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211.
Cramer N Buchweitz M Laschat S Frey W Baro A Mathieu D Richter C Schwalbe H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(9):2488-2503
Cylindramide (1) was built up from three components: a hydroxyornithine derivative 7, a tetrazolylsulfone 8, and a substituted pentalene subunit 9. Derivative 7 was prepared in a six-step reaction sequence involving the Wittig reaction and a Sharpless asymmetric dihydroxylation starting from N-Boc-3-aminopropanal (12). Tetrazolylsulfone 8 was accessible in four steps from dioxinone 22. The synthesis of the pentalene fragment 9 started from cycloocta-1,5-diene 26, that was converted into enantiopure bicyclo[3.3.0]octanedione 29. The latter was functionalized to give derivative 9. The total synthesis was accomplished by inducing C-C bond formation by Sonogashira coupling of derivatives 9 and 7 followed by olefination with tetrazolylsulfone 8 under Julia-Kocienski conditions, macrocyclization, and subsequent Lacey-Dieckmann condensation to form the tetramic acid unit. As indicated by extensive 1H and 13C NMR spectroscopic investigations (DQF-COSY, ROESY spectra), the stereochemistry of synthetic cylindramide (1) corresponds with that of the naturally occurring product. ROE data were used for molecular modeling of the lowest-energy structures for cylindramide. 相似文献
212.
Bowman A Allix M Pelloquin D Rosseinsky MJ 《Journal of the American Chemical Society》2006,128(39):12606-12607
The n = 3 Ruddlesden-Popper phase Sr3LaFe1.5Co1.5O10+/-delta is capable of sustaining O contents as low as O7.5 with a mean metal oxidation state of +2 and three coordination at the central site in the trilayer of originally octahedral transition metal sites. The shortening of the axial bonds to the flanking octahedral layers stabilizes the low oxidation state and consequent unusual low coordination number of the Fe2+ and Co2+ cations within the extended structure. 相似文献
213.
Roger M Barros N Arliguie T Thuéry P Maron L Ephritikhine M 《Journal of the American Chemical Society》2006,128(27):8790-8802
Reaction of U(NEt(2))(4) with HS-2,4,6-(t)Bu(3)C(6)H(2) (HSMes) gave U(SMes)(3)(NEt(2))(py) (1), whereas similar treatment of U[N(SiMe(3))SiMe(2)CH(2)][N(SiMe(3))(2)](2) afforded U(SMes)[N(SiMe(3))(2)](3) (2) and U(SMes)(3)[N(SiMe(3))(2)]. The first neutral homoleptic uranium(IV) thiolate to have been crystallographically characterized, U(SMes)(4) (4), was isolated from the reaction of U(BH(4))(4) and KSMes. The first homoleptic thiolate complex of uranium(III), U(SMes)(3) (5), was synthesized by protonolysis of U[N(SiMe(3))(2)](3) with HSMes in cyclohexane. The crystal structure of 5 exhibits the novel eta(3) ligation mode for the arylthiolate ligand. Comparison of the crystal structure of 5 with those of the isomorphous lanthanide congeners Ln(SMes)(3) (Ln = La, Ce, Pr, and Nd) indicates that the U-S, U-C(ipso)(), and U-C(ortho)() bond lengths are shorter than the corresponding ones in the 4f-element analogues, when taking into account the variation in the ionic radii of the metals. The distance between the uranium and the carbon atoms involved in the U...H-C epsilon agostic interaction of each thiolate ligand is shorter, by approximately 0.05 A, than that expected from a purely ionic bonding model. The lanthanide(III)/actinide(III) differentiation was analyzed by density functional theory (DFT). The nature of the M-S bond is shown to be ionic strongly polarized at the sulfur for M = U and iono-covalent (i.e. strongly ionic with low orbital interaction), for M = Ln. The strength of the U...H-C epsilon agostic interaction is proposed to be controlled by the maximization of the interaction between U(+) and S(-) under steric constraints. The eta(3) ligation mode of the arylthiolate ligand is also obtained from DFT. 相似文献
214.
We propose a numerical method to accurately discriminate the influence of the different intrachannel nonlinear effects occurring in 40 Gbit/s optical transmissions, following an analogy with methods used to discriminate WDM interchannel effects. In contrast to other studies showing the predominance of intrachannel cross-phase modulation when low-dispersion fibers are used, in our study intrachannel four-wave mixing is the most penalizing effect in all investigated cases. 相似文献
215.
Swiss rolls are one instance of metamaterials, and can be described as an effective medium with a complex, anisotropic magnetic permeability. It has been shown that bundles of Swiss rolls can guide the magnetic flux in magnetic resonance measurements and increase the coupling between the nuclear spins and the receiver coil. Here, we investigate, with a numerical model, whether Swiss rolls can boost the detected signal in a NMR experiment, where the rolls could provide a low-reluctance return path for the magnetic flux when shaped in a yoke encircling the sample. The system consisting of the nuclear spin, the rolls and the receiver coil is analyzed with the method of finite differences in time domain (FDTD). The results show that small gains in the received signal are possible, but only if the losses (resistive and dielectric) in the rolls are reduced by over one order of magnitude from their present value in state-of-the-art materials. This situation arises because of the energy dissipation in the rolls and the mode splitting caused by the coupling between the rolls and the resonant coil. 相似文献
216.
