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101.
Suppressing the environmental dependence of the open‐circuit voltage in inverted polymer solar cells through a radical polymer anodic modifier
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![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Lizbeth Rostro Lucio Galicia Bryan W. Boudouris 《Journal of Polymer Science.Polymer Physics》2015,53(5):311-316
Developing stable, readily‐synthesized, and solution‐processable transparent conducting polymers for interfacial modifying layers in organic photovoltaic (OPV) devices has become of great importance. Here, the radical polymer, poly(2,2,6,6‐tetramethylpiperidinyloxy methacrylate (PTMA), is shown to not affect the absorption of the well‐studied poly(3‐hexylthiophene) (P3HT) and [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) active layer when incorporated into inverted OPV devices, as it is highly transparent in the visible spectrum due to the non‐conjugated nature of the PTMA backbone. The inclusion of this radical polymer as an anode‐modifying layer enhanced the open‐circuit voltage and short‐circuit current density values over devices that did not contain an anodic modifier. Importantly, devices fabricated with the PTMA interlayer had performance metrics that were time‐independent over the entire course of multiples days of testing after exposing the OPV devices to ambient conditions. Furthermore, these high performance values were independent of the metal used as the top electrode contact in the inverted OPV devices. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 311–316 相似文献
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A tunable microwave-assisted protocol for the synthesis of two biologically relevant families of heterocycles has been designed. Via a simple switch of reaction conditions, the same starting materials can be engaged in either an improved synthesis of the dihydrotriazine scaffold or a novel, first-in-class MCR to render the challenging 5-aminoimidazole nucleus in a single step. An additional first-in-class MCR is also reported utilizing guanidines to afford 2,5-aminoimidazoles. 相似文献
104.
Synthesis and Biological Evaluation of RGD Peptidomimetic–Paclitaxel Conjugates Bearing Lysosomally Cleavable Linkers
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![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Alberto Dal Corso Dr. Michele Caruso Dr. Laura Belvisi Dr. Daniela Arosio Prof. Dr. Umberto Piarulli Dr. Clara Albanese Dr. Fabio Gasparri Dr. Aurelio Marsiglio Dr. Francesco Sola Dr. Sonia Troiani Dr. Barbara Valsasina Dr. Luca Pignataro Dr. Daniele Donati Prof. Dr. Cesare Gennari 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(18):6921-6929
Two small‐molecule–drug conjugates (SMDCs, 6 and 7 ) featuring lysosomally cleavable linkers (namely the Val–Ala and Phe–Lys peptide sequences) were synthesized by conjugation of the αvβ3‐integrin ligand cyclo[DKP–RGD]‐CH2NH2 ( 2 ) to the anticancer drug paclitaxel (PTX). A third cyclo[DKP–RGD]–PTX conjugate with a nonpeptide “uncleavable” linker ( 8 ) was also synthesized to be tested as a negative control. These three SMDCs were able to inhibit biotinylated vitronectin binding to the purified αVβ3‐integrin receptor at nanomolar concentrations and showed good stability at pH 7.4 and pH 5.5. Cleavage of the two peptide linkers was observed in the presence of lysosomal enzymes, whereas conjugate 8 , which possesses a nonpeptide “uncleavable” linker, remained intact under these conditions. The antiproliferative activities of the conjugates were evaluated against two isogenic cell lines expressing the integrin receptor at different levels: the acute lymphoblastic leukemia cell line CCRF‐CEM (αVβ3?) and its subclone CCRF‐CEM αVβ3 (αVβ3+). Fairly effective integrin targeting was displayed by the cyclo[DKP–RGD]–Val–Ala–PTX conjugate ( 6 ), which was found to differentially inhibit proliferation in antigen‐positive CCRF‐CEM αVβ3 versus antigen‐negative isogenic CCRF‐CEM cells. The total lack of activity displayed by the “uncleavable” cyclo[DKP–RGD]–PTX conjugate ( 8 ) clearly demonstrates the importance of the peptide linker for achieving the selective release of the cytotoxic payload. 相似文献
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Fabio Drucker David Richeson Jim Wiseman 《Journal of Dynamics and Differential Equations》2016,28(2):301-315
We consider shift spaces in which elements of the alphabet may overlap nontransitively. We define a notion of entropy for such spaces and show that it is equal to a limit of entropies of standard (non-overlapping) shifts when the underlying shift is of finite type. When a shift space with overlaps arises as a model for a discrete dynamical system with a finite set of overlapping neighborhoods, the entropy gives a lower bound for the topological entropy of the dynamical system. 相似文献
108.
Ilario Losito Fabio Mavelli Annamaria Demarinis Loiotile Francesco Palmisano 《Analytica chimica acta》2012
A simple software, to be used as an aid in the identification of non-tryptic peptides based on low resolution (3D-ion trap) tandem (MS/MS) and sequential (MS3) mass spectrometry data, is presented. 相似文献
109.
Fabio Briscese Yeinzon Rodríguez Guillermo A. González 《Foundations of Physics》2012,42(11):1444-1451
We argue that the true nature of the renormalizability of Horava-Lifshitz gravity lies in the presence of higher order spatial derivatives and not in the anisotropic Lifshitz scaling of space and time. We discuss the possibility of constructing a higher order spatial derivatives model that has the same renormalization properties of Horava-Lifshitz gravity but that does not make use of the Lifshitz scaling. In addition, the state-of-the-art of the Lorentz symmetry restoration in Horava-Lifshitz-type theories of gravitation is reviewed. 相似文献
110.