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951.
E. S. Voropai M. P. Samtsov K. N. Kaplevskii A. A. Maskevich V. I. Stepuro O. I. Povarova I. M. Kuznetsova K. K. Turoverov A. L. Fink V. N. Uverskii 《Journal of Applied Spectroscopy》2003,70(6):868-874
Comparative analysis of the absorption and fluorescence spectra and fluorescence excitation spectra of thioflavin T (ThT) in various solvents and in the composition of amyloid fibrils has shown that ThT, when excited in the region of the long-wavelength absorption band, fluoresces in the spectral region with a maximum at 478–484 nm. The appearance in aqueous and alcohol solutions of a fluorescence band with a maximum near 440 nm has been attributed to the presence in the composition of the ThT preparations of an impurity with an absorption band in the 340–350-nm range. The literature data showing that in glycerol ThT has a wide fluorescence spectrum with two maxima are due to the artifact connected with the use of a high concentration of the dye. It has been suggested that the cause of the low quantum yield of ThT aqueous and alcohol solutions is the breakage of the system of conjugated bonds due to the reorientation of the benzothiozole and benzaminic rings of ThT in the excited state with respect to one another. The main factor determining the high quantum yield of fluorescence of ThT incorporated in fibrils is the steric restriction of the rotation of the rings about one another under these conditions. The suggestions made have been verified by the quantum-chemical calculation of the ThT molecule geometry in the ground and excited states. 相似文献
952.
采用溶胶-凝胶法在Pt/Ti/SiO2/Si衬底上制备了不同La掺杂浓度PLZT(x/40/60)薄膜- x射线衍射分析表明制备的PLZT(x/40/60)薄膜是具有单一钙钛矿结构的多晶薄膜- 通过红外椭圆偏振光谱仪测量了波长为2-5—12-6μm范围内PLZT薄膜的椭偏光谱,采用经典色 散模型拟合获得PLZT薄膜的红外光学常数,同时也拟合获得PLZT薄膜的厚度- 随着La掺杂浓 度的增大,折射率逐渐减小- 而消光系数除PLZT(4/40/60)薄膜外,呈现逐渐增大的趋势- 分析表明这些差异主要与PLZ
关键词:
PLZT薄膜
红外光学性质
红外椭圆偏振光谱 相似文献
953.
954.
955.
956.
957.
K. Olimov K. G. Gulamov V. V. Lugovoi S. L. Lutpullaev Kh. K. Olimov V. I. Petrov 《Physics of Atomic Nuclei》2007,70(11):1977-1979
958.
Lai-Jiu Lin 《Journal of Global Optimization》2007,38(1):21-39
In this paper, we study an existence theorem of systems of generalized quasivariational inclusions problem. By this result,
we establish the existence theorems of solutions of systems of generalized equations, systems of generalized vector quasiequilibrium
problem, collective variational fixed point, systems of generalized quasiloose saddle point, systems of minimax theorem, mathematical
program with systems of variational inclusions constraints, mathematical program with systems of equilibrium constraints and
systems of bilevel problem and semi-infinite problem with systems of equilibrium problem constraints.
This research was supported by the National Science Council of the Republic of China. 相似文献
959.
960.
The emission characteristics of a transverse volume discharge in a He: HCl = 10: 1 mixture at a total pressure of 1–8 kPa were investigated. The plasma volume was 18 × 2.2 × 1 cm3, the interelectrode distance was d=2.2 cm, and the charging voltage of the main storage capacitor was 5–10 kV. The emission characteristics of the discharge were studied in the spectral range of 500–1000 nm. This type of discharge can be used in pulsed dry-etching plasmochemical reactors. The density of atomic chlorine radicals in the plasma was optimized in terms of the pressure of the initial working He-HCl mixture by measuring the relative radiation intensity of the Cl 837(5)-nm spectral line. The density of molecular radicals can be monitored indirectly by recording radiation from the excited chlorine-free decomposition products of HCl molecules (the Hα 656-nm line). 相似文献