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51.
Protonated methane, CH(5)(+), is a key reactive intermediate in hydrocarbon chemistry and a borderline case for chemical structure theory, being the simplest example of hypercoordinated carbon. Early quantum mechanical calculations predicted that the properties of this species could not be associated with only one structure, because it presents serious limitations of the Born-Oppenheimer approximation. However, ab initio molecular dynamics and diffusion Monte Carlo calculations showed that the most populated structure could be pictured as a CH(3) tripod linked to a H(2) moiety. Despite this controversy, a model for the chemical bonds involved in this ion still lacks. Here we present a modern valence bond model for the electronic structure of CH(5)(+). The chemical bond scheme derived directly from our calculations pictures this ion as H(3)C...H(2)(+). The fluxionality can be seen as the result of a proton transfer between C-H bonds. A new insight on the vibrational bands at approximately 2400 and approximately 2700 cm(-1) is suggested. Our results show that the chemical bond model can be profitably applied to such intriguing systems. 相似文献
52.
Kilcoyne AL Aguilar A Müller A Schippers S Cisneros C Alna'washi G Aryal NB Baral KK Esteves DA Thomas CM Phaneuf RA 《Physical review letters》2010,105(21):213001
Experimental evidence is presented for confinement resonances associated with photoabsorption by a Xe atom in a C60 cage. The giant 4d resonance in photoionization of Xe is predicted to be redistributed into four components due to multipath interference of photoelectron waves reflected by the cage. The measurements were made in the photon energy range 60-150 eV by merging a beam of synchrotron radiation with a mass/charge selected Xe@C??+ ion beam. The phenomenon was observed in the Xe@C(58)(3+) product ion channel. [corrected] 相似文献
53.
基于惩罚与补贴的再制造闭环供应链网络均衡模型 总被引:1,自引:0,他引:1
为研究我国废旧电子产品(WEEE)立法的问题,分析了供应商、制造商、零售商、需求市场及回收商的行为,分别建立了变分不等式模型,并在此基础上建立了五级再制造闭环供应链网络均衡模型。模型考虑了政府对于制造商的惩罚政策与对于回收商的补贴政策。通过修正投影算法求解算例,仿真分析了旧材料转化率、回收率、惩罚及补贴政策对闭环供应链网络均衡结果的影响。结果表明,随着政府对于回收商的补贴的增加,不但回收商的回收量提高,闭环供应链的新材料需求量、旧材料需求量、销售量均增加;相反,随着政府对于制造商未完成的回收量的罚款增加,回收量、新材料需求量、旧材料需求量、销售量均降低;追求高回收率的政策并不总是有效的;而提高WEEE的旧材料转化率对于闭环供应链有利。 相似文献
54.
55.
Leitão JM Esteves da Silva JC Girón AJ Muñoz de la Peña A 《Journal of fluorescence》2008,18(6):1065-1076
Excitation emission fluorescence matrices (EEMs) of Verapamil drug were obtained by direct and by derivatization fluorescence
spectroscopy. The fluorescence excitation and emission wavelengths were displaced to longer wavelengths and the fluorescence
intensity was enhanced upon derivation with respect to the native fluorescence of the drug. The complete EEM of the native
fluorescence of the drug and of the derivatization product were rapidly acquired by using a charged-coupled device detector
(CCD), which is advantageous in terms of speed in the analysis, with respect to the use of a conventional photomultiplier
detector. The EEMs were analyzed by several second-order multivariate calibration methods exploiting the second order advantage.
The three-dimensional decomposition methods used, based in different assumptions about the trilinearity of the three way data
structure under analysis, were parallel factor analysis (PARAFAC), bilinear least squares (BLLS), parallel factor analysis
2 (PARAFAC2) and multivariate curve resolution—alternating least squares (MCR-ALS). The determination was performed by using
the standard addition approach. The figures of merit of the PARAFAC and BLLS methods were calculated, obtaining a lower limit
of detection with the derivatization procedure, when compared with the direct measurement of the fluorescence of the drug.
