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861.
862.
Jean B Heux L Dubreuil F Chambat G Cousin F 《Langmuir : the ACS journal of surfaces and colloids》2009,25(7):3920-3923
Layer-by-layer assembly was used to build thin films, consisting of multiple layers alternating cellulose nanocrystals and xyloglucan, benefiting from the strong non-electrostatic cellulose-xyloglucan interaction. Data from atomic force microscopy and neutron reflectivity showed that these well-defined films exhibited a thickness increasing linearly with the number of layers, without increase in surface roughness. These "green" nanocomposite films, reminiscent of plant cell wall, are composed of a regular stack of single layers of cellulose nanocrystals separated by very thin xyloglucan spacers. Such architecture differs from the one formed by cellulose/polycations multilayers, where the cellulose phase itself consists of a double layer. 相似文献
863.
Sebastien Anizan Emmanuelle Bichon Thibault Duval Fabrice Monteau Nora Cesbron Jean‐Philippe Antignac Bruno Le Bizec 《Journal of mass spectrometry : JMS》2012,47(1):131-140
The use of anabolic steroids as growth promoters for meat‐producing animals is banned within the European Union. However, screening for the illegal use of natural steroid hormones still represents a difficult challenge because of the high interindividual and physiological variability of the endogenous concentration levels in animals. In this context, the development of untargeted profiling approaches for identifying new relevant biomarkers of exposure and/or effect has been emerging for a couple of years. The present study deals with an untargeted metabolomics approach on the basis of GC‐MS aiming to reveal potential biomarkers signing a fraudulent administration of 4‐androstenedione (AED), an anabolic androgenic steroid chosen as template. After a sample preparation based on microextraction by packed sorbent, urinary profiles of the free and deglucurono‐conjugates urinary metabolites were acquired by GC‐MS in the full‐scan acquisition mode. Data processing and chemometric procedures highlighted 125 ions, allowing discrimination between samples collected before and after an administration of 4‐AED. After a first evaluation of the signal robustness using additional and independent non‐compliant samples, 17 steroid‐like metabolites were pointed out as relevant candidate biomarkers. All these metabolites were then monitored using a targeted GC‐MS/MS method for an additional assessment of their capacity to be used as biomarkers. Finally, two steroids, namely 5α‐androstane‐3β,17α‐diol and 5α‐androst‐2‐en‐17‐one, were concluded to be compatible with such a definition and which could be finally usable for screening purpose of AED abuse in cattle. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
864.
Thomas Dutriez Marion Courtiade Didier Thiébaut Hugues Dulot Fabrice Bertoncini Marie‐Claire Hennion 《Journal of separation science》2010,33(12):1787-1796
In a context of environmental preservation, purification and conversion of heavy petroleum cuts into high‐quality fuel becomes essential. The interest for the characterization of those very complex matrices becomes a trendy analytical challenge, when it comes to get molecular information for the optimization of industrial processes. Among new analytical techniques, high‐temperature 2‐D GC has recently proved its applicability to heavy petroleum matrices, but lacks in selectivity to separate all chemical groups. To gain resolution, heart cutting is demonstrated for LC separation of saturated, aromatic and polar compounds prior to high‐temperature 2‐D GC. Therefore, an extended global resolution was obtained, especially by a better distinction of saturated compounds. This includes iso‐paraffins and biomarker polynaphthenic structures, which are impossible to quantify with MS methods. This new way to analyze heavy petroleum fractions gives innovative opportunities for the construction of global weight distributions by carbon atoms number and by chemical families. This can right now be employed for quantitative analysis of heavy petroleum fractions and for studying conversion processes. 相似文献
865.
Joël Aerts Samuel Voccia Fabrice Giacomelli David Thonon Geoffrey Warnock 《Tetrahedron letters》2010,51(1):64-9734
The use of a polymeric solid support loaded with a long alkyl chain quaternary ammonium allows the rapid and efficient recovery of cyclotron produced [18F]F− from [18O]water to a low water content organic solution compatible with fast nucleophilic labelling of most precursors for PET radiopharmaceuticals in high yield. 相似文献
866.
Joanna Kostka Fabrice Gritti Georges Guiochon Krzysztof Kaczmarski 《Journal of chromatography. A》2010,1217(28):4704-4712
Currently, chromatographic analyses are carried out by operating columns packed with sub-2 μm particles under very high pressure gradients, up to 1200 bar for 5 cm long columns. This provides the high flow rates that are necessary for the achievement of high column efficiencies and short analysis times. However, operating columns at high flow rates under such high pressure gradients generate a large amount of heat due to the viscous friction of the mobile phase stream that percolates through a low permeability bed. The evacuation of this heat causes the formation of significant or even large axial and radial gradients of all the physico-chemical parameters characterizing the packing material and the mobile phase, eventually resulting in a loss of column efficiency. We previously developed and successfully applied a model combining the heat and the mass balances of a chromatographic column operated under very high pressure gradients (VHPLC). The use of this model requires accurate estimates of the dispersion coefficients at each applied mobile phase velocity. This work reports on a modification of the mass balance model such that only one measurement is now necessary to accurately predict elution peak profiles in a wide range of mobile phase velocities. The conditions under which the simple equilibrium-dispersive (ED) and transport-dispersive (TD) models are applicable in VHPLC are also discussed. This work proves that the new combination of the heat transfer and the ED model discussed in this work enables the calculation of accurate profiles for peaks eluted under extreme conditions, like when the column is thermostated in a water bath. 相似文献
867.
We study the heat kernel of the sub-Laplacian $L$ on the CR sphere $\mathbb{S }^{2n+1}$ . An explicit and geometrically meaningful formula for the heat kernel is obtained. As a by-product we recover in a simple way the Green function of the conformal sub-Laplacian $-L+n^2$ that was obtained by Geller (J Differ Geom 15:417–435, 1980), and also get an explicit formula for the sub-Riemannian distance. The key point is to work in a set of coordinates that reflects the symmetries coming from the fibration $\mathbb{S }^{2n+1} \rightarrow \mathbb{CP }^n$ . 相似文献
868.
869.
We derive an exact formula for solutions to the Stokes equations in the half space with an external forcing term. This formula is used to establish local and global existence and uniqueness in a suitable Besov space for solutions to the Navier Stokes equations. In particular, wellposedness is proved for initial data in L3(R3 +). 相似文献
870.
Planchon TA Amir W Field JJ Durfee CG Squier JA Rousseau P Albert O Mourou G 《Optics letters》2006,31(14):2214-2216
By using the third-harmonic signal generated at an air-dielectric interface, we demonstrate a novel way of correcting wavefront aberrations induced by high-numerical-aperture optics. The third harmonic is used as the input physical parameter of a genetic algorithm working in closed loop with a 37-actuator deformable mirror. This method is simple and reliable and can be used to correct aberrations of tightly focused beams, a regime where other methods have limitations. Improvement of the third-harmonic signal generated with an f/1.2 parabolic mirror by 1 order of magnitude is demonstrated. 相似文献