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91.
Nasser R. El-Brollosy Claus Nielsen Erik B. Pedersen 《Monatshefte für Chemie / Chemical Monthly》2005,12(2):1247-1254
A series of Emivirine and GCA-186 analogues substituted at N-1 with indan-1-yloxymethyl (6a–6c) and indan-2-yloxymethyl (6d–6f) were synthesized by reaction of the corresponding bis(indanyloxy)methans with uracils having 5-ethyl or 5-isopropyl and 6-benzyl or 6-(3,5-dimethylbenzyl) substituents. A route to the corresponding N-1 substituted 4-hydroxybut-2-enyloxymethyl analogue was also devised. All newly synthesized compounds showed potent activity against wild-type HIV-1, the most active compound being 5-ethyl-1-(indan-1-yloxymethyl)-6-(3,5-dimethylbenzyl)uracil (6b), which was 50-fold more active than Emivirine. 相似文献
92.
alpha-Glycylglycine in its actual crystalline phase is studied by ab initio calculated nuclear quadrupole coupling constants. These physical quantities are computed for 2H and 14N in the hydrogen bonds. The type of hydrogen bond is the N-H...O type. The computations are performed with the RHF and B3LYP methods and 6-31++G** and 6-311++G** basis sets using the Gaussian 98 program. Values of the calculated nuclear quadrupole coupling constants are shown in Tables 1-3. The aim of this work is the study of 2H and 14N quadrupole coupling constants which contribute in the CON2H...O=CN2H type of hydrogen bond. The computed nuclear quadrupole coupling constants of 2H nuclei meet the related experimental values. In addition, the computed chi value of 14N belonging to the -CO-14NH- group agrees well with values obtained experimentally. However, there are some discrepancies between calculated 14N chi values of the N+H3 residue and experiments. Also, the values of these physical parameters are calculated for >C2H2 of alpha-glycylglycine in its crystalline phase. Calculations for these parameters are carried out in a single molecule using X-ray diffraction coordinates, too. 相似文献
93.
Aluminium dodecyl sulfate trihydrate [Al(DS)3].3H2O is easily prepared and can be used as a Lewis acid surfactant catalyst in water to conduct the highly efficient Michael addition of indoles and pyrrole to alpha,beta-unsaturated electron-deficient compounds at room temperature. 相似文献
94.
Nasser E. Bastani Thomas E. Gundersen Rune Blomhoff 《Rapid communications in mass spectrometry : RCM》2009,23(18):2885-2890
F2‐isoprostanes are a family of prostaglandin F2‐like compounds that are formed by free‐radical‐catalyzed peroxidation of arachidonic acid. Several F2‐isoprostanes, but in particular 8‐epi PGF2α, are widely used as oxidative stress biomarkers. An analytical method based on liquid chromatography with negative electrospray ionization (ESI) coupled to tandem mass spectrometric detection (LC/MS/MS) was developed for the determination of 8‐epi PGF2α concentrations in human plasma, whole blood, erythrocytes and urine. 8‐epi PGF2α‐d4, a stable isotope derivative of 8‐epi PGF2α, was used as an internal standard (IS). A 50 µL sample was focused on‐column and separated on two 3 µm particle size SUPELCOSIL? ABZ+Plus HPLC columns (15 cm × 4.6 mm and 7.5 cm × 4.6 mm) connected in series. An Applied Biosystems 4000 Q TRAP LC/MS/MS system with ESI was operated in multiple reaction monitoring (MRM) mode with the precursor‐to‐product ion transitions m/z 353.4 → 193.1 (8‐epi PGF2α), 357.4 → 197.1 (8‐epi PGF2α‐d4), used for quantification. The assay was fully validated and found to have adequate accuracy, precision, linearity, sensitivity and selectivity. The mass limit of detection (mLOD) was 1 pg of analyte eluting from the column. The assay has been successfully applied to the analysis of human plasma, whole blood, erythrocytes and urine samples. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
95.
96.
