全文获取类型
收费全文 | 7445篇 |
免费 | 1385篇 |
国内免费 | 1982篇 |
专业分类
化学 | 5552篇 |
晶体学 | 280篇 |
力学 | 534篇 |
综合类 | 225篇 |
数学 | 870篇 |
物理学 | 3351篇 |
出版年
2024年 | 26篇 |
2023年 | 138篇 |
2022年 | 239篇 |
2021年 | 237篇 |
2020年 | 254篇 |
2019年 | 241篇 |
2018年 | 211篇 |
2017年 | 264篇 |
2016年 | 260篇 |
2015年 | 351篇 |
2014年 | 419篇 |
2013年 | 600篇 |
2012年 | 625篇 |
2011年 | 727篇 |
2010年 | 622篇 |
2009年 | 554篇 |
2008年 | 648篇 |
2007年 | 626篇 |
2006年 | 523篇 |
2005年 | 463篇 |
2004年 | 372篇 |
2003年 | 285篇 |
2002年 | 295篇 |
2001年 | 274篇 |
2000年 | 305篇 |
1999年 | 202篇 |
1998年 | 131篇 |
1997年 | 121篇 |
1996年 | 118篇 |
1995年 | 105篇 |
1994年 | 85篇 |
1993年 | 80篇 |
1992年 | 75篇 |
1991年 | 57篇 |
1990年 | 41篇 |
1989年 | 37篇 |
1988年 | 34篇 |
1987年 | 27篇 |
1986年 | 21篇 |
1985年 | 22篇 |
1984年 | 22篇 |
1983年 | 14篇 |
1982年 | 14篇 |
1981年 | 18篇 |
1980年 | 5篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1974年 | 3篇 |
1971年 | 2篇 |
1965年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
51.
52.
Qiongyou Wu Fanqi Qu Jinqiao Wan Xun Zhu Yi Xia Ling Peng 《Helvetica chimica acta》2004,87(4):811-819
Ribavirin, the only small molecule available so far for treating hepatitis‐C‐virus infection, was recently used in an emergency context to treat patients with severe acute respiratory syndrome (SARS) in the early stages of the disease. To study the mechanisms responsible for the antiviral effects of ribavirin by using a photolabeling approach, we designed, synthesized, and characterized the azidotriazole nucleosides 1 and 2 as photolabeling probes of ribavirin. These probes were synthesized either by performing nucleophilic substitution of the corresponding bromotriazole nucleoside with NaN3 (Scheme 2) or by directly coupling the azidotriazole with the protected ribose sugar (Scheme 4). The azidotriazole nucleosides 1 and 2 showed a fast, clear‐cut photochemical reaction, which suggests that they are promising candidates for use in photolabeling studies. 相似文献
53.
J C Zhu C H Li Y Liu Z H Zhang A X Hou S S Qu 《Journal of Thermal Analysis and Calorimetry》2006,83(1):181-186
After the occurrence of 'Minamata disease' in 1950,
mercury aroused much more attention, and lots of studies concerned have been
made. The purpose of the present paper is to study the effect of mercuric
chloride on the mitochondria suspension isolated from the liver tissue of Cyprinus carpio from the direct viewpoint of energy
by using the microcalorimetric method. The metabolic thermogenic curves of
the mitochondria suspension at 25°C were obtained, and the mitochondria
metabolic thermokinetic equations were established, from which we obtained
the thermodynamic and thermokinetic parameters: thermogenic rate constant
(k), heat output (Q),
average heat power (Pav),
etc. Experimental results indicated that low concentration of mercuric chloride
(5 nmol Hg2+/(mg protein)) stimulates the thermogenesis
of mitochondria, suggesting a strong effect of uncoupling action, while high
concentration of mercuric chloride (20 nmol Hg2+/(mg
protein)) inhibits the metabolism of mitochondria completely, suggesting a
fatal effect on the phosphorylation system. The effect of Hg2+
on mitochondria is concentration-depended, from which the probable reaction
mechanism of Hg2+ to the mitochondria was proposed.
