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51.
Songlan Sun Gaia De Angelis Dr. Stefania Bertella Marie J. Jones Dr. Graham R. Dick Prof. Esther Amstad Prof. Jeremy S. Luterbacher 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(5):e202312823
Concerns over the sustainability and end-of-life properties of fossil-derived surfactants have driven interest in bio-based alternatives. Lignocellulosic biomass with its polar functional groups is an obvious feedstock for surfactant production but its use is limited by process complexity and low yield. Here, we present a simple two-step approach to prepare bio-based amphiphiles directly from hemicellulose and lignin at high yields (29 % w/w based on the total raw biomass and >80 % w/w of these two fractions). Acetal functionalization of xylan and lignin with fatty aldehydes during fractionation introduced hydrophobic segments and subsequent defunctionalization by hydrogenolysis of the xylose derivatives or acidic hydrolysis of the lignin derivatives produced amphiphiles. The resulting biodegradable xylose acetals and/or ethers, and lignin-based amphiphilic polymers both largely retained their original natural structures, but exhibited competitive or superior surface activity in water/oil systems compared to common bio-based surfactants. 相似文献
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Nierengarten H Leize E Breuning E Garcia A Romero-Salguero F Rojo J Lehn JM Van Dorsselaer A 《Journal of mass spectrometry : JMS》2002,37(1):56-62
The self-assembly of the terdentate ligands 1a-h, based on terpyridine-like binding sites, with octahedrally coordinated metal ions, such as Fe(II), Co(II), Cu(II), Zn(II), Cd(II), Hg(II) and Pb(II), leads to the formation of the supramolecular grid-type complexes 2a-c(M(II)), 3d-g(M(II)) and 4h(M(II)). The structures and compositions of these coordination complexes in solution were deduced from electrospray mass spectrometry (ESMS) measurements. The results agree with the data available from x-ray radiocrystallography in the solid state and/or NMR spectroscopy in solution. ESMS may be applied in cases where other methods are difficult to use or inconclusive. This study stresses the power of ESMS in supramolecular chemistry. 相似文献
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García-Herrero A Montero E Muñoz JL Espinosa JF Vián A García JL Asensio JL Cañada FJ Jiménez-Barbero J 《Journal of the American Chemical Society》2002,124(17):4804-4810
We show that the conformational features of the molecular complexes of E. coli beta-galactosidase and O-glycosides may differ from those formed with closely related compounds in their chemical nature, such as C- and S-glycosyl analogues. In the particular case presented here, NMR and ab initio quantum mechanical results show that the 3D-shapes of the ligand/inhibitor within the enzyme binding site depend on the chemical nature of the compounds. In fact, they depend on the relative size of the stereoelectronic barriers for chair deformation or for rotation around Phi glycosidic linkage. 相似文献
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We have developed an aberro-polariscope that simultaneously measures spatially resolved polarization properties and wave-front aberration in a living human eye. The setup consists of an infrared Hartmann-Shack sensor that incorporates a polariscope. A series of four Hartmann-Shack images corresponding to independent polarization states were recorded. The corresponding wave-front aberration was computed from each image. Moreover, from each set of four images spatially resolved (over the pupil plane) parameters of polarization were also determined. This instrument allows useful information on both the optical and the biomechanical properties of the eye to be obtained. 相似文献
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We examine the long-run average availability and cost rate of a maintained system which deteriorates according to a random-shock process. Shocks arrive according to a Poisson process. The system fails whenever the cumulative damage exceeds a given threshold. The system's failures are not self-announcing, hence, failures must be detected via inspections. The system is inspected at periodic or exponentially distributed intervals. Systems are replaced by preventive maintenance or after failure (corrective maintenance), whichever occurs first. When the distribution function of the shock magnitudes belongs to the class of subexponential distributions, we obtain simple approximations for the availability and the cost rate. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
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Copper chloride-catalyzed S-arylation of arenethiols is effected with activated aryl chlorides in neat water by using ethylenediamine as the pair ligand/base. This convenient, environmentally more friendly procedure for the coupling of aryl chlorides allows the arylation between sterically demanding coupling partners. 相似文献
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