有机高分子固载钯催化剂的羰基化和加氢催化性能

本文利用耐温性能较好的主链上含有多个配位原子(N,O)能成膜的直链高分子杂环联苯聚醚酮(PEK),带酚酞侧基的聚醚砜(PES-C)和两种聚酰亚胺(PCK和PIK)为载体固载PdCl~2,制备了高分子固载钯催化剂。研究了它们在烯丙基溴的常压羰基化反应和1-辛烯的常压加氢反应中的催化性能。考察了催化剂的制备方法、Pd含量、溶剂和高分子的主链结构对催化剂活性的影响。催化剂Pd-PEK(Ⅰ) (Pd wt%=0.22%)和Pd-PES-C(Ⅱ)(Pd wt%=0.28%)在温和的条件下对上述两反应都表现出了很高的催化活性。在极低的Pd含量(Pd wt%=0.04%)时,催化剂Pd-PES-C(Ⅲ)显示出了特别高的初活性,TOF~m~a~x分别达345mol CO/mol Pd·min和493mol H~2/mol Pd·min。实验结果表明制备方法等因素对催化剂的活性有很大的影响。     

FT-Raman Spectra Studies on Open Ferrocene

ＦＴ－ＲａｍａｎＳｐｅｃｔｒａＳｔｕｄｉｅｓｏｎＯｐｅｎＦｅｒｒｏｃｅｎｅＷＡＮＧＹｕｅ;ＪＩＡＮＧＳｈｉ－ｍｅｉ;ＦＡＮＹｕ－ｇｕｏａｎｄＳＵＮＣｈｕｎ－ｔｉｎｇ（ＴｈｅＫｅｙＬａｂｏｒａｔｏｒｙｆｏｒＭｏｌｅｃｕｌａｒＳｐｅｃｔｒｕｍａｎｄＳｔｒ...     

水溶液中芘的荧光被核酸碱基猝灭的研究

众所周知,稠环芳烃是一类具有致癌性的物质.虽然对其致癌机理的认识尚未形成一致的看法,但一般都认为同稠环芳烃与DNA,蛋白质等生物活性物质的相互作用有关.因为致癌物后的致癌作用最终都是通过损伤细胞中的DNA而实现的.     

荧光猝灭方法研究腺苷酸衍生物与嘧啶碱的弱相互作用──Stern-Volmer方程在竞争吸收体系中的修正式

已知在液氮温度下(77 K)核酸碱基之间能生成基态复合物^[1],这些复合物的荧光发射有比较大的红移.在室温条件下,核酸碱基的荧光发射量子产率很低,以至几乎无法检测.     

The Unitarity of the W(3) Algebra from SU(3) Parafermion

We express the vacuum expectation value of the SU(3)k parafermion fields by that of two bosons and SU(3)_k current algebra. When k = 1,2,3, the SU(3)_k current algebra becomes an inner product of a unitary representation, and T(z), W⁽³⁾(z) are equivalent to "quasiself-adjoint" operators in this represen tation.     

Supersymmetric Pair Coherent States

Based on the permu table property between the two-mode boson-fermion annihilator for a supersymmetric harmonic oscillator, which is described by H = b^↑b + f^↑f, and the "charge" operators b^↑b - f^↑f we construct the supersymmetric pair coherent state. The super-lie algebra associated with the supersymmetric pair coherent state is analyzed.     

Supersymmetric Unitary Operator for Some Generalized Jaynes-Cummings Models

We introduce supersymmetric unitary operators to directly diagonalize some generalized Jaynes-Cummings (J-C) Hamiltonians; which more deeply shows that supersymmetry is a natural language to depict the J-C model.     

SYNTHESES OF AZETIDINES VIA PHOTOCYCLOADDITION OF C=C TO C=N DOUBLE BONDS

The photocycloaddition of 6-azauracil (AU) with olefins have been carried out. Four new compounds,1,2,4-triazabicyclo [4,2,0] octane and 1,2,4-triazatricyclo [4,2,0^1.6,0^7.12]dodecane derivatives,were obtained. Based on structure identificationof productsand photosensitization behavior of this syste,the regioselection and the multiplicity of thisreaction were discussed.     

Inverse of Radiation Field Operators and the Generalized Jaynes-Cummings Model

We generalize the standard Jaynes-Cummings model (JCM) to a model Hamiltonian with the radiation field operators being the inverse of a harmonic oscillator's creation and annihilation operators. Some new commutative relations about the inverse operators are derived and the generalized JCM Hamiltonian's eigenstates are derived.     

3-氯-2-烃基四氢吡喃的镁开环反应

研究了用镁对3-氯-2-烃基四氢吡喃(1)的开环反应,制得一系列5-烃基-4-戊烯-1-醇(2),上述反应产率高,立体选择性强,无论顺式或反式的(1)开环时都得到反式(2).