Chiral bidiaziridines by a two-step domino aziridination of meso-α-diimines

Chiral racemic α-diimines, tested in aziridination reactions with NsONHCO₂Et, for the first time led to the synthesis of (±)-bidiaziridines, stereoselectively derived from the corresponding meso (E-s-trans-E)-α-diimines. Moreover, a minor bidiaziridine isomer, probably a meso form that was lost under classical work-up conditions, can be obtained by adding water to the crude mixtures at the end of amination reactions. The results definitively prove that the imine aziridination by carbamates is a two-step domino process. The structures of the compounds were determined using 2D NMR on purified bidiaziridines.     

Evidence of Sn adatoms quantum tunneling at the alpha-Sn/Si(111) surface

We present a low-temperature scanning tunneling microscopy study of the alpha-Sn/Si(111) surface that demonstrates the fluctuating behavior of the Sn adatoms. The dynamical fluctuation model, successfully applied in describing the alpha-Sn/Ge(111) surface, is proposed for the related alpha-Sn/Si(111) surface too, although with a much lower transition temperature. In addition, a new phenomenon appears responsible for the unexpected evidence that the average oscillation frequency remains constant at temperatures lower than 15 K, in contradiction to the Arrhenius law. We explain this phenomenon as quantum tunneling of Sn adatoms.     

Precision and sensitivity optimization of quantitative measurements in solid state NMR

This work presents a methodology for optimizing the precision, accuracy and sensitivity of quantitative solid state NMR measurements based on the external reference method. It is shown that the sample must be exclusively located within and completely span the coil region where the NMR response is directly proportional to the sample amount. We describe two methods to determine this "quantitative" coil volume, based on whether the probe is equipped or not with a gradient coil. In addition, to improve the sensitivity and the accuracy, an optimum rotor packing design is described, which allows the sample volume of the rotor to be matched to the quantitative coil volume. Experiments conducted on adamantane and NaCl, which are representative of a soft and hard material, respectively, show that one order of magnitude increase in experimental precision can be achieved with this methodology. Interestingly, the precision can be further improved by using the ERETIC method in order to compensate for most instrumental instabilities.     

Dynamic response of rocking cracked masonry walls

The behaviour of masonry constructions results to be very far from the one characterizing ductile structures. In masonry constructions, the seismic action activates a rocking motion rather than a dissipating mechanism. A strength resource of masonry structures, properly reinforced in order to avoid early local failures, consists in exhibiting rocking behaviour, until a failure condition is attained. Aim of the paper is to investigate the dynamic behaviour of masonry single storey walls, according to Housner’s studies and innovatively introducing the effect of diagonal cracks developing from the toes of the piers and shown by typical post-earthquake cracking patterns. The proposed procedure can be easily applied to the case of multi-storey regular masonry walls with openings representing the main resistant structural components of a masonry building. Starting from the evaluation of the incipient rocking acceleration of the system, the free and forced motions of the wall are examined. In the paper, according to the classical Housner’s approach, the energy dissipation occurring during the impact is modelled. Finally, a numerical application, considering a simple constant horizontal acceleration impulse of given duration has been carried out.

     

Application of modal analysis methods to the design of wireless power transfer systems

Meccanica - Wireless recharge of electric vehicles is an important field of research. Design of inductive power transfer systems involves the optimization of resonant coils coupled through mutually...     

Superfluidity and quantum melting of p-H2 clusters

Structural and superfluid properties of p-H2 clusters of size up to N=40 molecules, are studied at low temperature (0.5 K相似文献   

The adsorption of a substituted benzene,the ethynyl-trifluoro-toluene on Si(100)-2 × 1

The adsorption of 3-ethynyl-trifluoro-toluene (ETFT) on Si(100)-2 × 1 surface in ultra high vacuum is studied in the low coverage regime, through a joint experimental and theoretical approach. The STM images of both filled and empty states revealed few distinct adsorption configurations. On the basis of Density Functional Theory (DFT) calculations the STM images were simulated and three main adsorption configurations were identified, with a predominance of di-sigma bonded species that leave the benzene ring unreacted. A discussion of the reactivity of the reconstructed silicon surface towards benzene derivatives is proposed by comparing the adsorption of ETFT close related molecules, like styrene and phenylacetylene.     

Large deviations and Lifshitz singularity of the integrated density of states of random Hamiltonians

We consider the integrated density of states (IDS) ρ_∞(λ) of random Hamiltonian H_ω=?Δ+V_ω, V_ω being a random field on ? ^d which satisfies a mixing condition. We prove that the probability of large fluctuations of the finite volume IDS |Λ|^?1ρ(λ, H_Λ(ω)), Λ ? ? ^d , around the thermodynamic limit ρ_∞(λ) is bounded from above by exp {?k|Λ|},k>0. In this case ρ_∞(λ) can be recovered from a variational principle. Furthermore we show the existence of a Lifshitztype of singularity of ρ_∞(λ) as λ → 0⁺ in the case where V_ω is non-negative. More precisely we prove the following bound: ρ_∞(λ)≦exp(?kλ^?d/2) as λ → 0⁺ k>0. This last result is then discussed in some examples.     

Energy as a Fifth Dimension

A recent analysis of the experimental data on some physical phenomena ruled by the four fundamental interactions (electromagnetic, weak, strong and gravitational) seems to show the possibility of describing such interactions in terms of a deformation of the usual Minkowski spacetime, with a metric whose coefficients do depend on the energy of the process considered. In this paper, we show that such results can be accounted for in terms of a Kaluza-Klein-like scheme, based on a five-dimensional Riemannian space in which energy plays the role of the fifth dimension. The corresponding five-dimensional Einstein equations in vacuum are solved in some cases of physical relevance and it is shown that all the phenomenological metrics describing the four fundamental forces are recovered as special cases of the classes of solutions found. Possible developments of the formalism are also briefly outlined.     

Permanence and Positive Periodic Solutions for Kolmogorov Competing Species Systems

We prove the existence of periodic solutions in a compact attractor of (R⁺)ⁿ for the Kolmogorov system x′_i = x_if_i(t, x₁, …, x_n), i = l, …, n in the competitive case. Extension to differential delay equations are con- sidered too. Applications are given to Lotka-Volterra systems with periodic coefficients.