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51.
Fabian Gaufillet éric Akmansoy 《Applied Physics A: Materials Science & Processing》2012,109(4):1071-1074
We have designed a flat graded index lens made from a metallic graded 2D photonic crystal. The gradient of index has been obtained by varying the filling factor of a flat slab of photonic crystal in the direction perpendicular to that of the propagation of the electromagnetic field. This gradient has been designed in such a way that the flat slab focuses a plane wave. With applications in the microwave range in view, we considered a photonic crystal which consists of copper strips. 相似文献
52.
Redox‐Active Tetraruthenium Macrocycles Built from 1,4‐Divinylphenylene‐Bridged Diruthenium Complexes 下载免费PDF全文
Stefan Scheerer Dr. Michael Linseis Dr. Evelyn Wuttke Sabrina Weickert Prof. Dr. Malte Drescher Dr. Oliver Tröppner Prof. Dr. Ivana Ivanović‐Burmazović Andreas Irmler Prof. Dr. Fabian Pauly Prof. Dr. Rainer F. Winter 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(28):9574-9590
Metallamacrocylic tetraruthenium complexes were generated by treatment of 1,4‐divinylphenylene‐bridged diruthenium complexes with functionalized 1,3‐benzene dicarboxylic acids and characterized by HR ESI‐MS and multinuclear NMR spectroscopy. Every divinylphenylene diruthenium subunit is oxidized in two consecutive one‐electron steps with half‐wave potential splittings in the range of 250 to 330 mV. Additional, smaller redox‐splittings between the +/2+ and 0/+ and the 3+/4+ and 2+/3+ redox processes, corresponding to the first and the second oxidations of every divinylphenylene diruthenium entity, are due to electrostatic effects. The lack of electronic coupling through bond or through space is explained by the nodal properties of the relevant molecular orbitals and the lateral side‐by‐side arrangement of the divinylphenylene linkers. The polyelectrochromic behavior of the divinylphenylene diruthenium precursors is retained and even amplified in these metallamacrocyclic structures. EPR studies down to T=4 K indicate that the dications 1‐H2+ and 1‐OBu2+ are paramagnetic. The dications and the tetracation of macrocycle 3‐H display intense (dications) or weak ( 3‐H4+ ) EPR signals. Quantum chemical calculations indicate that the four most stable conformers of the macrocycles are largely devoid of strain. Bond parameters, energies as well as charge and spin density distributions of model macrocycle 5‐HMe were calculated for the different charge and spin states. 相似文献
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While the number of models dedicated to predicting the consequences of alternative resource management strategies has increased, instances in which authors look back at past predictions to learn from discrepancies between these and observed developments are scarce. In the past decades, the French Guiana shrimp fishery has experienced shrimp market globalization and decreasing levels of shrimp recruitment due to environmental changes. In 2006, a bio‐economic model of this fishery was developed to simulate its possible responses to economic and environmental scenarios up to 2016. Here, we compare here these predictions to the observed trajectories. While the number of active vessels corresponds to that which was predicted, the estimated shrimp stock does not. Important driving factors had not been anticipated, including a general strike, natural disasters, and the end of the global financial crisis. These results show the importance of participative approaches involving stakeholders in the co‐construction and shared representation of scenarios. Recommendations for resource managers
- Effective fisheries resources management and a fortiori, the capacity of the fisheries to adapt to global change, requires understanding of both ecological and economics dynamics.
- The temporal trajectory of the trawling shrimp fisheries has been well monitored, and the decline of both stock and fleet is understood regarding ecological and economic changes: Changes in the environmental conditions of shrimp recruitment, and oil price increase and selling price decrease.
- However, our bio‐economic modeling work showed that, even with a good understanding of the dynamics explaining past trajectories, unpredictable events (strike, natural disasters…) have acted as other key driving factors altering the capacity of the model to represent possible futures.
- These results led us to recommend a better integration of the expertise of social and political scientists in developing models of bio‐economic systems to increase the quality of scenario predictions, and to argue for more participative approaches involving the stakeholders.
55.
We consider the class of closed generic fluid network (GFN) models, which provides an abstract framework containing a wide
variety of fluid networks. Within this framework a Lyapunov method for stability of GFN models was proposed by Ye and Chen.
They proved that stability of a GFN model is equivalent to the existence of a functional on the set of paths that is decaying
along paths. This result falls short of a converse Lyapunov theorem in that no state-dependent Lyapunov function is constructed.
