全文获取类型
收费全文 | 710篇 |
免费 | 36篇 |
国内免费 | 3篇 |
专业分类
化学 | 500篇 |
晶体学 | 8篇 |
力学 | 17篇 |
数学 | 107篇 |
物理学 | 117篇 |
出版年
2023年 | 4篇 |
2022年 | 12篇 |
2021年 | 13篇 |
2020年 | 23篇 |
2019年 | 13篇 |
2018年 | 6篇 |
2017年 | 11篇 |
2016年 | 20篇 |
2015年 | 22篇 |
2014年 | 20篇 |
2013年 | 30篇 |
2012年 | 60篇 |
2011年 | 58篇 |
2010年 | 44篇 |
2009年 | 20篇 |
2008年 | 59篇 |
2007年 | 44篇 |
2006年 | 37篇 |
2005年 | 34篇 |
2004年 | 23篇 |
2003年 | 18篇 |
2002年 | 16篇 |
2001年 | 9篇 |
2000年 | 7篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 9篇 |
1982年 | 3篇 |
1980年 | 4篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 7篇 |
1973年 | 2篇 |
1939年 | 3篇 |
1924年 | 2篇 |
排序方式: 共有749条查询结果,搜索用时 15 毫秒
81.
82.
83.
Semidefinite programming (SDP) may be seen as a generalization of linear programming (LP). In particular, one may extend interior point algorithms for LP to SDP, but it has proven much more difficult to exploit structure in the SDP data during computation. 相似文献
84.
Gusenbauer Claudia Peter Karolina Cabane Etienne Konnerth Johannes 《Cellulose (London, England)》2022,29(2):763-776
Cellulose - Chemical force microcopy, a variation of atomic force microscopy, opened the door to visualize chemical nano-properties of various materials in their natural state. The key function of... 相似文献
85.
Benoít Rigo Etienne Tullier Didier Barbry Daniel Couturier Vincent Warin Jocelyne Lamiot Franois Baert 《Journal of heterocyclic chemistry》1990,27(5):1383-1386
3,5-Dihydrobenz[f]indolizin-3-one was prepared by a novel dehydration reaction involving the heating of 1,2,3,5,10,10a-hexahydro[f]indolizine-3,10-dione with polyphosphoric acid. The structure of this new compound was established by X-ray crystallography, by nmr spectroscopy and by reduction to the known products 1,2,3,5-tetrahydrobenz[f]indolizin-3-one and 1,2,3,5,10,10a-hexahydrobenz[f]indolizin-3-one. 相似文献
86.
87.
Tandem CH Activation/Arylation Catalyzed by Low‐Valent Iron Complexes with Bisiminopyridine Ligands 下载免费PDF全文
Elise Salanouve Ghania Bouzemame Dr. Sébastien Blanchard Dr. Etienne Derat Dr. Marine Desage‐El Murr Prof. Louis Fensterbank 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(16):4754-4761
Tandem C?H activation/arylation between unactivated arenes and aryl halides catalyzed by iron complexes that bear redox‐active non‐innocent bisiminopyridine ligands is reported. Similar reactions catalyzed by first‐row transition metals have been shown to involve substrate‐based aryl radicals, whereas our catalytic system likely involves ligand‐centered radicals. Preliminary mechanistic investigations based on spectroscopic and reactivity studies, in conjunction with DFT calculations, led us to propose that the reaction could proceed through an inner‐sphere C?H activation pathway, which is rarely observed in the case of iron complexes. This bielectronic noble‐metal‐like behavior could be sustained by the redox‐active non‐innocent bisiminopyridine ligands. 相似文献
88.
The oscillating flow field in a thermoacoustic stack is visualized experimentally using PIV measurements, and computationally using results of low-Mach-number simulations. The experiments and computations are performed under similar conditions. Results are obtained for two distinct configurations, involving thin and thick stack plates. In the first case, the flow field around the edge of the stack exhibits elongated vorticity layers, while in the latter it is dominated by the shedding and impingement of concentrated vortices. A close agreement between experimental and computational results is found, thus providing strong support for both approaches and further predictions. To cite this article: P. Blanc-Benon et al., C. R. Mecanique 331 (2003). 相似文献
89.
Morgan Tizzotti Marie‐Pierre Labeau Thierry Hamaide Eric Drockenmuller Aurélia Charlot Etienne Fleury 《Journal of polymer science. Part A, Polymer chemistry》2010,48(13):2733-2742
Thermosensitive guar‐based hydrogels are obtained in water solutions by copper‐catalyzed 1,3‐dipolar cycloaddition between alkyne‐functionalized guars and α,ω‐diazido‐poly[(ethylene glycol)‐co‐(propylene glycol)]. Characterization by TGA, HR‐MAS 1H NMR, and rheology have shown that hydrogels with tunable physico‐chemical properties, such as crosslinking density, viscoelasticity, swelling ratio, and so forth, could be obtained by varying the guar molar mass, the degree of alkyne functionality, the guar/crosslinker weight ratio, and the reaction temperature. Based on swelling measurements, it has been shown that the thermal sensitiveness of guar‐based hydrogels is fast, reversible, and intimately related to the weight fraction of the thermosensitive crosslinker in the network. Finally, the monitoring of doxorubicin hydrochloride release has demonstrated the potential of these hydrogels as temperature‐dependent drug release devices. The robust, efficient, and orthogonal approach described herein represents a general approach towards the development of well‐controlled guar‐based hydrogels using α,ω‐diazido crosslinkers. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2733–2742, 2010 相似文献
90.