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31.
Wilfredo Hernndez Evgenia Spodine Rainer Richter Karl‐Heinz Hallmeier Uwe Schrder Lothar Beyer 《无机化学与普通化学杂志》2003,629(14):2559-2565
The platinum(II) mixed ligand complexes [PtCl(L1‐6)(dmso)] with six differently substituted thiourea derivatives HL, R2NC(S)NHC(O)R′ (R = Et, R′ = p‐O2N‐Ph: HL1; R = Ph, R′ = p‐O2N‐Ph: HL2; R = R′ = Ph: HL3; R = Et, R′ = o‐Cl‐Ph: HL4; R2N = EtOC(O)N(CH2CH2)2N, R′ = Ph: HL5) and Et2NC(S)N=CNH‐1‐Naph (HL6), as well as the bis(benzoylthioureato‐κO, κS)‐platinum(II) complexes [Pt(L1, 2)2] have been synthesized and characterized by elemental analysis, IR, FAB(+)‐MS, 1H‐NMR, 13C‐NMR, as well as X‐ray structure analysis ([PtCl(L1)(dmso)] and [PtCl(L3, 4)(dmso)]) and ESCA ([PtCl(L1, 2)(dmso)] and [Pt(L1, 2)2]). The mixed ligand complexes [PtCl(L)(dmso)] have a nearly square‐planar coordination at the platinum atoms. After deprotonation, the thiourea derivatives coordinate bidentately via O and S, DMSO bonds monodentately to the PtII atom via S atom in a cis arrangement with respect to the thiocarbonyl sulphur atom. The Pt—S‐bonds to the DMSO are significant shorter than those to the thiocarbonyl‐S atom. In comparison with the unsubstituted case, electron withdrawing substituents at the phenyl group of the benzoyl moiety of the thioureate (p‐NO2, o‐Cl) cause a significant elongation of the Pt—S(dmso)‐bond trans arranged to the benzoyl‐O—Pt‐bond. The ESCA data confirm the found coordination and bonding conditions. The Pt 4f7/2 electron binding energies of the complexes [PtCl(L1, 2)(dmso)] are higher than those of the bis(benzoylthioureato)‐complexes [Pt(L1, 2)2]. This may indicate a withdrawal of electron density from platinum(II) caused by the DMSO ligands. 相似文献
32.
The real solutions to a system of sparse polynomial equations may be realized as a fiber of a projection map from a toric variety. When the toric variety is orientable, the degree of this map is a lower bound for the number of real solutions to the system of equations. We strengthen previous work by characterizing when the toric variety is orientable. This is based on work of Nakayama and Nishimura, who characterized the orientability of smooth real toric varieties. 相似文献
33.
34.
N. E. Kochkina V. A. Padokhin O. A. Skobeleva 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2013,87(5):876-878
The unimodal distribution of hydrodynamic radii is determined by DLS measurements of starch molecule sizes. The starch was hydrolyzed in 0.3 M hydrochloric acid for 3–9 h. The ratio of amylose to amylopectin is shown to remain constant. 相似文献
35.
36.
Ushak S Spodine E Le Fur E Venegas-Yazigi D Pivan JY Schnelle W Cardoso-Gil R Kniep R 《Inorganic chemistry》2006,45(14):5393-5398
Two new hybrid organic/inorganic copper oxovanadium diphosphonates [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)] x H2O (1) and [(Cu2(phen)2(O3P(CH2)3PO3)(V2O5)] x C3H8 (2) have been obtained by hydrothermal synthesis. The compounds are monoclinic, and they crystallize in the space group P2(1)/n with cell parameters of a = 11.788(2) A, b = 17.887(3) A, c = 14.158(2) A, and beta = 93.99(0) degrees and in the space group C2/c with cell parameters of a = 11.025(1) A, b = 18.664(2) A, c = 15.054(2) A, and beta = 90.06(0) degrees, respectively. Both compounds present two-dimensional frameworks built up from infinite chains of corner-sharing vanadium tetrahedra and diphosphonate groups connected by copper tetramers for (1) and copper dimers for (2). The remarkable feature of (2) is the encapsulation of propane molecules, stabilized by strong hydrogen bonding between the layers. The magnetic properties of the compounds have been investigated showing antiferromagnetic coupling with Tmax = 64 K for (1) and Curie-like paramagnetic behavior for (2). 相似文献
37.
Evgenia Yu. Basova Irina Yu. Goryacheva Tatiana Yu. Rusanova Natalia A. Burmistrova Richard Dietrich Erwin Märtlbauer Christ’l Detavernier Carlos Van Peteghem Sarah De Saeger 《Analytical and bioanalytical chemistry》2010,397(1):55-62
An immunochemically based test for non-instrumental simultaneous detection of zearalenone (ZEA) and T-2 toxin (T2) in feed was developed. The method combines clean-up of sample extract, pre-concentration of analytes by immunoextraction and immunodetection through the enzymatic reaction of horseradish peroxidase (HRP). The test is housed inside a standard 1-mL solid-phase extraction column and consists of three layers: two test layers (one for ZEA and another for T2) with immobilised specific antibodies and one control layer with bound anti-HRP antibodies. Feed extract was passed through an additional column with clean-up layer, which was disconnected after extract application. Total assay time was about 15 min for six samples and detection time was 4 min after chromogenic substrate application. Under optimised conditions a cut-off level for ZEA and T2 of 100 µg/kg was established. Different feed types were analysed for ZEA and T2 contamination by the proposed method and results were confirmed by LC-MS/MS. Figure
An immunochemically-based test for non-instrumental simultaneous detection of zearalenone (ZEA) and T-2 toxin (T2) in feed. 相似文献
38.
Svetlana A. Popova Evgenia V. Pavlova Oksana G. Shevchenko Irina Yu. Chukicheva Aleksandr V. Kutchin 《Molecules (Basel, Switzerland)》2021,26(12)
The pyrazoline ring is defined as a “privileged structure” in medicinal chemistry. A variety of pharmacological properties of pyrazolines is associated with the nature and position of various substituents, which is especially evident in diarylpyrazolines. Compounds with a chalcone fragment show a wide range of biological properties as well as high reactivity which is primarily due to the presence of an α, β-unsaturated carbonyl system. At the same time, bicyclic monoterpenoids deserve special attention as a source of a key structural block or as one of the pharmacophore components of biologically active molecules. A series of new diarylpyrazoline derivatives based on isobornylchalcones with different substitutes (MeO, Hal, NO2, N(Me)2) was synthesized. Antioxidant properties of the obtained compounds were comparatively evaluated using in vitro model Fe2+/ascorbate-initiated lipid peroxidation in the substrate containing brain lipids of laboratory mice. It was demonstrated that the combination of the electron-donating group in the para-position of ring B and OH-group in the ring A in the structure of chalcone fragment provides significant antioxidant activity of synthesized diarylpyrazoline derivatives. 相似文献
39.
Edward A. Karakhanov Elena A. Runova Grigori V. Berezkin Evgenia B. Neimerovets 《Macromolecular Symposia》1994,80(1):231-240
Catalytic reactions of carbon monoxide are investigated in presence of polyethylene-bound palladium and rhodium complexes and it was shown that such catalysts with temperature-dependent solubility are applicable for carbonylation of organic halides and hydroformylation of alkenes due to high activity and recoverability. 相似文献