Mathieu Lewin 《Letters in Mathematical Physics》2018,108(4):985-1006
For neutral and positively charged atoms and molecules, we prove the existence of infinitely many Hartree–Fock critical points below the first energy threshold (that is, the lowest energy of the same system with one electron removed). This is the equivalent, in Hartree–Fock theory, of the famous Zhislin–Sigalov theorem which states the existence of infinitely many eigenvalues below the bottom of the essential spectrum of the N-particle linear Schrödinger operator. Our result improves a theorem of Lions in 1987 who already constructed infinitely many Hartree–Fock critical points, but with much higher energy. Our main contribution is the proof that the Hartree–Fock functional satisfies the Palais–Smale property below the first energy threshold. We then use minimax methods in the N-particle space, instead of working in the one-particle space. 相似文献
217.
Marie Labat Jean-Blaise Brubach Alessandra Ciavardini Marie-Emmanuelle Couprie Erik Elkaim Pierre Fertey Tom Ferte Philippe Hollander Nicolas Hubert Emmanuelle Jal Claire Laulhé Jan Luning Olivier Marcouillé Thierry Moreno Paul Morin Francois Polack Pascale Prigent Sylvain Ravy Jean-Paul Ricaud Pascale Roy Mathieu Silly Fausto Sirotti Amina Taleb Marie-Agnès Tordeux Amor Nadji 《Journal of synchrotron radiation》2018,25(2):385-398
The investigation of ultrafast dynamics, taking place on the few to sub‐picosecond time scale, is today a very active research area pursued in a variety of scientific domains. With the recent advent of X‐ray free‐electron lasers (XFELs), providing very intense X‐ray pulses of duration as short as a few femtoseconds, this research field has gained further momentum. As a consequence, the demand for access strongly exceeds the capacity of the very few XFEL facilities existing worldwide. This situation motivates the development of alternative sub‐picosecond pulsed X‐ray sources among which femtoslicing facilities at synchrotron radiation storage rings are standing out due to their tunability over an extended photon energy range and their high stability. Following the success of the femtoslicing installations at ALS, BESSY‐II, SLS and UVSOR, SOLEIL decided to implement a femtoslicing facility. Several challenges were faced, including operation at the highest electron beam energy ever, and achievement of slice separation exclusively with the natural dispersion function of the storage ring. SOLEIL's setup also enables, for the first time, delivering sub‐picosecond pulses simultaneously to several beamlines. This last feature enlarges the experimental capabilities of the facility, which covers the soft and hard X‐ray photon energy range. In this paper, the commissioning of this original femtoslicing facility is reported. Furthermore, it is shown that the slicing‐induced THz signal can be used to derive a quantitative estimate for the degree of energy exchange between the femtosecond infrared laser pulse and the circulating electron bunch. 相似文献
218.
Balaji Subramanian Nadjda Tchoukanova Yahia Djaoued Claude Pelletier Mathieu Ferron Jacques Robichaud 《Journal of Raman spectroscopy : JRS》2014,45(4):299-304
Recent research interests in geometrical isomers of astaxanthin (AST) are motivated by their metabolic activities in aquatic animals and human. It has been established that cis‐isomers of AST are selectively absorbed in human plasma during the metabolic process; however, exact absorption mechanism is still unclear. Hence, a detailed investigation of the structural and optical properties of geometrical isomers of AST is required. Among the techniques available for the study of AST and other carotenoids, Raman spectroscopy has been much acclaimed. Raman spectra have been shown to be influenced by the electronic and mechanical confinement effects arising from the conjugated polyene chain of carotenoids. In this work, we present Raman studies of geometrical isomers of AST, along with their optical absorption characteristics. Geometrical isomers of AST were prepared by heating all trans‐AST in solution form, and the isomers were separated using high performance liquid chromatography. Optical absorption spectra of cis‐isomers of AST showed hypsochromic shifts in the main absorption band and formation of new bands at lower wavelengths. A detailed Raman spectral analysis performed on the cis‐isomers of AST showed new modes which have not been observed and accounted for so far. In addition, we demonstrate that the electronic and mechanical confinement effects in the polyene chain of AST play an important role in the Raman spectra of geometrical isomers of AST. It is anticipated that this work will demonstrate that Raman spectroscopy is an important diagnostic tool in distinguishing and identifying the geometrical isomers of AST. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
219.
We study here the elementary properties of the relative entropy ${\mathcal{H}_\varphi(A, B) = {\rm Tr}[\varphi(A) - \varphi(B) - \varphi'(B)(A - B)]}$ for φ a convex function and A, B bounded self-adjoint operators. In particular, we prove that this relative entropy is monotone if and only if φ′ is operator monotone. We use this to appropriately define ${\mathcal{H}_\varphi(A, B)}$ in infinite dimension. 相似文献
220.
A range of tricyclic nitrogen heterocycles were synthesized in a straightforward and efficient manner via a sequence involving palladium-catalyzed N-arylation and C(sp(3))-H arylation as the key steps. Whereas the C(sp(3))-H arylation furnished fused 6,5,6-membered ring systems efficiently, the formation of the more strained 6,5,5-membered systems proved to be more challenging and required a subtle adjustment of the reaction conditions. 相似文献