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31.
Dr. Sebastian C. Cosgrove Dr. Matthew P. Thompson Dr. Syed T. Ahmed Dr. Fabio Parmeggiani Prof. Nicholas J. Turner 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(41):18313-18317
The combination of biocatalysis and chemo-catalysis increasingly offers chemists access to more diverse chemical architectures. Here, we describe the combination of a toolbox of chiral-amine-producing biocatalysts with a Buchwald–Hartwig cross-coupling reaction, affording a variety of α-chiral aniline derivatives. The use of a surfactant allowed reactions to be performed sequentially in the same flask, preventing the palladium catalyst from being inhibited by the high concentrations of ammonia, salts, or buffers present in the aqueous media in most cases. The methodology was further extended by combining with a dual-enzyme biocatalytic hydrogen-borrowing cascade in one pot to allow for the conversion of a racemic alcohol to a chiral aniline. 相似文献
32.
Pioger P Couderc V Lefort L Barthelemy A Baronio F De Angelis C Min Y Quiring V Sohler W 《Optics letters》2002,27(24):2182-2184
We show numerically and experimentally that spatial trapping can be induced in quadratic media even if the pump pulse's duration is shorter than the group-delay mismatch between fundamental wave and second-harmonic components. The influence of phase mismatch and pulse power on the trapping effect is discussed. Spatial, temporal, and spectral behaviors that accompany self-trapped propagation are highlighted. 相似文献
33.
Fabio Nicola 《Journal d'Analyse Mathématique》2005,96(1):297-311
We give necessary and sufficient conditions for a lower bound with a gain of 3/2 derivatives (the so-called Weak-Hörmander inequality) for a class of systems with double characteristics. 相似文献
34.
Victor B. Tinti Debora Marani Andre S. Ferlauto Fabio C. Fonseca Vincenzo Esposito Daniel Z. de Florio 《Particle & Particle Systems Characterization》2020,37(2):1900472
A fast and accurate experimental method is demonstrated to assess the fraction of exsolved metallic nanoparticles using magnetic measurements. As a benchmark, nanometric metallic nickel exsolved from (La1−xSrx)(Cr1−yNiy)O3−δ is used for its high relevance as a solid oxide fuel cell component. The method is based on the difference in the magnetic response of the exsolved metallic nickel (ferromagnetic) and Sr-doped lanthanum chromite ceramic matrix (paramagnetic). The exsolved nickel results in coherent nanoparticles pinned on the surface of the Sr-doped lanthanum chromite ceramic matrix, as evidenced by electron microscopy analyses. The results obtained indicate the procedure as a fast and sensitive method to study the exsolution of ferromagnetic nanoparticles. 相似文献
35.
36.
Francescamaria Donati Piero Boraschi Roberto Gigoni Simonetta Salemi Fabio Falaschi Carlo Bartolozzi 《Magnetic resonance imaging》2013
Purpose
To present diffusion and perfusion magnetic resonance imaging (MRI) characteristics of focal nodular hyperplasia (FNH) of the liver.Materials and Methods
Thirty-five patients with 52 FNHs (21 were pathologically-confirmed) underwent MRI at 1.5-T device. MR diffusion [diffusion-weighted imaging (DWI)] was performed using a free-breathing single-shot, spin-echo, echo-planar sequence with b gradient factor value of 500 s/mm². MR perfusion [perfusion-weighted imaging (PWI)] consisted of a 3D free-breathing LAVA sequence repeated up to 5 minutes after injection of 7 mL Gd-BOPTA (MultiHance, Bracco, Italy) and 20 mL saline flush at a flow rate of 4 mL/s. Apparent diffusion coefficient (ADC) and time-signal intensity curve (TSIC) were obtained for both normal liver and each FNH by two reviewers in conference; maximum enhancement (ME) percentage, time to peak enhancement (TTP), and maximal slope (MS) were also calculated.Results
On DWI mean ADC value was 1.624×10− 3 mm2/s for normal liver and 1.629×10− 3 mm2/s for FNH. ADC value for each FNH and the normal liver was not statistically different (P= .936). On PWI, TSIC-Type 1 (quick and marked enhancement and quick decay followed by slowly decaying) was observed in all 52 FNHs, and TSIC-Type 2 (fast enhancement followed by slowly decaying plateau) in all normal livers. The mean ME, TTP and MS values were significantly different for FNH and normal liver (P= .005).Conclusion
FNHs of the liver showed typical diffusion and perfusion MRI characteristics in all cases. On the ADC map, we could get similar value between the FNHs and the background parenchyma. On the perfusion imaging, FNHs showed a different pattern distinguished from the background liver. 相似文献37.
A stochastic global optimization method is applied to the challenging problem of finding the minimum energy conformation of a cluster of identical atoms interacting through the Lennard-Jones potential. The method proposed incorporates within an already existing and quite successful method, monotonic basin hopping, a two-phase local search procedure which is capable of significantly enlarging the basin of attraction of the global optimum. The experiments reported confirm the considerable advantages of this approach, in particular for all those cases which are considered in the literature as the most challenging ones, namely 75, 98, 102 atoms. While being capable of discovering all putative global optima in the range considered, the method proposed improves by more than two orders of magnitude the speed and the percentage of success in finding the global optima of clusters of 75, 98, 102 atoms. 相似文献
38.
Pier?Paolo?ProsiniEmail author Maria?Carewska Gabriele?Tarquini Fabio?Maroni Agnese?Birrozzi Francesco?Nobili 《Ionics》2016,22(4):515-528
This paper describes the preparation and characterization of a high-voltage lithium-ion battery based on Sn-decorated reduced graphene oxide and LiNi0.5Mn1.5O4 as the anode and cathode active materials, respectively. The Sn-decorated reduced graphene oxide is prepared using a microwave-assisted hydrothermal synthesis method followed by reduction at high temperature of a mixture of (C6H5)2SnCl2 and graphene oxide. The so-obtained anode material is characterized by thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, and electron diffraction spectroscopy. The LiNi0.5Mn1.5O4 is a commercially available product. The two materials are used to prepare composite electrodes, and their electrochemical properties are investigated by galvanostatic charge/discharge cycles at various current densities in lithium cells. The electrodes are then used to assemble a high-voltage lithium-ion cell, and the cell is tested to evaluate its performance as a function of discharge rate and cycle number. 相似文献
39.
E. P. Serrano M. I. Troparevsky M. A. Fabio 《Journal of Contemporary Mathematical Analysis (Armenian Academy of Sciences)》2014,49(2):91-97
The paper considers an inverse problem associated with equations of the form Kf = g, where K is a convolution-type operator. The aim is to find a solution f for given function g. We construct approximate solutions by applying a wavelet basis that is well adapted to this problem. For this basis we calculate the elementary solutions that are the approximate preimages of the wavelets. The solution for the inverse problem is then constructed as an appropriate finite linear combination of the elementary solutions. Under certain assumptions we estimate the approximation error and discuss the advantages of the proposed scheme. 相似文献
40.
We study the complexity of the problem of deciding the existence of a spanning subgraph of a given graph, and of that of finding a maximum (weight) such subgraph. We establish some general relations between these problems, and we use these relations to obtain new NP-completeness results for maximum (weight) spanning subgraph problems from analogous results for existence problems and from results in extremal graph theory. On the positive side, we provide a decomposition method for the maximum (weight) spanning chordal subgraph problem that can be used, e.g., to obtain a linear (or O(nlogn)) time algorithm for such problems in graphs with vertex degree bounded by 3. 相似文献