In this paper we construct state-dependent Lyapunov functions in contrast to path-wise functionals. We first show by counterexamples
that closed GFN models do not provide sufficient information that allow for a converse Lyapunov theorem. To resolve this problem
we introduce the class of strict GFN models by forcing closed GFN models to satisfy a concatenation and a semicontinuity condition.
For the class of strict GFN models we define a state-dependent Lyapunov function and show that a converse Lyapunov theorem
holds. Finally, it is shown that common fluid network models, like general work-conserving and priority fluid network models
as well as certain linear Skorokhod problems define strict GFN models. 相似文献
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57.
Fabian Uhlemann Prof. Dr. Andreas Schnepf 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(31):10748-10753
The reaction of a metastable SiCl2 solution with the sterically less‐demanding carbene N,N‐diisopropylimidazo‐2‐ylidene (IPr) yields the salt [(IPr3Si3Cl5)+]Cl? ( 1 ‐Cl), containing a silyl cation with a Si3 backbone. Salt 1 is highly reactive, but it can be used as a reagent in deuterated dichloromethane, whereby dehalogenation with Me3SiOTf (OTf=O3SCF3) gives the dicationic silyl halide [(IPr3Si3Cl4)]2+ 2 . Quantum chemical calculations show that the HOMO is localized at the negatively charged central silicon atom of 1 and 2 , and thus although both compounds are cations they are better described as silanides, which was also corroborated by NMR investigations. 相似文献
58.
Fabian Benz Christoph Roderburg David Vargas Cardenas Mihael Vucur Jérémie Gautheron Alexander Koch Henning Zimmermann J?rn Janssen Lukas Nieuwenhuijsen Mark Luedde Norbert Frey Frank Tacke Christian Trautwein Tom Luedde 《Experimental & molecular medicine》2013,45(9):e42
MicroRNA (miRNA) levels in serum have recently emerged as potential novel biomarkers for various diseases. miRNAs are routinely measured by standard quantitative real-time PCR (qPCR); however, the high sensitivity of qPCR demands appropriate normalization to correct for nonbiological variation. Presently, RNU6B (U6) is used for data normalization of circulating miRNAs in many studies. However, it was suggested that serum levels of U6 themselves might differ between individuals. Therefore, no consensus has been reached on the best normalization strategy in ‘circulating miRNA''. We analyzed U6 levels as well as levels of spiked-in SV40-RNA in sera of 44 healthy volunteers, 203 intensive care unit patients and 64 patients with liver fibrosis. Levels of U6 demonstrated a high variability in sera of healthy donors, patients with critical illness and liver fibrosis. This high variability could also be confirmed in sera of mice after the cecal ligation and puncture procedure. Most importantly, levels of circulating U6 were significantly upregulated in sera of patients with critical illness and sepsis compared with controls and correlated with established markers of inflammation. In patients with liver fibrosis, U6 levels were significantly downregulated. In contrast, levels of spiked-in SV40 displayed a significantly higher stability both in human cohorts (healthy, critical illness, liver fibrosis) and in mice. Thus, we conclude that U6 levels in the serum are dysregulated in a disease-specific manner. Therefore, U6 should not be used for data normalization of circulating miRNAs in inflammatory diseases and previous studies using this approach should be interpreted with caution. Further studies are warranted to identify specific regulatory processes of U6 levels in sepsis and liver fibrosis. 相似文献
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60.
Dipl. Chem. Keven Muller Dr. Yu Sun Andreas Heimermann Fabian Menges Gereon Niedner‐Schatteburg Christoph van Wüllen Prof. Dr. Werner R. Thiel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(24):7825-7834
Pyridinylazolato (N–N′) ruthenium(II) complexes of the type [(N–N′)RuCl(PMe3)3] have been obtained in high yields by treating the corresponding functionalised azolylpyridines with [RuCl2(PMe3)4] in the presence of a base. 15N NMR spectroscopy was used to elucidate the electronic influence of the substituents attached to the azolyl ring. The findings are in agreement with slight differences in the bond lengths of the ruthenium complexes. Furthermore, the electronic nature of the azolate moiety modulates the catalytic activity of the ruthenium complexes in the hydrogenation of carbon dioxide under supercritical conditions and in the transfer hydrogenation of acetophenone. DFT calculations were performed to shed light on the mechanism of the hydrogenation of carbon dioxide and to clarify the impact of the electronic nature of the pyridinylazolate ligands. 相似文献