In Verapamil drug the best estimations were found with the BLLS and the MCR-ALS models. In the quantification of Verapamil
in a pharmaceutical formulation the best estimation, when compared with the result obtained by the US Pharmacopeia high performance
liquid chromatography approach, was obtained by direct fluorescence spectroscopy with MCR-ALS and by derivatization fluorescence
spectroscopy with the PARAFAC2 model. 相似文献
56.
57.
Eliana F. C. Simões João M. M. Leitão Joaquim C. G. Esteves da Silva 《Journal of fluorescence》2014,24(2):639-648
The quantification of nitric oxide (NO) based on the quenching of the fluorescence of a nanocomposites sensor constituted by cadmium/selenium quantum dots (CdSe) stabilized by chitosan (CS) and mercaptosuccinic acid (MSA) is assessed. The optimization of the response of the CS-CdSe-MSA nanocomposites to NO was done by multivariate response surface experimental design methodologies. The highest fluorescence quenching was obtained at pH 5.5 and at room temperature. The NO quantification capability of CS-CdSe-MSA was evaluated using standard solutions and a NO donor reagent. A large linear working range from 5 to 200 μM and a limit of detection of 1.86 μM were obtained. Better quantification results were obtained using the NO donor reagent. Besides NO, the response of the fluorescence of CS-CdSe-MSA to the main reactive oxygen and nitrogen species and similar NO compounds was also assessed. 相似文献
58.
A new bioluminescent method for coenzyme A (CoA) quantification is described. It is based on the enzymatic conversion of dehydroluciferyl-adenylate
(L-AMP) into dehydroluciferyl-coenzyme A (L-CoA) by firefly luciferase (E.C. 1.13.12.7) (LUC), which causes a flash of light
that can be measured in a luminometer. The method was subjected to optimization using experimental design methodologies to
obtain optimum values for the concentrations of L-AMP ([L-AMP]), luciferase ([LUC]), ATP ([ATP]) and luciferin ([LH2]). This method has a linear response over the range of 0.25–4 μM of CoA, with a limit of detection (LOD) of 0.24 μM and a
limit of quantification (LOQ) of 0.80 μM. The assay has a relative standard deviation of about 7%. By coupling this optimized
procedure to bioluminescent detection, a sensible and robust method can be obtained for the analysis of CoA. 相似文献
59.
A Diltiazem kinetic spectrophotometric method was optimized by factorial analysis. The experimental method is based on a two-stage reaction of Diltiazem with hydroxylamine and a ferric salt: in the first stage there is a hydroxamic acid formation; and, in the second stage there is a red colour complex ferric hydroxamate formation. The variables under investigation were: solvent; hydroxylamine, sodium hydroxide and ammonium ferric sulphate concentrations; volume of perchloric acid; and, temperature. The responses of the reactional system were the maximum absorbance, the wavelength and the reaction time at maximum absorbance. Experimental design methodologies were used in the optimization. Fractional and full factorial designs followed by optimization Box-Behnken and central composite experimental designs were used. The observed optimum conditions were: methanol as reaction solvent; hydroxylamine concentration of 9.375%; sodium hydroxide concentration of 18.750%; ferric reagent concentration of 2.000%; minimum volume of perchloric acid to neutralize the sodium hydroxide; and, room temperature as reaction temperature. With this set of experimental conditions a reaction time of 10.5 s with maximum colour development at 512 nm wavelength was achieved. 相似文献
60.
Duarte Darío J. R. Miranda Margarida S. Esteves da Silva Joaquim C. G. Liebman Joel F. 《Structural chemistry》2016,27(2):663-670
Structural Chemistry - In this paper, we investigate the nature of the carbonyl and the intraring C–C, C–N, C–O, N–N, O–O and N–O bonds of cyclopropanone and the... 相似文献