscopy FT-IR, Nuclear Magnetic Resonance NMR and Scanning Electron Microscopy and Energy Dispersive Spectroscopy SEM–EDS), measuring their mechanical properties, flame resistance and contact angles, and a colorimetric test. The coated samples’ behavior was more hydrophobic the higher the methyl number of siloxane precursor, regardless of the coating’s thickness. Increasing the thickness improved the mechanical and thermal properties. The thickest coatings were obtained using a double coating process and a basic catalyst for the hydrolysis step, but this latter condition facilitated the formation of surface agglomerates, which make the paper too stiff and yellow.     

Magnetic anomaly in UCN trapping: signal for neutron oscillations to parallel world?

Present experiments do not exclude that the neutron n oscillates, with an appreciable probability, into its invisible degenerate twin from a parallel world, the so-called mirror neutron n′. These oscillations were searched experimentally by monitoring the neutron losses in ultra-cold neutron traps, where they can be revealed by the magnetic field dependence of n–n′ transition probability. In this work we reanalyze the experimental data acquired by the group of A.P. Serebrov at Institute Laue–Langevin, and find a dependence at more than 5σ away from the null hypothesis. This anomaly can be interpreted as oscillation of neutrons to mirror neutrons with a timescale of few seconds, in the presence of a mirror magnetic field order 0.1 G at the Earth. This result, if confirmed by future experiments, will have deepest consequences for fundamental particle physics, astrophysics and cosmology.     

Stereoselective Synthesis of 1,3-Disaccharides through Diels-Alder Reactions: Part 2[ 1 ]: Convenient Protecting Groups for Heterodienes and Conformational Evaluations

Improved synthesis of 1,3-disaccharides, obtained diastereomerically pure by [4+2] hetero cycloadditions between glycals and α -thiono-β -keto-δ -lactones, has been reported. The choice of appropriate protecting groups for β -keto-δ -lactones, stable under cycloaddition conditions employed, sensibly shortened the synthesis of heterodienic precursors. The first example of a β -oxy-imino-δ -lactone synthesized from β -keto-δ -lactones was also reported. Molecular modeling and conformational evaluations about the cycloaddition features allowed tentatively rationalizing the experimental results.     

Modelling the air transport with complex networks: A short review

Air transport is a key infrastructure of modern societies. In this paper we review some recent approaches to air transport, which make extensive use of theory of complex networks. We discuss possible networks that can be defined for the air transport and we focus our attention to networks of airports connected by flights. We review several papers investigating the topology of these networks and their dynamics for time scales ranging from years to intraday intervals, and consider also the resilience properties of air networks to extreme events. Finally we discuss the results of some recent papers investigating the dynamics on air transport network, with emphasis on passengers traveling in the network and epidemic spreading.