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11.
12.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
13.
两个ιp(Γ,E)型空间的单位球面间满等距映射的表现定理及等距延拓 总被引:1,自引:0,他引:1
本文得到两个实的ιp(Γ,E)型空间单位球面之间满等距映射的表现定理(这里,1≤p<+∞,p≠2,E为内积空间),并导出上述映射可延拓为全空间上的实线性等距算子. 相似文献
14.
单壁碳纳米管的SERS研究 总被引:2,自引:2,他引:0
本文通过改进实验方法,将单壁碳纳米管的乙醇溶液与金胶混合并制作成固体薄膜,使单壁碳纳米管夹裹在金纳米粒子之间,保证了吸附的紧密性,获得了高质量的单壁碳纳米管SERS光谱。不但观测到文献中报道的径向呼吸振动模(RBM)和C-C正切拉伸模(GM)的增强,还在1100-1500cm-1区域观测到一组新峰,其峰形完整并有相当的强度。这些峰在现有的文献中几乎没有报导。文章对这组新峰的出现进行了初步的分析。 相似文献
15.
A new chemiluminescence method for the determination of carbamazepine (CBZ) has been developed. The method is based on the chemiluminescence produced in the reaction of tris(2,2'-bipyridine)ruthenium(III) and CBZ in an acidic medium. The chemiluminescence intensity was enhanced by organic solvents in the reaction system. Under the optimum experimental conditions, the calibration curve was linear over the range 4.0 x 10(-3)-8.6 x 10(-7) mol/L for CBZ. The detection limit (S/N = 3) was 2.5 x 10(-7) mol/L and the relative standard deviation of six replicate measurements was 2.6% for 4.0 x 10(-4) mol/L of CBZ. The possible reaction mechanism were also discussed. The chemiluminescence method was successfully applied to assay the CBZ contents in pharmaceutical tablets. 相似文献
16.
事件空间中二阶非Четаев型非完整系统的守恒律 总被引:1,自引:1,他引:0
研究事件空间中二阶非чeTaeB型非完整系统的守恒律。提出事件空间中的Jourdain原理,引入事件空间中的Jorudain生成元,给出无限小变换下的Jourdain原理的不变性条件。在一定条件下得到事件空间中系统的守恒律。并举例说明结果的应用。 相似文献
17.
本文通过对有效需求一物价指数统计模型的研究 ,估计出了有效需求方程 ,并且通过对模型的估计结果分析得出如下结论 :物价指数对有效需求的影响是显著的 :通货紧缩、物价指数持续走低是有效需求不足的主要原因 ,治理通货紧缩应该是解决我国有效需求不足的主要任务。 相似文献
18.
De Ming ZHU Ying SUN 《数学学报(英文版)》2007,23(8):1495-1504
In this paper, we study the dynamical behavior for a 4-dimensional reversible system near its heteroclinic loop connecting a saddle-focus and a saddle. The existence of infinitely many reversible 1-homoclinic orbits to the saddle and 2-homoclinic orbits to the saddle-focus is shown. And it is also proved that, corresponding to each 1-homoclinic (resp. 2-homoclinic) orbit F, there is a spiral segment such that the associated orbits starting from the segment are all reversible 1-periodic (resp. 2-periodic) and accumulate onto F. Moreover, each 2-homoclinic orbit may be also accumulated by a sequence of reversible 4-homoclinic orbits. 相似文献
19.
DING Ning FANG Jian-Hui 《理论物理通讯》2006,46(2):265-268
In this paper the Lie symmetry and conserved quantities for nonholonomic Vacco dynamical systems are studied. The determining equation of the Lie symmetry for the system is given. The general Hojman conserved quantity and the Lutzky conserved quantity deduced from the symmetry are obtained. 相似文献
20.
We report viscometric data collected in a Couette rheometry on dilute, single‐solvent polystyrene (PS)/dioctyl phthalate (DOP) solutions over a variety of polymer molecular weights (5.5 × 105 ≤ Mw ≤ 3.0 × 106 Da) and system temperatures (288 K ≤ T ≤ 318 K). In view of the essential viscometric features, the current data may be classified into three categories: The first concerns all the investigated solutions at low shear rates, where the solution properties are found to agree excellently with the Zimm model predictions. The second includes all sample solutions, except for high‐molecular‐weight PS samples (Mw ≥ 2.0 × 106 Da), where excellent time–temperature superposition is observed for the steady‐state polymer viscosity at constant polymer molecular weights. No similar superposition applies at a constant temperature but varied polymer molecular weights, however. The third appears to be characteristic of dilute high‐molecular‐weight polymer solutions, for which the effects of temperature on the viscosity curve are further complicated at high shear rates. The implications concerning the relative importance of hydrodynamic interactions, segmental interactions, and chain extensibility with increasing polymer molecular weight, system temperature, and shear rate are discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 787–794, 2006 相似文献