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91.
Battaglieri M Brunoldi M De Vita R Laget JM Osipenko M Ripani M Taiuti M Adams G Amaryan MJ Anciant E Anghinolfi M Armstrong DS Asavapibhop B Asryan G Audit G Auger T Avakian H Barrow S Beard K Bektasoglu M Berman BL Bersani A Bianchi N Biselli AS Boiarinov S Bouchigny S Bradford R Branford D Briscoe WJ Brooks WK Burkert VD Calarco JR Capitani GP Carman DS Carnahan B Cazes A Cetina C Cole PL Coleman A Cords D Corvisiero P Crabb D Crannell H Cummings JP DeSanctis E Degtyarenko PV Demirchyan R 《Physical review letters》2003,90(2):022002
The differential cross section, dsigma/dt, for omega meson exclusive photoproduction on the proton above the resonance region (2.6相似文献
92.
Helen O. Leung Oluwatoyin M. Ibidapo Mary B. Bianchi 《Journal of Molecular Spectroscopy》2003,222(1):3-14
The rotational spectra of six isotopomers of the linear and bent isomers of HF-N2O have been collected in the 7-18 GHz region with a Fourier transform microwave spectrometer. The nuclear hyperfine structure in the spectra produced by HF spin-spin coupling interaction and nuclear quadrupole coupling interactions due to the D nucleus of DF and the nuclei of N2O have been resolved and analyzed. In the linear isomer, H in HF is bonded to the terminal N in N2O. The NF bond lengths are 2.9808(2) Å for the HF-containing isotopomers and 2.9732(2) Å for the DF-containing isotopomers. The zero point angles are 23.1° for HF and 31-34° for N2O. The hyperfine constants suggest that the HF bond is lengthened by 0.0105 Å upon complexation and that the electric field gradients of the two nitrogen nuclei in N2O are perturbed differently in the complex. In the bent isomer, the hydrogen bond is formed between HF and O in N2O. The intermolecular distances are 3.4942(2) Å for the HF-containing isotopomers and 3.4436(2) Å for the DF-containing isotopomers, with HF and N2O forming angles of 34° and 46°, respectively, with the intermolecular axis. The nuclear quadrupole coupling constants of the two nitrogen nuclei do not indicate electric field gradient perturbation in this isomer. 相似文献
93.
Palii AV Tsukerblat BS Coronado E Clemente-Juan JM Borrás-Almenar JJ 《Inorganic chemistry》2003,42(7):2455-2458
The microscopic theory of the magnetically anisotropic effective pseudo-spin-(1)/(2) Hamiltonian for a pair of Co(2+) ions is reported. In the framework of the second-order perturbation approach, the analytical expressions are found for the components of the tensor of the exchange interaction, g-tensor, and the factor in the temperature independent paramagnetic contribution. The parameters of the Hamiltonian are expressed in terms of the basic intra- and intercenter parameters of the pair, namely, the spin-orbit coupling constant, orbital reduction factor, exchange integral, and low symmetry crystal field parameters including axial and rhombic terms. 相似文献
94.
95.
96.
We have synthesized a new environment-sensitive fluorophore, 6-N,N-dimethylamino-2,3-naphthalimide (6DMN). This chromophore exhibits valuable fluorescent properties as a biological probe with emission in the 500-600 nm range and a marked response to changes in the environment polarity. The 6DMN fluorescence is red-shifted in polar protic environments, with the maximum emission intensity shifting more than 100 nm from 491 nm in toluene to 592 nm in water. Additionally, the fluorescence quantum yield decreases more than 100-fold from chloroform (Phi = 0.225) to water (Phi = 0.002). The scope and applications of the 6DMN probe are expanded with the synthesis of an Fmoc-protected amino acid derivative (5), which contains the fluorophore. This unnatural amino acid has been introduced into several peptides, demonstrating that it can be manipulated under standard solid-phase peptide synthesis conditions. Peptides incorporating the new residue can be implemented for monitoring protein-protein interactions as exemplified in studies with Src homology 2 (SH2) phosphotyrosine binding domains. The designed peptides exhibit a significant increase in the quantum yield of the long wavelength fluorescence emission band (596 nm) upon binding to selected SH2 domains (e.g., Crk SH2, Abl SH2, and PI3K SH2). The peptides can be used as ratiometric sensors, since the short wavelength band (460 nm) was found almost invariable throughout the titrations. 相似文献
97.