So the microcalorimetric method can be used in the toxicology research. 相似文献
54.
Organic photovoltaic (OPV) cells were fabricated via vacuum vapor deposition with {4-[2-(3-di-cyanomethylidene-5,5-dimethylcyclohexenyl)vinyl]phenyl}di(1-naphthyl)amine (DNP-2CN) as the electron donor, and fullerene (C60) as the electron acceptor. A thin film (10 nm) of tris(8-quinolinolato)aluminum (Alq3) was adopted as the buffer layer. A device based on this DNP-2CN exhibited an open circuit voltage (Voc) of 370 mV, a short-circuit current density (Jsc) of 0.61 mAocm 2, and a white-light power conversion efficiency ( η) of 0.09% (AM1.5, 75 mW.cm^- 2). 相似文献
55.
56.
The bimolecular single collision reaction potential energy surface of an isocyanate NCO radical with a ketene CH2CO molecule was investigated by means of B3LYP and QCISD(T) methods. The computed results indicate that two possible reaction channels exist on the surface. One is an addition-elimination reaction process, in which the CH2CO molecule is attacked by the nitrogen atom at its methylene carbon atom to lead to the formation of the intermediate OCNCH2CO followed by a C-C rupture channel to the products CH2NCO+CO. The other is a direct hydrogen abstraction channel from CHzCO by the NCO radical to afford the products HCCO+HNCO. Because of a higher barrier in the hydrogen abstraction reaction than in the addition-elimination reaction, the direct hydrogen abstraction pathway can only be considered as a secondary reaction channel in the reaction kinetics of NCO+ CH2CO. The predicted results are in good agreement with previous experimental and theoretical investigations. 相似文献
57.
Fe(acac)3-Al(i-Bu)3-α,α'-联吡啶催化丙烯腈与苯乙烯共聚合 总被引:1,自引:0,他引:1
研究了Fe(acac)3-Al(i-Bu)3-α,α'-联吡啶(acac=乙酰丙酮)催化体系催化丙烯腈(AN)与苯乙烯共聚合,用元素分析和核磁共振研究了共聚物的结构,在单体比为1:1时共聚物中丙烯腈/苯乙烯含量分别为49.3%和50.7%.用凝胶渗透色谱研究了聚合物分子量和分子量分布,共聚物分子量分布较窄.动力学研究表明共聚合反应对单体浓度呈一级关系,表观活化能为57.8kJ/mol. 相似文献
58.
A new sensing method (BAW-TAL technique), which combined the bulk acoustic wave (BAW) technique with the gelation reaction of Tachypleus amebocyte lysate (TAL), was used for viscosity and density measurement and applied to the detection of Escherichia coliform (E. coli). This method depended on the fact that the viscosity and density of the mixture increased, and as a result, the resonance frequency decreased correspondingly after TAL was mixed with the heated E. coli solution that contained endotoxin. Results showed that the frequency shift was linearly related to the logarithm of E. coli concentration in the range of 2.7x10(4)-2.7x10(8) cells/ml. The correlation coefficient was 0.996. This BAW-TAL method was compared with the standard pour plate counts (PPC) method. The proposed method was much more rapid and simpler for detection of E. coli than the traditional methods. 相似文献
59.
Annals of Global Analysis and Geometry - In this paper, we study a problem of finding compact hypersurfaces of prescribed mean curvature with free boundary in a ball. We transform the problem to an... 相似文献
60.
In this paper, a tumor immune model with time delay is studied. First, the stability of nonnegative equilibria is analyzed. Then the time delay τ is selected as a bifurcation parameter and the existence of Hopf bifurcation is proved. Finally, by using the canonical method and the central manifold theory, the criteria for judging the direction and stability of Hopf bifurcation are given. 相似文献