全文获取类型
收费全文 | 295篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 274篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 14篇 |
物理学 | 10篇 |
出版年
2020年 | 2篇 |
2019年 | 1篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 9篇 |
2013年 | 10篇 |
2012年 | 29篇 |
2011年 | 31篇 |
2010年 | 12篇 |
2009年 | 8篇 |
2008年 | 24篇 |
2007年 | 13篇 |
2006年 | 19篇 |
2005年 | 19篇 |
2004年 | 21篇 |
2003年 | 20篇 |
2002年 | 15篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 7篇 |
1984年 | 1篇 |
1982年 | 6篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1973年 | 1篇 |
1969年 | 2篇 |
1968年 | 1篇 |
1964年 | 1篇 |
1960年 | 1篇 |
1959年 | 2篇 |
1956年 | 3篇 |
1955年 | 2篇 |
1954年 | 1篇 |
排序方式: 共有302条查询结果,搜索用时 31 毫秒
31.
Three novel pentacyclic meroterpenoids with a unique dilactone structure containing C-C bonded bi- and tricyclic γ-lactone moieties, biyoulactones A-C (1-3), were isolated from the roots of Hypericum chinense, and their structures were elucidated on the basis of spectroscopic data. The relative and absolute stereochemistry of 1 was assigned by a combination of NOESY and a single crystal X-ray diffraction analysis. 相似文献
32.
Futaba DN Yamada T Kobashi K Yumura M Hata K 《Journal of the American Chemical Society》2011,133(15):5716-5719
The layer number is of great importance for nanocarbon materials, such as carbon nanotubes (CNTs) and graphene. While simple optical methods exist to evaluate few-layer graphene, equivalent analysis for CNTs is limited to transmission electron microscopy. We present a simple macroscopic method based on the (002) X-ray diffraction peak to evaluate the average wall number of CNTs in the range from single- to few-walled. The key was the finding that the (002) peak could be decomposed into two basic components: the intertube structure (outer-wall contacts) and the intratube structure (concentric shells). Decomposition of the peaks revealed a linear relationship between the average wall number and the ratio of the intertube and intratube contributions to the (002) peak. Good agreement with CNTs having average wall numbers ranging from 1 to ~5 demonstrated this as a macroscopic method for average wall number analysis. 相似文献
33.
34.
35.
Ko-Ki Kunimoto Kouji Kimura Takatomo Takai Hitoshi Senda Motoo Shiro Akio Kuwae 《光谱学快报》2013,46(4):509-522
Two polymorphic forms (I and II) of 4-fluorophenylpyruvic acid (F-PPA) were obtained by crystallization from different solvents, showing a melting point at 163.2 and 171.0 °C. Crystal structures of polymorphs I and II were determined by X-ray crystallography. IR and Raman spectra of the two polymorphs were measured and the spectral characteristics were compared with those of phenylpyruvic acid. the two polymorphs show similar molecular and crystal structures to each other, except for the molecular geometries of the enol and the carboxylic acid moieties. Distinct IR spectral differences which result from the crystal field splitting were observed between the two polymorphs. 相似文献
36.
37.
Motoo Tori Aki Watanabe Yasuko Okamoto Shigeru Takaoka Chiaki Kuroda Ryo Hanai 《Tetrahedron》2008,64(19):4486-4495
Twenty-six eremophilane-type sesquiterpenoids, including six new compounds, were isolated from the title species. One of the new compounds, kanaitzensol, suggested the presence of an enzyme for the conversion of eremophil-7(11)-en-8-one derivative to furanoeremophilanes. The plant was collected at 15 locations in Yunnan Province of China and found to be diverse with respect to its sesquiterpenoid composition. DNA sequencing also revealed a large intraspecific diversity of the plant. 相似文献
38.
Novel chiral phosphonoacetates bearing a stereogenic phosphorus atom were successfully synthesized by enzyme-catalyzed kinetic resolution of racemic phosphonoacetates. 相似文献
39.
40.