The orthorhombic crystal structure of [Co2(CO)6(μ‐CO)(μ‐C4O2H2)] ( 1 ) was determined at 150 K (Fig. 1). Two C−H⋅⋅⋅O bonds connect the molecules, forming waving ribbons along the b axis. The experimental electron density, determined with the aspherical‐atom formalism, was analyzed with the topological theory of molecular structure. The presence of the Co−Co bond critical point indicates for the first time the existence of a metal−metal bond in a system with bridged ligands. The bond critical properties of the intramolecular bonds and of the intermolecular interactions show features similar to those found in [Mn2(CO)10], confirming our previously established bonding classification for organometallic and coordination compounds. 相似文献
98.
Mario Bianchi Gloria Menchi Franco Francalanci Franco Piacenti Ugo Matteoli Piero Frediani Carlo Botteghi 《Journal of organometallic chemistry》1980,188(1):109-119
Saturated monocarboxylic acids up to C6, several bicarboxylic acids and some of the corresponding anhydrides are hydrogenated in the homogeneous phase with H4Ru4(CO)8(PBu3)4 as catalyst to give the corresponding alcohols (present among the reaction products as esters) or lactones at 100–200°C under a pressure of 100–200 atm of hydrogen. Anhydrides react at temperatures lower than those needed for acids. Esters are not reduced. Only δ-valerolactone is hydrogenated to 1,5-pentanediol. Ruthenium carbonyl carboxylates have been recovered at the end of the reaction and appear to be catalytically active intermediates. 相似文献
99.
Arsac F Bianchi D Chovelon JM Ferronato C Herrmann JM 《The journal of physical chemistry. A》2006,110(12):4213-4222
The present study concerns an experimental microkinetic approach of the photocatalytic oxidation (PCO) of isopropyl alcohol (IPA) into acetone on a pure anatase TiO2 solid according to a procedure previously developed. Mainly, the kinetic parameters of each surface elementary step of a plausible kinetic model of the PCO of IPA are experimentally determined: natures and amounts of the adsorbed species and rate constants (preexponential factors and activation energies). These kinetic parameters are used to evaluate a priori the catalytic activity (turnover frequency, TOF, in s(-1)) of the solid that is compared to the experimental value. The kinetics parameters are obtained by using experiments in the transient regime with either a FTIR or a mass spectrometer as a detector. The microkinetic study shows that only strongly adsorbed IPA species (two species denoted nd-IPA(sads) and d-IPA(sads) due to non- and dissociative chemisorption of IPA respectively) are involved in the PCO of IPA. A strong competitive chemisorption between IPA(sads) and a strongly adsorbed acetone species controls the high selectivity in acetone of the PCO at a high coverage of the surface by IPA(sads). The apparent rate constant (1.4 10(-3) s(-1)) of the Langmuir-Hinshelwood elementary step between IPA(sads) and the active oxygen containing species generated by the UV irradiation provides the TOF of the PCO for IPA/O2 gas mixtures. The kinetic parameters of the elementary steps determined by the experimental microkinetic approach allow us to provide a reasonable simulation of the experimental data (coverages of the adsorbed species and partial pressures of the gases of interest) recorded during a static PCO of IPA(sads) species. 相似文献
100.
Coronado E Galán-Mascarós JR Martí-Gastaldo C Palomares E Durrant JR Vilar R Gratzel M Nazeeruddin MK 《Journal of the American Chemical Society》2005,127(35):12351-12356
The selectivity and sensitivity of two colorimetric sensors based on the ruthenium complexes N719 [bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) bis(tetrabutylammonium) bis(thiocyanate)] and N749 [(2,2':6',2' '-terpyridine-4,4',4' '-tricarboxylate)ruthenium(II) tris(tetrabutylammonium) tris(isothiocyanate)] are described. It was found that mercury ions coordinate reversibly to the sulfur atom of the dyes' NCS groups. This interaction induces a color change in the dyes at submicromolar concentrations of mercury. Furthermore, the color change of these dyes is selective for mercury(II) when compared with other ions such as lead(II), cadmium(II), zinc(II), or iron(II). The detection limit for mercury(II) ions--using UV-vis spectroscopy--in homogeneous aqueous solutions is estimated to be approximately 20 ppb for N719 and approximately 150 ppb for N749. Moreover, the sensor molecules can be adsorbed onto high-surface-area mesoporous metal oxide films, allowing reversible heterogeneous sensing of mercury ions in aqueous solution. The results shown herein have important implications in the development of new reversible colorimetric sensors for the fast, easy, and selective detection and monitoring of mercuric ions in aqueous solutions. 相似文献