Nasser–eddine Tatar 《Mediterranean Journal of Mathematics》2013,10(1):213-226
A new assumption on the relaxation in a viscoelastic problem ensuring uniform stability in an arbitrary rate is established. This assumption replaces a usual condition and allows for a much wider class of kernels. As consequences several earlier results are extended and improved. 相似文献
97.
Bakr F. Abdel-Wahab Hatem A. Abdel-Aziz Essam M. Ahmed 《Monatshefte für Chemie / Chemical Monthly》2009,20(7):601-605
Abstract
Potassium hydrazinecarbodithioate were prepared by treatment of acid hydrazides with carbon disulfide in the presence of potassium hydroxide. Reaction of this potassium salt with hydrazine hydrate, phenacyl bromide, or hydrazonoyl chlorides afforded 1,2,4-triazole, 1,3-thiazole, and 1,3,4-thiadiazoles. Reaction of 1,2,4-triazole with phenacyl bromide or hydrazonoyl chlorides afforded the corresponding 1,2,4-triazolo[3,4-b][1, 3, 4]-thiadiazines. All these new compounds were screened for antibacterial and antifungal activity. Some had promising activity. 相似文献98.
The asymptotic iteration method is used to find exact and approximate solutions of Schrödinger’s equation for a number of one-dimensional trigonometric potentials (sine-squared, double-cosine, tangent-squared, and complex cotangent). Analytic and approximate solutions are obtained by first using a coordinate transformation to reduce the Schrödinger equation to a second-order differential equation with an appropriate form. The asymptotic iteration method is also employed indirectly to obtain the terms in perturbation expansions, both for the energies and for the corresponding eigenfunctions. 相似文献
99.
Distributed point source method (DPSM) is gradually gaining popularity in the field of non-destructive evaluation (NDE). DPSM is a semi-analytical technique that can be used to calculate the ultrasonic fields produced by transducers of finite dimension placed in homogeneous or non-homogeneous media. This technique has been already used to model ultrasonic fields in homogeneous and multi-layered fluid structures. In this paper the method is extended to model the ultrasonic fields generated in both fluid and solid media near a fluid-solid interface when the transducer is placed in the fluid half-space near the interface. Most results in this paper are generated by the newly developed DPSM technique that requires matrix inversion. This technique is identified as the matrix inversion based DPSM technique. Some of these results are compared with the results produced by the Rayleigh-Sommerfield integral based DPSM technique. Theory behind both matrix inversion based and Rayleigh-Sommerfield integral based DPSM techniques is presented in this paper. The matrix inversion based DPSM technique is found to be very efficient for computing the ultrasonic field in non-homogeneous materials. One objective of this study is to model ultrasonic fields in both solids and fluids generated by the leaky Rayleigh wave when finite size transducers are inclined at Rayleigh critical angles. This phenomenon has been correctly modelled by the technique. It should be mentioned here that techniques based on paraxial assumptions fail to model the critical reflection phenomenon. Other advantages of the DPSM technique compared to the currently available techniques for transducer radiation modelling are discussed in the paper under Introduction. 相似文献
100.
H. El-Ghandoor Ibraheem Nasser M. A. Abd-El Rahman R. Hassan 《Optics & Laser Technology》2000,32(4):281
A new technique (El-Ghandoor et al., Opt. Laser Technol. 31(7) (1999) 481–488) has been applied to study the shape of transverse interference fringes, instead of multiple beam Fizeau fringes (Marhic, Stein, Appl. Phys. Lett. 35 (1975) 1678–1682), from a GRIN optical fiber. In this technique, a laser light sheet is used to illuminate and pass directly through the optical fiber. Theoretical expressions are derived for the optical path differences of three groups of interference beams. The first one passes through the cladding, the core, and then the cladding once again; the second passes through the cladding only, and the third passes through the surrounding air. Theoretical expressions for the shape of transverse interference fringes formed across isotropic non-absorbing optical fibers are also calculated. 相似文献