Fe3O4 Segregation and Transport Properties of La0.67Ca0.33MnO3

Effect of Fe3O4 segregation at grain boundaries on the electrical transport and magnetic properties of La0.67Ca0.33MnO3 is investigated. The experimental results show that the Fe3O4 segregation not only shifts the paramagnetic-ferromagnetic transition temperature of La0.6TCa0.33MnO3 to a lower temperature region but also induces a new transition in a lower temperature region. Meanwhile, the transition processes observed in both the resistivity and magnetization curves are obviously widened. Compared to pure La0.67Ca0.33MnO3, we assume that the Fe3O4 segregation level at the grain boundaries can modify the electrical transport and magnetic properties of La0.67Ca0.33MnO3.     

有机磷杀虫剂胺丙畏的红外光谱研究

本文采用红外光谱仪对有机磷杀虫剂胺丙畏进行研究,通过其红外光谱信息,对谱峰进行归属,并鉴定出胺丙畏中的Z,E-异构体。     

Synthesis, Structure and Characterization of Manganese（ Ⅱ ） Coordination Polymer with Camphoric Acid and 1, 10-Phenanthroline

IntroductionThe syntheses of metal-organic coordination poly-mers have been attracting increasing attention owing tothe potential applications of their functional materials incatalysis,non-linear optics,magnetism sensors andmolecular recognition[1—7].Coordination polymers crys-tallized from polyaromatic acids and metal-ions are ofgreat interest for their polymeric structures and porousproperties[8—12].Their network topologies based on mo-lecular building blocks are usually controlled and mod…     

U-矩阵理论、Bogoliubov变换以及BCS尝试波函数

本文应用U-矩阵理论研究了具有BCS哈氏量的超导体系,证明U-矩阵理论中的U-算符,一般与正则交换相联系。假设微扰的互作用哈氏量瞬时地被启动,并且体系的哈氏量Η_BCS稍经Hartree型近似或经C-数近似处理后,从U-矩阵理论便可推导出Bogoliubov变换。与此同时,还可推导出超导体系的BCS基态波函数,从而了解其正确性。     

Bayes分析中多源验前信息融合的ML-II方法

在Bayes小子样理论中,验前分布的获取和表示是一个关键问题.针对工程实践中遇到的验前信息的多源性,给出了一种基于第二类极大似然估计原理(M L-II)的多源异总体验前分布的融合方法,并通过仿真实例证明了该方法的有效性.     

以高温超导体为基础的颗粒复合磁电阻器件

外加磁场对超导电性有强烈抑制作用，等效于一个显的正磁电阻．将高温超导体与具有不同磁电阻特性的其它材料复合，构成纳米颗粒复合体，可改变其磁场响应，调节成分配比还可使总磁电阻在特定的温度和外磁场下改变符号，即可调谐磁电阻．根据这一原理，我们制备了以La1.85Sr0.15CuO4和YBa2Cu3O7-δ为基础的颗粒复合磁电阻器件，并在其中观测到了以可调谐磁电阻为代表的丰富的磁电现象．这些器件在磁探测、磁记录和磁场标定等方面具有重要应用价值．     

Inner Surface Modification of a Tube by Magnetic Glow-Arc Plasma Source Ion Implantation

A new method named the magnetic glow-arc plasma source ion implantation （MGA-PSⅡ） is proposed for inner surface modification of tubes. In MGA-PSⅡ, under the control of an axial magnetic field, which is generated by an electric coil around the tube sample, glow arc plasma moves spirally into the tube from its two ends. A negative voltage applied on the tube realized its inner surface implantation. Titanium nitride （TIN） films are prepared on the inner surface of a stainless steel tube in diameter 90mm and length 600mm. Hardness tests show that the hardness at the tube centre is up to 20 GPa. XRD, XPS and AES analyses demonstrate that good quality of TiN films can be achieved.     

用形状指数研究苯酚类化合物对大型蚤的急性毒性

基于分子拓扑理论，计算了18种取代苯酚的Kier分子形状拓扑指数（^mK）．利用最小二乘法建立了不同pH值下11种取代苯酚对大型蚤急性毒性（pIC50）的QSAR模型，其相关系数（R^2）依次为：0．963（pH=6．0），0．966（pH=7．8），0.846（pH=9．0）．这些模型的计算值与其实验值基本吻合．通过留一法检验及对其余7种取代苯酚类化合物的pIC50值进行预测，结果表明该模型具有良好的稳健性和预测能力．     

核子诱导的χcJ抑制

本文主要运用夸克交换模型计算所得的核子— χcJ 离解截面研究Pb +Pb和S +Pb中心碰撞过程中强子物质中的 χcJ 抑制 .并定性地研究了核子动量和核子气温度对热平均截面地影响 .Pb +Pb和S +Pb中心碰撞中 χcJ 存活率表明核子与反核子所诱导的 χcJ 抑制是很明显的 .     

Quantum Statistical Properties of k-Quantum Nonlinear Coherent States

In our preceding work, a class of k-quantum nonlinear coherent states, i.e., the k eigenstates of the powersBk (k ≥ 3) of the annihilation operator B=-a1/f(N) of f-oscillators, are introduced. In this paper, we introduce a newkind of higher-order squeezing and an antibunching effect. The quantum statistical properties of the k states are studied.The result shows that the M-th order [M = (n 1/2)k; n = 0, 1,...] squeezing effects exist in all of the k states when kis even. There is the antibunching effect in all of the k states.